A phase-field model for thermomechanically-induced fracture in NiTi at the single crystal level, i.e., fracture under loading paths that may take advantage of either of the functional properties of NiTi–superelasticity or shape memory effect–, is presented, formulated within the kinematically linear regime. The model accounts for reversible phase transformation from austenite to martensite habit plane variants and plastic deformation in the austenite phase. Transformation-induced plastic deformation is viewed as a mechanism for accommodation of the local deformation incompatibility at the austenite–martensite interfaces and is accounted for by introducing an interaction term in the free energy derived based on the Mori–Tanaka and Kröner micromechanical assumptions and the hypothesis of martensite instantaneous growth within austenite. Based on experimental observations suggesting that NiTi fractures in a stress-controlled manner, damage is assumed to be driven by the elastic energy, i.e., phase transformation and plastic deformation are assumed to contribute in crack formation and growth indirectly through stress redistribution. The model is restricted to quasistatic mechanical loading (no latent heat effects), thermal loading sufficiently slow with respect to the time rate of heat transfer by conduction (no thermal gradients), and a temperature range below 𝑀𝑑, which is the temperature above which the austenite phase is stable, i.e., stress-induced martensitic transformation is suppressed. The numerical implementation of the model is based on an efficient scheme of viscous regularization in both phase transformation and plastic deformation, an explicit numerical integration via a tangent modulus method, and a staggered scheme for the coupling of the unknown fields. The model is shown able to capture transformation-induced toughening, i.e., stable crack advance attributed to the shielding effect of inelastic deformation left in the wake of the growing crack under nominal isothermal loading, actuation-induced fracture under a constant bias load, and crystallographic dependence on crack pattern.
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Room temperature crack-healing in an atomically layered ternary carbide
Ceramic materials provide outstanding chemical and structural stability at high temperatures and in hostile environments but are susceptible to catastrophic fracture that severely limits their applicability. Traditional approaches to partially overcome this limitation rely on activating toughening mechanisms during crack growth to postpone fracture. Here, we demonstrate a more potent toughening mechanism that involves an intriguing possibility of healing the cracks as they form, even at room temperature, in an atomically layered ternary carbide. Crystals of this class of ceramic materials readily fracture along weakly bonded crystallographic planes. However, the onset of an abstruse mode of deformation, referred to as kinking in these materials, induces large crystallographic rotations and plastic deformation that physically heal the cracks. This implies that the toughness of numerous other layered ceramic materials, whose broader applications have been limited by their susceptibility to catastrophic fracture, can also be enhanced by microstructural engineering to promote kinking and crack-healing.
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- Award ID(s):
- 1944496
- NSF-PAR ID:
- 10330631
- Date Published:
- Journal Name:
- Science Advances
- Volume:
- 7
- Issue:
- 33
- ISSN:
- 2375-2548
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract Hydrogen embrittlement (HE) causes sudden, costly failures of metal components across a wide range of industries. Yet, despite over a century of research, the physical mechanisms of HE are too poorly understood to predict HE-induced failures with confidence. We use non-destructive, synchrotron-based techniques to investigate the relationship between the crystallographic character of grain boundaries and their susceptibility to hydrogen-assisted fracture in a nickel superalloy. Our data lead us to identify a class of grain boundaries with striking resistance to hydrogen-assisted crack propagation: boundaries with low-index planes (BLIPs). BLIPs are boundaries where at least one of the neighboring grains has a low Miller index facet—{001}, {011}, or {111}—along the grain boundary plane. These boundaries deflect propagating cracks, toughening the material and improving its HE resistance. Our finding paves the way to improved predictions of HE based on the density and distribution of BLIPs in metal microstructures.
