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1. Low-J CO Line Ratios from Single-dish CO Mapping Surveys and PHANGS-ALMA

   https://doi.org/10.3847/1538-4357/ac3490  

   Leroy, Adam K. ; Rosolowsky, Erik ; Usero, Antonio ; Sandstrom, Karin ; Schinnerer, Eva ; Schruba, Andreas ; Bolatto, Alberto D. ; Sun, Jiayi ; Barnes, Ashley. T. ; Belfiore, Francesco ; et al ( March 2022 , The Astrophysical Journal)

   Abstract We measure the low- J CO line ratios R 21 ≡ CO (2–1)/CO (1–0), R 32 ≡ CO (3–2)/CO (2–1), and R 31 ≡CO (3–2)/CO (1–0) using whole-disk CO maps of nearby galaxies. We draw CO (2–1) from PHANGS-ALMA, HERACLES, and follow-up IRAM surveys; CO (1–0) from COMING and the Nobeyama CO Atlas of Nearby Spiral Galaxies; and CO (3–2) from the James Clerk Maxwell Telescope Nearby Galaxy Legacy Survey and Atacama Pathfinder Experiment Large APEX Sub-Millimetre Array mapping. All together, this yields 76, 47, and 29 maps of R 21 , R 32 , and R 31 atmore »20″ ∼ 1.3 kpc resolution, covering 43, 34, and 20 galaxies. Disk galaxies with high stellar mass, log ( M ⋆ / M ⊙ ) = 10.25 – 11 , and star formation rate (SFR) = 1–5 M ⊙ yr −1 , dominate the sample. We find galaxy-integrated mean values and a 16%–84% range of R 21 = 0.65 (0.50–0.83), R 32 = 0.50 (0.23–0.59), and R 31 = 0.31 (0.20–0.42). We identify weak trends relating galaxy-integrated line ratios to properties expected to correlate with excitation, including SFR/ M ⋆ and SFR/ L CO . Within galaxies, we measure central enhancements with respect to the galaxy-averaged value of ∼ 0.18 − 0.14 + 0.09 dex for R 21 , 0.27 − 0.15 + 0.13 dex for R 31 , and 0.08 − 0.09 + 0.11 dex for R 32 . All three line ratios anticorrelate with galactocentric radius and positively correlate with the local SFR surface density and specific SFR, and we provide approximate fits to these relations. The observed ratios can be reasonably reproduced by models with low temperature, moderate opacity, and moderate densities, in good agreement with expectations for the cold interstellar medium. Because the line ratios are expected to anticorrelate with the CO (1–0)-to-H 2 conversion factor, α CO 1 − 0 , these results have general implications for the interpretation of CO emission from galaxies.« less
2. Maximum Matching in Two, Three, and a Few More Passes Over Graph Streams

   https://doi.org/10.4230/LIPIcs.APPROX-RANDOM.2017.15  

   Kale, Sagar ; Tirodkar, Sumedh ( August 2017 , Approximation, Randomization, and Combinatorial Optimization. Algorithms and Techniques)

   We consider the maximum matching problem in the semi-streaming model formalized by Feigenbaum, Kannan, McGregor, Suri, and Zhang that is inspired by giant graphs of today. As our main result, we give a two-pass (1/2 + 1/16)-approximation algorithm for triangle-free graphs and a two-pass (1/2 + 1/32)-approximation algorithm for general graphs; these improve the approximation ratios of 1/2 + 1/52 for bipartite graphs and 1/2 + 1/140 for general graphs by Konrad, Magniez, and Mathieu. In three passes, we are able to achieve approximation ratios of 1/2 + 1/10 for triangle-free graphs and 1/2 + 1/19.753 for general graphs. Wemore »also give a multi-pass algorithm where we bound the number of passes precisely—we give a (2/3 − ε)- approximation algorithm that uses 2/(3ε) passes for triangle-free graphs and 4/(3ε) passes for general graphs. Our algorithms are simple and combinatorial, use O(n log n) space, and (can be implemented to) have O(1) update time per edge. For general graphs, our multi-pass algorithm improves the best known deterministic algorithms in terms of the number of passes: * Ahn and Guha give a (2/3−ε)-approximation algorithm that uses O(log(1/ε)/ε2) passes, whereas our (2/3 − ε)-approximation algorithm uses 4/(3ε) passes; * they also give a (1 − ε)-approximation algorithm that uses O(log n · poly(1/ε)) passes, where n is the number of vertices of the input graph; although our algorithm is (2/3−ε)-approximation, our number of passes do not depend on n. Earlier multi-pass algorithms either have a large constant inside big-O notation for the number of passes or the constant cannot be determined due to the involved analysis, so our multi-pass algorithm should use much fewer passes for approximation ratios bounded slightly below 2/3.« less
3. UV Inactivation of SARS-CoV-2 across the UVC Spectrum: KrCl* Excimer, Mercury-Vapor, and Light-Emitting-Diode (LED) Sources

