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1. Towards understanding the magnetic properties of the breathing pyrochlore compound Ba3Yb2Zn5O11through single-crystal studies

   https://doi.org/10.1038/s41535-022-00488-w  

   Dissanayake, Sachith ; Shi, Zhenzhong ; Rau, Jeffrey G. ; Bag, Rabindranath ; Steinhardt, William ; Butch, Nicholas P. ; Frontzek, Matthias ; Podlesnyak, Andrey ; Graf, David ; Marjerrison, Casey ; et al ( August 2022 , npj Quantum Materials)

   Ba₃Yb₂Zn₅O₁₁is exceptional among breathing pyrochlore compounds for being in the nearly-decoupled limit where inter-tetrahedron interactions are weak, hosting isolated clusters or molecular magnet-like tetrahedra of magnetic ytterbium (Yb³⁺) ions. In this work, we present the study carried out on single-crystal samples of the breathing pyrochlore Ba₃Yb₂Zn₅O₁₁, using a variety of magnetometry and neutron scattering techniques along with theoretical modeling. We employ inelastic neutron scattering to investigate the magnetic dynamics as a function of applied field (with respect to both magnitude and direction) down to a temperature of 70 mK, where inelastic scattering reveals dispersionless bands of excitations as found in earlier powder sample studies, in good agreement with a single-tetrahedron model. However, diffuse neutron scattering at zero field and dc-susceptibility at finite field exhibit features suggesting the presence of excitations at low-energy that are not captured by the single tetrahedron model. Analysis of the local structure down to 2 K via pair distribution function analysis finds no evidence of structural disorder. We conclude that effects beyond the single tetrahedron model are important in describing the low-energy, low-temperature physics of Ba₃Yb₂Zn₅O₁₁, but their nature remains undetermined.

    

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2. Crossover of high-energy spin fluctuations from collective triplons to localized magnetic excitations in Sr14−xCaxCu24O41 ladders

   https://doi.org/10.1038/s41535-022-00502-1  

   Tseng, Y. ; Thomas, J. ; Zhang, W. ; Paris, E. ; Puphal, P. ; Bag, R. ; Deng, G. ; Asmara, T. C. ; Strocov, V. N. ; Singh, S. ; et al ( December 2022 , npj Quantum Materials)

   Abstract We studied the magnetic excitations in the quasi-one-dimensional (q-1D) ladder subsystem of Sr 14−x Ca x Cu 24 O 41 (SCCO) using Cu L 3 -edge resonant inelastic X-ray scattering (RIXS). By comparing momentum-resolved RIXS spectra with high ( x  = 12.2) and without ( x  = 0) Ca content, we track the evolution of the magnetic excitations from collective two-triplon (2 T) excitations ( x  = 0) to weakly-dispersive gapped modes at an energy of 280 meV ( x  = 12.2). Density matrix renormalization group (DMRG) calculations of the RIXS response in the doped ladders suggest that the flat magnetic dispersion and damped excitation profile observed at x  = 12.2 originates from enhanced hole localization. This interpretation is supported by polarization-dependent RIXS measurements, where we disentangle the spin-conserving Δ S  = 0 scattering from the predominant Δ S  = 1 spin-flip signal in the RIXS spectra. The results show that the low-energy weight in the Δ S  = 0 channel is depleted when Sr is replaced by Ca, consistent with a reduced carrier mobility. Our results demonstrate that off-ladder impurities can affect both the low-energy magnetic excitations and superconducting correlations in the CuO 4 plaquettes. Finally, our study characterizes the magnetic and charge fluctuations in the phase from which superconductivity emerges in SCCO at elevated pressures. 

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3. Multiphase magnetism in Yb 2 Ti 2 O 7

   https://doi.org/10.1073/pnas.2008791117  

   Scheie, Allen ; Kindervater, Jonas ; Zhang, Shu ; Changlani, Hitesh J. ; Sala, Gabriele ; Ehlers, Georg ; Heinemann, Andre ; Tucker, Gregory S. ; Koohpayeh, Seyed M. ; Broholm, Collin ( October 2020 , Proceedings of the National Academy of Sciences)

   We use neutron scattering to show that ferromagnetism and antiferromagnetism coexist in the low T state of the pyrochlore quantum magnet${\text{Yb}}_2{\text{Ti}}_2{\mathrm{O}}_7$. While magnetic Bragg peaks evidence long-range static ferromagnetic order, inelastic scattering shows that short-range correlated antiferromagnetism is also present. Small-angle neutron scattering provides direct evidence for mesoscale magnetic structure that we associate with metastable antiferromagnetism. Classical Monte Carlo simulations based on exchange interactions inferred from$⟨111⟩$-oriented high-field spin wave measurements confirm that antiferromagnetism is metastable within the otherwise ferromagnetic ground state. The apparent lack of coherent spin wave excitations and strong sensitivity to quenched disorder characterizing${\text{Yb}}_2{\text{Ti}}_2{\mathrm{O}}_7$is a consequence of this multiphase magnetism.

