We use yearlong vertical temperature profile time‐series (seven thermistors at evenly spaced depth intervals from 10 to 70 cm) from five sites in and around the Deep Hole thermal area, southeast of Stevenson Island, Yellowstone Lake, to investigate heat and mass fluxes across the lake floor. The records demonstrate that thermal gradients in surficial sediments are modulated by a rich spectrum of bottom water temperature variations generated by hydrodynamic processes, and that sites inside the thermal area also respond to hydrothermal variations. We develop and implement a new method for estimating the sediment effective thermal diffusivity and pore fluid vertical flow rate that exploits the full spectrum of observed temperature variations to generate the parameter estimates, uncertainties, and metrics to assess statistical significance. Sediments at sites outside thermal areas have gradients of ∼7.5°C/m, in situ thermal diffusivities of ∼1.6 × 10−7 m2/s consistent with highly porous (80–90%) siliceous sediments, and experience hypolentic flow in the upper ∼20 cm. Sites inside the Deep Hole thermal area exhibit considerable spatial and temporal variability, with gradients of 1–32°C/m, and higher thermal diffusivities of ∼2–12 × 10−7 m2/s, consistent with hydrothermal alteration of biogenic silica to clays, quartz, and pyrite. Upward pore fluid flow at these sites is observed across multiple depth intervals, with maximum values of ∼3 cm/day. The observed spatial and temporal variability within the thermal area is consistent with upward finger flow combined with short wavelength convection within the porous sediments above a steam reservoir.
We present a mechanism for thermal cycling that does not require electricity; instead, the device functions as a heat engine and requires only a generic heat source and a shape memory alloy (SMA) spring. The SMA spring mechanically translates to a low-temperature reservoir when heated, and the subsequent cooling of the spring causes translation back to a high-temperature reservoir. The usefulness of the mechanism is displayed by performing the quantitative polymerase chain reaction (qPCR), an important biological assay that requires thermal cycling for amplification of nucleic acids. The ability to perform qPCR with a generic heat source enables a variety of significant health diagnostic tests to be performed in resource limited settings, where electricity access may not be available or reliable. We demonstrate robust thermal cycling using a direct flame, sunlight, and electricity as heat sources, with maximum heating and cooling rates of 4.4 °C s−1and −2.7 °C s−1, respectively.
more » « less- Award ID(s):
- 1719875
- NSF-PAR ID:
- 10303192
- Publisher / Repository:
- IOP Publishing
- Date Published:
- Journal Name:
- Smart Materials and Structures
- Volume:
- 29
- Issue:
- 4
- ISSN:
- 0964-1726
- Page Range / eLocation ID:
- Article No. 045038
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
more » « less
Abstract -
more » « less
Summary We combined optical and atomic force microscopy to observe morphology and kinetics of microstructures (typically referred to as bees) that formed at free surfaces of unmodified Performance Graded (PG) 64‐22 asphalt binders upon cooling from 150°C to room temperature (RT) at 5°C min–1, and changes in these microstructures when the surface was terminated with a transparent solid (glass) or liquid (glycerol) overlayer. The main findings are: (1) at free binder surfaces, wrinkled microstructures started to form near the crystallization temperature (∼45°C) of saturates such as wax observed by differential scanning calorimetry, then grew to ∼5 µm diameter, ∼25 nm wrinkle amplitude and 10–30% surface area coverage upon cooling to RT, where they persisted indefinitely without observable change in shape or density. (2) Glycerol coverage of the binder surface during cooling reduced wrinkled area and wrinkle amplitude three‐fold compared to free binder surfaces upon initial cooling to RT; continued glycerol coverage at RT eliminated most surface microstructures within ∼4 h. (3) No surface microstructures were observed to form at binder surfaces covered with glass. (4) Submicron bulk microstructures were observed by near‐infrared microscopy beneath the surfaces of all binder samples, with size, shape and density independent of surface coverage. No tendency of such structures to float to the top or sink to the bottom of mm‐thick samples was observed. (5) We attribute the dependence of surface wrinkling on surface coverage to variation in interface tension, based on a thin‐film continuum mechanics model.
Lay Description Asphalt binder, or bitumen, is the glue that holds aggregate particles together to form a road surface. It is derived from the heavy residue that remains after distilling gasoline, diesel and other lighter products out of crude oil. Nevertheless, bitumen varies widely in composition and mechanical properties. To avoid expensive road failures, bitumen must be processed after distillation so that its mechanical properties satisfy diverse climate and load requirements. International standards now guide these mechanical properties, but yield varying long‐term performance as local source composition and preparation methods vary.
