More Like this

1. Materializing rival ground states in the barlowite family of kagome magnets: quantum spin liquid, spin ordered, and valence bond crystal states

   https://doi.org/10.1038/s41535-020-0222-8  

   Smaha, Rebecca W. ; He, Wei ; Jiang, Jack Mingde ; Wen, Jiajia ; Jiang, Yi-Fan ; Sheckelton, John P. ; Titus, Charles J. ; Wang, Suyin Grass ; Chen, Yu-Sheng ; Teat, Simon J. ; et al ( December 2020 , npj Quantum Materials)

   null (Ed.)

   Abstract The spin- $$\frac{1}{2}$$ 1 2 kagome antiferromagnet is considered an ideal host for a quantum spin liquid (QSL) ground state. We find that when the bonds of the kagome lattice are modulated with a periodic pattern, new quantum ground states emerge. Newly synthesized crystalline barlowite (Cu 4 (OH) 6 FBr) and Zn-substituted barlowite demonstrate the delicate interplay between singlet states and spin order on the spin- $$\frac{1}{2}$$ 1 2 kagome lattice. Comprehensive structural measurements demonstrate that our new variant of barlowite maintains hexagonal symmetry at low temperatures with an arrangement of distorted and undistorted kagome triangles, for which numerical simulations predict a pinwheel valence bond crystal (VBC) state instead of a QSL. The presence of interlayer spins eventually leads to an interesting pinwheel q  = 0 magnetic order. Partially Zn-substituted barlowite (Cu 3.44 Zn 0.56 (OH) 6 FBr) has an ideal kagome lattice and shows QSL behavior, indicating a surprising robustness of the QSL against interlayer impurities. The magnetic susceptibility is similar to that of herbertsmithite, even though the Cu 2+ impurities are above the percolation threshold for the interlayer lattice and they couple more strongly to the nearest kagome moment. This system is a unique playground displaying QSL, VBC, and spin order, furthering our understanding of these highly competitive quantum states. 

   more » « less
2. Phase diagram of YbZnGaO4 in applied magnetic field

   https://doi.org/10.1038/s41535-021-00380-z  

   Steinhardt, William ; Maksimov, P. A. ; Dissanayake, Sachith ; Shi, Zhenzhong ; Butch, Nicholas P. ; Graf, David ; Podlesnyak, Andrey ; Liu, Yaohua ; Zhao, Yang ; Xu, Guangyong ; et al ( September 2021 , npj Quantum Materials)

   Recently, Yb-based triangular-lattice antiferromagnets have garnered significant interest as possible quantum spin-liquid candidates. One example is YbMgGaO₄, which showed many promising spin-liquid features, but also possesses a high degree of disorder owing to site-mixing between the non-magnetic cations. To further elucidate the role of chemical disorder and to explore the phase diagram of these materials in applied field, we present neutron scattering and sensitive magnetometry measurements of the closely related compound, YbZnGaO₄. Our results suggest a difference in magnetic anisotropy between the two compounds, and we use key observations of the magnetic phase crossover to motivate an exploration of the field- and exchange parameter-dependent phase diagram, providing an expanded view of the available magnetic states in applied field. This enriched map of the phase space serves as a basis to restrict the values of parameters describing the magnetic Hamiltonian with broad application to recently discovered related materials.

    

   more » « less
3. Momentum-independent magnetic excitation continuum in the honeycomb iridate H3LiIr2O6

   https://doi.org/10.1038/s41467-023-40769-x  

   de la Torre, A. ; Zager, B. ; Bahrami, F. ; Upton, M. H. ; Kim, J. ; Fabbris, G. ; Lee, G. -H. ; Yang, W. ; Haskel, D. ; Tafti, F. ; et al ( August 2023 , Nature Communications)

   Understanding the interplay between the inherent disorder and the correlated fluctuating-spin ground state is a key element in the search for quantum spin liquids. H₃LiIr₂O₆is considered to be a spin liquid that is proximate to the Kitaev-limit quantum spin liquid. Its ground state shows no magnetic order or spin freezing as expected for the spin liquid state. However, hydrogen zero-point motion and stacking faults are known to be present. The resulting bond disorder has been invoked to explain the existence of unexpected low-energy spin excitations, although data interpretation remains challenging. Here, we use resonant X-ray spectroscopies to map the collective excitations in H₃LiIr₂O₆and characterize its magnetic state. In the low-temperature correlated state, we reveal a broad bandwidth of magnetic excitations. The central energy and the high-energy tail of the continuum are consistent with expectations for dominant ferromagnetic Kitaev interactions between dynamically fluctuating spins. Furthermore, the absence of a momentum dependence to these excitations are consistent with disorder-induced broken translational invariance. Our low-energy data and the energy and width of the crystal field excitations support an interpretation of H₃LiIr₂O₆as a disordered topological spin liquid in close proximity to bond-disordered versions of the Kitaev quantum spin liquid.

    

   more » « less
4. Topological Quantum Phase Transitions of Anisotropic Antiferromagnetic Kitaev Model Driven by Magnetic Field

   https://doi.org/10.1002/andp.202200012  

   Jia, Shi‐Qing ; Quan, Ya‐Min ; Zou, Liang‐Jian ; Lin, Hai‐Qing ( May 2022 , Annalen der Physik)

   The evolution of quantum spin liquid states (QSL) of the anisotropic antiferromagnetic (AFM) Kitaev model with the [001] magnetic field by utilizing the finite‐temperature Lanczos method (FTLM) is investigated. In this anisotropic Kitaev model with and (K is the energy unit), due to the competition between anisotropy and magnetic field, the system emerges four exotic quantum phase transitions (QPTs) when and , while only two QPTs when . At these magnetic‐field tuning quantum phase transition points, the low‐energy excitation spectrums appear level crossover, and the specific heat, magnetic susceptibility and Wilson ratio display anomalies; accordingly, the topological Chern number may also change. These results demonstrate that the anisotropic interacting Kitaev model with modulating magnetic field displays more rich phase diagrams, in comparison with the isotropic Kitaev model.

    

   more » « less
5. Topological and magnetic phase transitions in the bilayer Kitaev-Ising model

   https://doi.org/10.1103/PhysRevB.109.024439  

   Vijayvargia, Aayush ; Seifert, Urban F. ; Erten, Onur ( January 2024 , Physical Review B)

   We investigate the phase diagram of a bilayer Kitaev honeycomb model with Ising interlayer interactions, deriving effective models via perturbation theory and performing Majorana mean-field theory calculations. We show that a diverse array of magnetic and topological phase transitions occur, depending on the direction of the interlayer Ising interaction and the relative sign of Kitaev interactions. When two layers have the same sign of the Kitaev interaction, a first-order transition from a Kitaev spin liquid to a magnetically ordered state takes place. The magnetic order points along the Ising axis and it is (anti)ferromagnetic for (anti)ferromagnetic Kitaev interactions. However, when two layers have opposite signs of the Kitaev interaction, we observe a notable weakening of magnetic ordering tendencies and the Kitaev spin liquid survives up to a remarkably larger interlayer exchange. Our mean-field analysis suggests the emergence of an intermediate gapped Z2 spin-liquid state, which eventually becomes unstable upon vison condensation. The confined phase is described by a highly frustrated 120∘ compass model. We furthermore use perturbation theory to study the model with the Ising axis pointing along the z axis or lying in the xy plane. In both cases, our analysis reveals the formation of one-dimensional Ising chains, which remain decoupled in perturbation theory, resulting in a subextensive ground-state degeneracy. Our results highlight the interplay between topological order and magnetic ordering tendencies in bilayer quantum spin liquids. 

   more » « less