GaAs(111)B are commercially available substrates widely used for the growth of van der Waals chalcogenide films. Wafer-scale, high-quality crystalline films can be deposited on GaAs(111)B substrates using molecular beam epitaxy. However, two obstacles persist in the use of GaAs(111)B: first, the surface dangling bonds make it challenging for the growth of van der Waals materials; second, the As-terminated surface is prone to aging in air. This study investigated a thermal treatment method for deoxidizing GaAs(111)B substrates while simultaneously passivating the surface dangling bonds with Se. By optimizing the treatment parameters, we obtained a flat and completely deoxidized platform for subsequent film growth, with highly reproducible operations. Furthermore, through first-principle calculations, we find that the most energetically favorable surface of GaAs(111)B after Se passivation consists of 25% As atoms and 75% Se atoms. Finally, we discovered that the common storage method using food-grade vacuum packaging cannot completely prevent substrate aging, and even after thermal treatment, aging still affects subsequent growth. Therefore, we recommend using N2-purged containers for better preservation.
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Maintaining Atomically Smooth GaAs Surfaces After High-Temperature Processing for Precise Interdiffusion Analysis and Materials Engineering
Arsenic’s high vapor pressure leads to thermal instability during hightemperature processing of GaAs, contributing to the performance degradation of subsequently fabricated devices. The resulting surface damage also obfuscates the exact quantitative characterization of the diffusion process, a critical step in device manufacturing. In this experiment, an encapsulant-and-sacrificial-layer procedure is employed to reduce arsenic sublimation and preserve a smooth surface. A capped GaAs/InGaAs/GaAs quantum well structure is subjected to rapid thermal annealing, and AFM, SEM, and EDS are used to compare the surface qualities of the postannealed encapsulated GaAs against the reference GaAs. For the encapsulated substrate, a smooth surface with an average root-mean-squared value of 6.5 Å is achieved after high-temperature processing. SIMS analysis is used to obtain the diffused indium atomic concentration profiles for a smooth and roughened GaAs surface and their corresponding diffusion parameters. The analysis demonstrates how precise diffusion parameter extraction requires preserving an atomically-smooth surface in semiconductor diffusion characterization.
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- Award ID(s):
- 1808065
- PAR ID:
- 10295323
- Date Published:
- Journal Name:
- Journal of vacuum science and technology
- Volume:
- Submitted
- ISSN:
- 2166-2746
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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