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Topological defects appear in symmetry breaking phase transitions and are ubiquitous throughout Nature. As an ideal testbed for their study, defect configurations in nematic liquid crystals (NLCs) could be exploited in a rich variety of technological applications. Here we report on robust theoretical and experimental investigations in which an external electric field is used to switch between predetermined stable chargeless disclination patterns in a nematic cell, where the cell is sufficiently thick that the disclinations start and terminate at the same surface. The different defect configurations are stabilized by a master substrate that enforces a lattice of surface defects exhibiting zero total topological charge value. Theoretically, we model disclination configurations using a Landau-de Gennes phenomenological model. Experimentally, we enable diverse defect patterns by implementing an in-house-developed atomic force measurement scribing method, where NLC configurations are monitored via polarized optical microscopy. We show numerically and experimentally that an “alphabet” of up to 18 unique line defect configurations can be stabilized in a 4 × 4 lattice of alternating s = ±1 surface defects, which can be “rewired” multistably using appropriate field manipulation. Our proof-of-concept mechanism may lead to a variety of applications, such as multistable optical displays and rewirable nanowires. Our studies also are of interest from a fundamental perspective. We demonstrate that a chargeless line could simultaneously exhibit defect-antidefect properties. Consequently, a pair of such antiparallel disclinations exhibits an attractive interaction. For a sufficiently closely spaced pair of substrate-pinned defects, this interaction could trigger rewiring, or annihilation if defects are depinned.
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Manipulation of mechanically nanopatterned line defect assemblies in plane-parallel nematic liquid crystals
Topological line defects are ubiquitous in nature and appear at all physical scales, including in condensed matter systems, nuclear physics, and cosmology. Particularly useful systems to study line defects are nematic liquid crystals (LCs), where they describe singular or nonsingular frustrations in orientational order and are referred to as disclinations. In nematic LCs, line defects could be relatively simply created, manipulated, and observed. We consider cases where disclinations are stabilized either topologically in plane-parallel confinements or by chirality. In the former case, we report on studies in which defect core transformations are investigated, the intriguing dynamics of strength disclinations in LCs exhibiting negative dielectric anisotropy, and stabilization and manipulation of assemblies of defects. For the case of chiral nematics, we consider nanoparticle-driven stabilization of defect lattices. The resulting line defect assemblies could pave the way to several applications in photonics, sensitive detectors, and information storage devices. These excitations, moreover, have numerous analogs in other branches of physics. Studying their universal properties in nematics could deepen understanding of several phenomena, which are still unresolved at the fundamental level.
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- Award ID(s):
- 1901797
- PAR ID:
- 10319780
- Date Published:
- Journal Name:
- Liquid Crystals Reviews
- ISSN:
- 2168-0396
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript
- Journal Article:
- https://doi.org/10.1080/21680396.2022.2042745
