Abstract We report the oxidative dimerization reaction of siloxydienes derived from simple enones that creates a new gamma‐gamma (γ‐γ) C−C bond using catalytic iron and benzoyl peroxide as the terminal oxidant in acetonitrile solvent at ambient temperature. The reaction shows a broad substrate scope including cyclic and acyclic siloxydienes derived from ketones, aldehydes, and esters, which are converted to 1,8‐dicarbonyl compounds under mild catalytic reaction conditions in 19–89 % yield across 30 examples. The method is suitable for the coupling of sterically demanding carbon centers, including the formation of vicinal quaternary centers. Conceptually, the dienol ether serves as a precursor to a conjugated radical cation, which undergoes highly site selective γ‐dimerization reactions. The γ‐γ dimerization strategy is applied to the synthesis of a bioactive analogue of honokiol.
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Commissioning of the 4$$\pi \,\gamma $$-summing array HECTOR at CASPAR: measurements of $$^{27}\text {Al}$$$$(p,\gamma )$$ $$^{28}\text {Si}$$ resonances 4850 feet underground
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Abstract A search for$${\text {Z}{}{}} {\text {Z}{}{}} $$ and$${\text {Z}{}{}} {\text {H}{}{}} $$ production in the$${\text {b}{}{}} {\bar{{\text {b}{}{}}}{}{}} {\text {b}{}{}} {\bar{{\text {b}{}{}}}{}{}} $$ final state is presented, where H is the standard model (SM) Higgs boson. The search uses an event sample of proton-proton collisions corresponding to an integrated luminosity of 133$$\,\text {fb}^{-1}$$ collected at a center-of-mass energy of 13$$\,\text {Te}\hspace{-.08em}\text {V}$$ with the CMS detector at the CERN LHC. The analysis introduces several novel techniques for deriving and validating a multi-dimensional background model based on control samples in data. A multiclass multivariate classifier customized for the$${\text {b}{}{}} {\bar{{\text {b}{}{}}}{}{}} {\text {b}{}{}} {\bar{{\text {b}{}{}}}{}{}} $$ final state is developed to derive the background model and extract the signal. The data are found to be consistent, within uncertainties, with the SM predictions. The observed (expected) upper limits at 95% confidence level are found to be 3.8 (3.8) and 5.0 (2.9) times the SM prediction for the$${\text {Z}{}{}} {\text {Z}{}{}} $$ and$${\text {Z}{}{}} {\text {H}{}{}} $$ production cross sections, respectively.more » « less
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Abstract Using proton–proton collision data corresponding to an integrated luminosity of$$140\hbox { fb}^{-1}$$ collected by the CMS experiment at$$\sqrt{s}= 13\,\text {Te}\hspace{-.08em}\text {V} $$ , the$${{{\Lambda }} _{\text {b}}^{{0}}} \rightarrow {{\text {J}/\uppsi }} {{{\Xi }} ^{{-}}} {{\text {K}} ^{{+}}} $$ decay is observed for the first time, with a statistical significance exceeding 5 standard deviations. The relative branching fraction, with respect to the$${{{\Lambda }} _{\text {b}}^{{0}}} \rightarrow {{{\uppsi }} ({2\textrm{S}})} {{\Lambda }} $$ decay, is measured to be$$\mathcal {B}({{{\Lambda }} _{\text {b}}^{{0}}} \rightarrow {{\text {J}/\uppsi }} {{{\Xi }} ^{{-}}} {{\text {K}} ^{{+}}} )/\mathcal {B}({{{\Lambda }} _{\text {b}}^{{0}}} \rightarrow {{{\uppsi }} ({2\textrm{S}})} {{\Lambda }} ) = [3.38\pm 1.02\pm 0.61\pm 0.03]\%$$ , where the first uncertainty is statistical, the second is systematic, and the third is related to the uncertainties in$$\mathcal {B}({{{\uppsi }} ({2\textrm{S}})} \rightarrow {{\text {J}/\uppsi }} {{{\uppi }} ^{{+}}} {{{\uppi }} ^{{-}}} )$$ and$$\mathcal {B}({{{\Xi }} ^{{-}}} \rightarrow {{\Lambda }} {{{\uppi }} ^{{-}}} )$$ .more » « less