    

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4. Effect of magnetic fields on the methyl rotation in a paramagnetic cobalt( ii ) complex. Quasielastic neutron scattering studies

   https://doi.org/10.1039/C8CP01660G  

   Stavretis, Shelby E. ; Mamontov, Eugene ; Moseley, Duncan H. ; Cheng, Yongqiang ; Daemen, Luke L. ; Ramirez-Cuesta, A. J. ; Xue, Zi-Ling ( January 2018 , Physical Chemistry Chemical Physics)

   Molecular dynamics is a fundamental property of metal complexes. These dynamic processes, especially for paramagnetic complexes under external magnetic fields, are in general not well understood. Quasielastic neutron scattering (QENS) in 0–4 T magnetic fields has been used to study the dynamics of Co(acac) 2 (D 2 O) 2 ( 1-d4 , acac = acetylacetonate). At 80–100 K, rotation of the methyl groups on the acac ligands is the dominant dynamical process. This rotation is slowed down by the magnetic field increase. Rotation times at 80 K are 5.6(3) × 10 −10 s at 0 T and 2.04(10) × 10 −9 s at 4 T. The QENS studies suggest that methyl groups in these paramagnetic Co( ii ) molecules do not behave as isolated units, which is consistent with results from earlier magnetic susceptibility studies indicating the presence of intermolecular interactions. DFT calculations show that unpaired electron spin density in 1 is dispersed to the atoms of both acac and H 2 O ligands. Methyl torsions in 1-d4 have also been observed at 5–100 K in inelastic neutron spectroscopy (INS). The QENS and INS results here help understand the dynamics of the compound in the solid state. 

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5. Nucleosynthesis signatures of neutrino-driven winds from proto-neutron stars: a perspective from chemical evolution models

   https://doi.org/10.1093/mnras/stab2828  

   Vincenzo, Fiorenzo ; Thompson, Todd A ; Weinberg, David H ; Griffith, Emily J ; Johnson, James W ; Johnson, Jennifer A ( October 2021 , Monthly Notices of the Royal Astronomical Society)

   ABSTRACT We test the hypothesis that the observed first-peak (Sr, Y, Zr) and second-peak (Ba) s-process elemental abundances in low-metallicity Milky Way stars, and the abundances of the elements Mo and Ru, can be explained by a pervasive r-process contribution originating in neutrino-driven winds from highly magnetic and rapidly rotating proto-neutron stars (proto-NSs). We construct chemical evolution models that incorporate recent calculations of proto-NS yields in addition to contributions from asymptotic giant branch stars, Type Ia supernovae, and two alternative sets of yields for massive star winds and core-collapse supernovae. For non-rotating massive star yields from either set, models without proto-NS winds underpredict the observed s-process peak abundances by 0.3–$1\, \text{dex}$ at low metallicity, and they severely underpredict Mo and Ru at all metallicities. Models incorporating wind yields from proto-NSs with spin periods P ∼ 2–$5\, \text{ms}$ fit the observed trends for all these elements well. Alternatively, models omitting proto-NS winds but adopting yields of rapidly rotating massive stars, with vrot between 150 and $300\, \text{km}\, \text{s}^{-1}$, can explain the observed abundance levels reasonably well for [Fe/H] < −2. These models overpredict [Sr/Fe] and [Mo/Fe] at higher metallicities, but with a tuned dependence of vrot on stellar metallicity they might achieve an acceptable fit at all [Fe/H]. If many proto-NSs are born with strong magnetic fields and short spin periods, then their neutrino-driven winds provide a natural source for Sr, Y, Zr, Mo, Ru, and Ba in low-metallicity stellar populations. Conversely, spherical winds from unmagnetized proto-NSs overproduce the observed Sr, Y, and Zr abundances by a large factor. 

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