The relative contributions of asthenospheric mantle, lithospheric mantle, and continental crust in the genesis of the Siberian Traps Large Igneous Province (ST-LIP) remain poorly constrained. Most models invoke partial melting of asthenospheric mantle within a mantle plume with an inventory of recycled crustal material, with or without melting of subcontinental lithospheric mantle, and crustal contamination during ascent through the continental lithosphere. A greater understanding of this topic is of fundamental importance because the ST-LIP basalts are associated with the large Permian-Triassic extinction and the world’s largest magmatic Ni-Cuplatinum group element sulfide resources (Ni-Cu-PGE), the Norilsk-Talnakh mining camp. The ~250 ± 2 Ma Siberian Traps at Norilsk contain a classic sequence of basaltic rocks that provide a spatial and stratigraphic context for the changing chemistry of the eruptive products. We present a detailed geochemical and Sr-Nd-Hf-Mo isotopic investigation of ST-LIP volcanic rocks and associated sedimentary rocks, including coal and anhydrite, from the Norilsk area. The 98Mo/95Mo isotope ratios (reported as δ98Mo ratio relative to NIST SRM 3134) vary significantly from −0.62 to 0.07 ‰ for the older basalt formations and −0.41 to 0.03 ‰ for the younger basalt formations. The range of δ98Mo and its correlation with the other geochemical tracers cannot be explained by post-magmatic alteration, magmatic differentiation, or sulfide fractionation as Mo behaves as a lithophile element under these magmatic conditions. We suggest that the δ98Mo range can be explained by the interaction of the plume with subcontinental lithospheric mantle modified by subduction processes. This is particularly prominent in the earlier Ivakinsky to Gudchikhinsky formations, where light δ98Mo values coupled with low Mo/Ce can be explained by contributions from a dehydrated eclogitic component, whereas more rare heavy δ98Mo values and high Mo/Ce likely require contributions from a fluid metasomatized mantle source. Later magmas of the Nadezhdinsky formation show clear evidence of crustal contamination in their combined Mo-Sr-Nd-Hf isotope and trace element systematics, while the later more voluminous Morongovsky type magmas are shallower, large degree melts with limited crustal interaction. Our data show the usefulness of Mo isotopes in deciphering magma sources of large igneous province eruptions.
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Initial Cenozoic Magmatic Activity in East Africa: New Geochemical Constraints on Magma Distribution within the Eocene Continental Flood Basalt Province
Abstract The initial interaction between material rising from the African Large Low Shear Velocity Province and the African lithosphere manifests as the Eocene continental large igneous province (LIP), centered on southern Ethiopia and northern Kenya. Here we present a geographically well-distributed geochemical dataset comprising the flood basalt lavas of the Eocene continental LIP to refine the regional volcano-stratigraphy into three distinct magmatic units: (1) the highly-alkaline small-volume Akobo Basalts (49.4–46.6 Ma), representing the initial phase of flood basalt volcanism derived from the melting of lithospheric-mantle metasomes, (2) the primitive and spatially restricted Amaro Basalts (45.2–39.58 Ma) representing the early main phase of flood basalt volcanism derived from the melting of the upwelling thermochemical anomaly, and (3) the spatially extensive Gamo-Makonnen magmatic unit (38-28 Ma) representing the mature main phase of flood basalt volcanism that has undergone significant processing within the lithosphere resulting in relatively homogeneous compositions. The focused intrusion of these main phase magmas over 10 m.y. preconditioned the African lithosphere for the localization of strain during subsequent episodes of lithospheric stretching. The focusing of strain into the region occupied by this continental LIP may have contributed to the initial extension in SW Ethiopia associated with the East African Rift. Supplementary material at https://doi.org/10.6084/m9.figshare.c.5557626
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- Award ID(s):
- 1824417
- PAR ID:
- 10294872
- Editor(s):
- Srivastava, R. K.
- Date Published:
- Journal Name:
- Geological Society, London, Special Publications
- Volume:
- 518
- ISSN:
- 0305-8719
- Page Range / eLocation ID:
- SP518-2020-262
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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