   https://doi.org/10.1128/AEM.01532-21  

   Ma, Ben ; Gundy, Patricia M. ; Gerba, Charles P. ; Sobsey, Mark D. ; Linden, Karl G. ( October 2021 , Applied and Environmental Microbiology)

   Dudley, Edward G. (Ed.)

   ABSTRACT Effective disinfection technology to combat severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) can help reduce viral transmission during the ongoing COVID-19 global pandemic and in the future. UV devices emitting UVC irradiation (200 to 280 nm) have proven to be effective for virus disinfection, but limited information is available for SARS-CoV-2 due to the safety requirements of testing, which is limited to biosafety level 3 (BSL3) laboratories. In this study, inactivation of SARS-CoV-2 in thin-film buffered aqueous solution (pH 7.4) was determined across UVC irradiation wavelengths of 222 to 282 nm from krypton chloride (KrCl*) excimers, a low-pressure mercury-vapor lamp, andmore »two UVC light-emitting diodes. Our results show that all tested UVC devices can effectively inactivate SARS-CoV-2, among which the KrCl* excimer had the best disinfection performance (i.e., highest inactivation rate). The inactivation rate constants of SARS-CoV-2 across wavelengths are similar to those for murine hepatitis virus (MHV) from our previous investigation, suggesting that MHV can serve as a reliable surrogate of SARS-CoV-2 with a lower BSL requirement (BSL2) during UV disinfection tests. This study provides fundamental information on UVC’s action on SARS-CoV-2 and guidance for achieving reliable disinfection performance with UVC devices. IMPORTANCE UV light is an effective tool to help stem the spread of respiratory viruses and protect public health in commercial, public, transportation, and health care settings. For effective use of UV, there is a need to determine the efficiency of different UV wavelengths in killing pathogens, specifically SARS-CoV-2, to support efforts to control the ongoing COVID-19 global pandemic and future coronavirus-caused respiratory virus pandemics. We found that SARS-CoV-2 can be inactivated effectively using a broad range of UVC wavelengths, and 222 nm provided the best disinfection performance. Interestingly, 222-nm irradiation has been found to be safe for human exposure up to thresholds that are beyond those effective for inactivating viruses. Therefore, applying UV light from KrCl* excimers in public spaces can effectively help reduce viral aerosol or surface-based transmissions.« less
4. Influence of infrastructure on water quality and greenhouse gas dynamics in urban streams

   https://doi.org/10.5194/bg-14-2831-2017  

   Smith, Rose M. ; Kaushal, Sujay S. ; Beaulieu, Jake J. ; Pennino, Michael J. ; Welty, Claire ( January 2017 , Biogeosciences)