In situ diagnostic methods that can predict bitumen performance independently of processing history are therefore needed. The present work focuses on one promising diagnostic candidate: microscopic observation of internal bitumen structure. Past bitumen microscopy has revealed microstructures of widely varying composition, size, shape and density. A challenge is distinguishing bulk microstructures, which directly influence a binder's mechanical properties, from surface microstructures, which often dominate optical microscopy because of bitumen's opacity and scanning‐probe microscopy because of its inherent surface specificity. In previously published work, we used infrared microscopy to enhance visibility of bulk microstructure. Here, as a foil to this work, we use visible‐wavelength microscopy together with atomic‐force microscopy (AFM) specifically to isolatesurface microstructure, to understand its distinct origin and morphology, and to demonstrate its unique sensitivity to surface alterations. To this end, optical microscopy complements AFM by enabling us to observe surface microstructures form at temperatures (50°C–70°C) at which bitumen's fluidity prevents AFM, and to observe surface microstructure beneath transparent, but chemically inert, liquid (glycerol) and solid (glass) overlayers, which alter surface tension compared to free surfaces. From this study, we learned, first, that, as bitumen cools, distinctly wrinkled surface microstructures form at the same temperature at which independent calorimetric studies showed crystallization in bitumen, causing it to release latent heat of crystallization. This shows that surface microstructures are likely precipitates of the crystallizable component(s). Second, a glycerol overlayer on the cooling bitumen results in smaller, less wrinkled, sparser microstructures, whereas a glass overlayer suppresses them altogether. In contrast, underlying smaller bulk microstructures are unaffected. This shows that surface tension is the driving force behind formation and wrinkling of surface precipitates. Taken together, the work advances our ability to diagnose bitumen samples noninvasively by clearly distinguishing surface from bulk microstructure. -
more » « less
In the world of soft-robotic medical devices, there is a growing need for low profile, non-rigid, and lower power actuators for soft exoskeletons and dynamic compression garments. Advanced compression garments with integrated shape memory materials have been developed recently to alleviate the functional and usability limitations associated with traditional compression garments. These advanced garments use contractile shape memory alloy (SMA) coil actuators to produce dynamic compression on the body through selective heating of the SMA material. While these garments can create spatially- and temporally-controllable compression, typical SMA materials (e.g., 70°C Flexinol) consume considerable power and require considerable thermal insulation to protect the wearer during the heating phase of the SMA actuation. Alternative SMA materials (e.g., NiTi #8 by Fort Wayne Metals, Inc.) transform below room temperature and do so using no applied electrical power and generate no waste heat. However, these materials are challenging to dynamically control and require active refrigeration to reset to material. In theory, low-temperature SMA actuators made from materials like NiTi #8 may maintain additional dynamic actuation capacity once equilibrated to room temperature (i.e., the material may not fully transform), as the SMA phase transformation temperature window expands when the material experiences applied stress. This paper investigates this possibility: we manufactured and tested low-temperature NiTi coil actuators to determine the magnitude of the additional force that can be generated via Joule heating once the material has equilibrated to room temperature. SMA spring actuators made from NiTi #8 consumed 84% less power and stabilized at significantly lower temperatures (26.0°C vs. 41.2°C) than SMA springs made from 70°C Flexinol, when actuated at identically fixed displacements (100% nominal strain) and when driven to produce equal forces (∼3.35N). This demonstration of low-power, minimal-heat exposure SMA actuation holds promise for many future wearable actuation applications, including dynamic compression garments.
-
Thermal energy harvesting from natural resources and waste heat is becoming critical due to ever-increasing environmental concerns. However, so far, available thermal energy harvesting technologies have only been able to generate electricity from large temperature gradients. Here, we report a fundamental breakthrough in low-grade thermal energy harvesting and demonstrate a device based on the thermomagnetic effect that uses ambient conditions as the heat sink and operates from a heat source at temperatures as low as 24 °C. This concept can convert temperature gradients as low as 2 °C into electricity while operating near room temperature. The device is found to exhibit a power density (power per unit volume of active material) of 105 μW cm −3 at a temperature difference of 2 °C, which increases to 465 μW cm −3 at a temperature difference of 10 °C. The power density increases by 2.5 times in the presence of wind with a speed of 2.0 m s −1 . This advancement in thermal energy harvesting technology will have a transformative effect on renewable energy generation and in reducing global warming.more » « less
-
more » « less
Abstract Many canyon‐bound rivers have been dammed and downstream flow and water temperatures modified. In some regions, climate change is expected to cause lower storage in reservoirs and warmer release temperatures, which may further alter downstream flow and thermal regimes. To anticipate potential future changes, we first need to understand the dominant heat transfer mechanisms in canyon‐bound river systems. Toward this end, we adapt a dynamic process‐based river routing and temperature model to account for complex shading and radiation characteristics found in canyon‐bound rivers. We apply the model to a 362 km segment of the Colorado River in Grand Canyon National Park, USA to simulate temperature over an 18‐year period. Extensive temperature and flow data sets from within the canyon were used to assess model performance. At the most downstream gaging location, root mean square errors of hourly flow routing and temperature predictions were 11.5 m3/s and 0.93°C, respectively. We found that heat fluxes controlling temperatures were highly variable over space and time, primarily due to shortwave radiation dynamics and hydropeaking flow conditions. Additionally, the large differences between air and water temperature during summer periods resulted in high sensible and latent heat fluxes. Sensitivity analyses indicate that reservoir release temperatures are most influential above the RM88 gage (141 km below Glen Canyon Dam), while a combination of discharge, shortwave radiation, and air temperature become more important farther downstream. This study illustrates the importance of understanding the spatial and temporal variability of topographic shading when predicting water temperatures in canyon‐bound rivers.