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Constraints on Element Mobility During Deformation Within the Seismogenic Zone, Shimanto Belt, Japanmore » « less
Abstract Subduction interfaces exhibit a variety of slip behaviors, including megathrust and slow earthquakes. Field observations are consistent with crack‐seal deformation, in which tensile cracks are sealed by fluid‐transported solute. However, there are few constraints on the mass fluxes and length and time scales of such deformation and attendant increases in cohesion within the seismogenic zone. Here, we present a systematic geochemical investigation of mass transport associated with development of crack‐seal veins in the Shimanto Belt—an accretionary complex that preserves a record of plate boundary slip behavior at temperatures relevant to the seismogenic zone: 150–350°C. These mélanges show evidence for shear across decameter‐scale zones of deformation dominated by anastomosing scaly fabrics and pervasive veins. We use meso‐ and microstructural observations with geochemical observations of scaly fabrics and crack‐seal veins to evaluate the role of silica redistribution in healing fracture porosity along the plate interface and modulating slip behavior. Crack‐seal veins contain primarily quartz with albite and calcite, and vein textures provide evidence for partial sealing. Bulk rock analyses determined that the amount of phyllosilicates, specifically illite and chlorite, increases with temperature. A simple mass‐balance model based on the immobile chemical component TiO2shows a systematic trend in mobility for all three mélanges and increased element mobility as a function of temperature. Scaly fabrics and veins show compositional evidence for locally sourced mineral redistribution. This study supports a model where development of scaly slip surfaces and fracture healing through temperature‐dependent mineral redistribution can impact slip behavior and fluid flow along the subduction plate interface.
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Abstract A sealant is required for the solid oxide fuel cell (SOFC) to maintain hermeticity at high operating temperatures, keep fuel and oxidant from mixing, and avoid shorting of the cell stack. Glass and glass–ceramic materials are widely used as a sealant because their properties can be tailored to meet the stringent requirements of SOFC stack, but they are susceptible to cracking. In contrast, a promising concept of self‐repairable glass for seals is pursued for making reliable seals that can self‐repair cracks at the SOFC operating temperatures. This concept is studied through measuring crack‐healing kinetics and independent measurement of glass viscosity for relating to the observed self‐repair. The cracks on the glass surface are created using a Vickers indenter to achieve a well‐defined crack geometry, and then the glass is exposed to elevated temperatures for different length of times to study the crack‐healing kinetics. The crack‐healing kinetics is compared with the predictions of our theoretical model and found to be in good agreement. In addition, glass viscosity is extracted from the healing kinetics and compared with the independent measurement of viscosity measured from the dilatometry and sintering data to further validate the crack‐healing theoretical model. These results are presented and discussed.
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Abstract Sand‐shale mélanges from the Kodiak accretionary complex and Shimanto belt of Japan record deformation during underthrusting along a paleosubduction interface in the range 150 to 350 °C. We use observations from these mélanges to construct a simple kinetic model that estimates the maximum time required to seal a single fracture as a measure of the rate of fault zone healing. Crack sealing involves diffusive redistribution of Si from mudstones with scaly fabric to undersaturated fluid‐filled cracks in sandstone blocks. Two driving forces are considered for the chemical potential gradient that drives crack sealing: (1) a transient drop in fluid pressure
∆P f , and (2) a difference in mean stress between scaly slip surfaces in mudstones and cracks in stronger sandstone blocks. Sealing times are more sensitive to mean stress than∆P f , with up to four orders of magnitude faster sealing. Sealing durations are dependent on crack spacing, silica diffusion kinetics, and magnitude of the strength contrast between block and matrix, each of which is loosely constrained for conditions relevant to the seismogenic zone. We apply the model to three active subduction zones and find that sealing rates are fastest along Cascadia and several orders of magnitude slower for a given depth along Nicaragua and Tohoku slab‐top geotherms. The model provides (1) a framework for geochemical processes that influence subduction mechanics via crack sealing and shear fabric development and (2) demonstration that kinetically driven mass redistribution during the interseismic period is a plausible mechanism for creating asperities along smooth, sediment‐dominated convergent margins.
- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1126/sciadv.abg2549