   Streams and rivers are significant sources of nitrous oxide (N₂O), carbon dioxide (CO₂), and methane (CH₄) globally, and watershed management can alter greenhouse gas (GHG) emissions from streams. We hypothesized that urban infrastructure significantly alters downstream water quality and contributes to variability in GHG saturation and emissions. We measured gas saturation and estimated emission rates in headwaters of two urban stream networks (Red Run and Dead Run) of the Baltimore Ecosystem Study Long-Term Ecological Research project. We identified four combinations of stormwater and sanitary infrastructure present in these watersheds, including: (1) stream burial, (2) inline stormwater wetlands, (3) riparian/floodplain preservation, and (4) septic systems.more »We selected two first-order catchments in each of these categories and measured GHG concentrations, emissions, and dissolved inorganic and organic carbon (DIC and DOC) and nutrient concentrations biweekly for 1 year. From a water quality perspective, the DOC : NO₃⁻ ratio of streamwater was significantly different across infrastructure categories. Multiple linear regressions including DOC : NO₃⁻ and other variables (dissolved oxygen, DO; total dissolved nitrogen, TDN; and temperature) explained much of the statistical variation in nitrous oxide (N₂O, r² =  0.78), carbon dioxide (CO₂, r² =  0.78), and methane (CH₄, r² =  0.50) saturation in stream water. We measured N₂O saturation ratios, which were among the highest reported in the literature for streams, ranging from 1.1 to 47 across all sites and dates. N₂O saturation ratios were highest in streams draining watersheds with septic systems and strongly correlated with TDN. The CO₂ saturation ratio was highly correlated with the N₂O saturation ratio across all sites and dates, and the CO₂ saturation ratio ranged from 1.1 to 73. CH₄ was always supersaturated, with saturation ratios ranging from 3.0 to 2157. Longitudinal surveys extending form headwaters to third-order outlets of Red Run and Dead Run took place in spring and fall. Linear regressions of these data yielded significant negative relationships between each gas with increasing watershed size as well as consistent relationships between solutes (TDN or DOC, and DOC : TDN ratio) and gas saturation. Despite a decline in gas saturation between the headwaters and stream outlet, streams remained saturated with GHGs throughout the drainage network, suggesting that urban streams are continuous sources of CO₂, CH₄, and N₂O. Our results suggest that infrastructure decisions can have significant effects on downstream water quality and greenhouse gases, and watershed management strategies may need to consider coupled impacts on urban water and air quality.« less
5. The importance of the counter-cation in reductive rare-earth metal chemistry: 18-crown-6 instead of 2,2,2-cryptand allows isolation of [Y ^II (NR ₂ ) ₃ ] ¹⁻ and ynediolate and enediolate complexes from CO reactions

   https://doi.org/10.1039/C9SC05794C  

   Ryan, Austin J. ; Ziller, Joseph W. ; Evans, William J. ( February 2020 , Chemical Science)

   The use of 18-crown-6 (18-c-6) in place of 2.2.2-cryptand (crypt) in rare earth amide reduction reactions involving potassium has proven to be crucial in the synthesis of Ln( ii ) complexes and isolation of their CO reduction products. The faster speed of crystallization with 18-c-6 appears to be important. Previous studies have shown that reduction of the trivalent amide complexes Ln(NR 2 ) 3 (R = SiMe 3 ) with potassium in the presence of 2.2.2-cryptand (crypt) forms the divalent [K(crypt)][Ln II (NR 2 ) 3 ] complexes for Ln = Gd, Tb, Dy, and Tm. However, for Ho andmore »Er, the [Ln(NR 2 ) 3 ] 1− anions were only isolable with [Rb(crypt)] 1+ counter-cations and isolation of the [Y II (NR 2 ) 3 ] 1− anion was not possible under any of these conditions. We now report that by changing the potassium chelator from crypt to 18-crown-6 (18-c-6), the [Ln(NR 2 ) 3 ] 1− anions can be isolated not only for Ln = Gd, Tb, Dy, and Tm, but also for Ho, Er, and Y. Specifically, these anions are isolated as salts of a 1 : 2 potassium : crown sandwich cation, [K(18-c-6) 2 ] 1+ , i.e. [K(18-c-6) 2 ][Ln(NR 2 ) 3 ]. The [K(18-c-6) 2 ] 1+ counter-cation was superior not only in the synthesis, but it also allowed the isolation of crystallographically-characterizable products from reactions of CO with the [Ln(NR 2 ) 3 ] 1− anions that were not obtainable from the [K(crypt)] 1+ analogs. Reaction of CO with [K(18-c-6) 2 ][Ln(NR 2 ) 3 ], generated in situ , yielded crystals of the ynediolate products, {[(R 2 N) 3 Ln] 2 (μ-OCCO)} 2− , which crystallized with counter-cations possessing 2 : 3 potassium : crown ratios, i.e. {[K 2 (18-c-6) 3 ]} 2+ , for Gd, Dy, Ho. In contrast, reaction of CO with a solution of isolated [K(18-c-6) 2 ][Gd(NR 2 ) 3 ], produced crystals of an enediolate complex isolated with a counter-cation with a 2 : 2 potassium : crown ratio namely [K(18-c-6)] 2 2+ in the complex [K(18-c-6)] 2 {[(R 2 N) 2 Gd 2 (μ-OCHCHO) 2 ]}.« less