More Like this

1. Determining the source of speleothem δ18O variability from in situ measurements of seasonal and inter-annual isotope trends in precipitation, cave drip water and modern calcite from sites in the Central Peruvian Andes

   Olson, E.J. ( December 2022 , American Geophysical Union Conference. Chicago, IL)

   In the past decade, Huagapo and Pacupahuain Caves in the Central Peruvian Andes have become sources of speleothem oxygen isotope (δ18O) paleoclimate records. These studies identify the South American Summer Monsoon (SASM) as the main climate system controlling δ18O variability. While this interpretation is verified through inter-proxy record comparisons on millennial scales, interpretation of the high-resolution variability within these records is limited by a lack of modern proxy calibration studies at these sites. Here we present results from a modern cave monitoring study undertaken to address the controls on the δ18O values of precipitation at these sites and how surface and in-cave processes affect the δ18O value of speleothem calcite. Speleothem calcite δ18O values reflect an integrated signal of atmospheric processes (e.g., rainout, Raleigh distillation, upstream moisture recycling, changes in moisture source), evaporation and mixing during infiltration in the soil and epikarst, and in-cave processes such as degassing and evaporation. In consideration of these factors, we compare isotope trends in precipitation, cave drip water and modern farmed calcite from the two cave sites. We find that precipitationδ18O values during peak monsoon activity (January -February) shows considerable inter-annual variation with averages of -16.7‰ for 2020, -18.5‰ for 2021 and -13.8‰ in 2022. We investigate the source of this variability in regional atmospheric circulation patterns using weather station data and back trajectories. The mean annual precipitation (MAP) from outside Huagapo Cave is δ18O = -15.5+/- 6‰, while seasonal samples of drip water δ18O = -14.5+/- 1‰, are offset from MAP possibly due to evaporation during infiltration. Cave drip waterδ18O has low variability over inter-annual and seasonal timescales indicating homogenization in the epikarst. Using geochemical and sensor data (e.g. cave relative humidity, temperature, and drip rate) as inputs for a karst based forward model, we simulate modern speleothem δ18O to quantitatively assess the combined effects of hydroclimate processes integration to the isotope record. 

   more » « less
2. High‐Resolution Mg/Ca and δ18O Patterns in Modern Neogloboquadrina pachyderma From the Fram Strait and Irminger Sea

   Livsey, C.M. ; Kozdon, R. ; Bauch, D. ; Brummer, G-J A. ; Jonkers, L. ; Orland, I. ; Hill, T. M. ; Spero, H.S. ( January 2020 , Paleoceanography and paleoclimatology)

   Abstract Neogloboquadrina pachyderma is the dominant species of planktonic foraminifera found in polar waters and is therefore invaluable for paleoceanographic studies of the high latitudes. However, the geochemistry of this species is complicated due to the development of a thick calcite crust in its final growth stage and at greater depths within the water column. We analyzed the in situ Mg/Ca and δ18O in discrete calcite zones using laser ablation‐inductively coupled plasma‐mass spectrometry, electron probe microanalysis, and secondary ion mass spectrometry within modern N. pachyderma shells from the highly dynamic Fram Strait and the seasonally isothermal/isohaline Irminger Sea. Here we compare shell geochemistry to the measured temperature, salinity, and δ18Osw in which the shells calcified to better understand the controls on N. pachyderma geochemical heterogeneity. We present a relationship between Mg/Ca and temperature in N. pachyderma lamellar calcite that is significantly different than published equations for shells that contained both crust and lamellar calcite. We also document highly variable secondary ion mass spectrometry δ18O results (up to a 3.3‰ range in single shells) on plankton tow samples which we hypothesize is due to the granular texture of shell walls. Finally, we document that the δ18O of the crust and lamellar calcite of N. pachyderma from an isothermal/isohaline environment are indistinguishable from each other, indicating that shifts in N. pachyderma δ18O are primarily controlled by changes in environmental temperature and/or salinity rather than differences in the sensitivities of the two calcite types to environmental conditions. 

   more » « less
3. Reconstructing Pliocene West Pacific Warm Pool Hydroclimate Using In Situ Microanalyses on Fossil Planktic Foraminifer Shells

   https://doi.org/10.1029/2019PA003772  

   Wycech, J. ; Kelly, D. C. ; Fournelle, J. ; Kitajima, K. ; Kozdon, R. ; Orland, I. J. ( June 2020 , Paleoceanography and Paleoclimatology)

   A controversial aspect of Pliocene (5.3–2.6 Ma) climate is whether El Niño‐like (El Padre) conditions, characterized by a reduced trans‐equatorial sea‐surface temperature (SST) gradient, prevailed across the Pacific. Evidence for El Padre is chiefly based on reconstructions of sea‐surface conditions derived from the oxygen isotope (δ¹⁸O) and Mg/Ca compositions of shells belonging to the planktic foraminiferTrilobatus sacculifer. However, fossil shells of this species are a mixture of multiple carbonate phases—pre‐gametogenic, gametogenic (reproductive), and diagenetic calcites—that formed under different physiological and/or environmental conditions and are averaged in conventional whole‐shell analyses. Through in situ measurements of micrometer‐scale domains within Pliocene‐aged shells ofT. sacculiferfrom Ocean Drilling Program Site 806 in the western equatorial Pacific, we show that the δ¹⁸O of gametogenic calcite is 0.6–0.8‰ higher than pre‐gametogenic calcite, while the Mg/Ca ratios of these two phases are the same. Both the whole‐shell and pre‐gametogenic Mg/Ca records indicate that average early Pliocene SSTs were ~1°C warmer than modern, with present‐day SSTs being established during the latest Pliocene and early Pleistocene (~3.0–2.0 Ma). The measurement of multiple calcite phases by whole‐shell δ¹⁸O analyses masks a late Pliocene to earliest Pleistocene (3.6–2.2 Ma) decrease in seawater δ¹⁸O (δ¹⁸O_sw) values reconstructed from in situ pre‐gametogenic δ¹⁸O and Mg/Ca measurements. Our novel δ¹⁸O_swrecord indicates that sea‐surface salinities in the west Pacific warm pool were higher than modern prior to ~3.5 Ma, which is consistent with more arid conditions under an El Padre state.

    

   more » « less
4. Evidence for Oceans pre-4300 Ma Confirmed by Preserved Igneous Compositions in Hadean Zircon

   https://doi.org/10.2138/am-2023-9180  

   Cameron, Emilia M. ; Blum, Tyler B. ; Cavosie, Aaron J. ; Kitajima, Kouki ; Nasdala, Lutz ; Orland, Ian J. ; Bonamici, Chloe E. ; Valley, John W. ( March 2024 , American Mineralogist)

   Detrital zircons from the Jack Hills are the dominant source of Hadean (pre-4000 Ma) terrestrial material available for study today. Values of δ18O in many of these zircons (6.0 to 7.5‰ are above the mantle-equilibrated value. For two decades, these mildly elevated values have been the primary evidence that protoliths of the zircon-forming magmas interacted at low temperature with liquid water before burial and melting, implying that the surface of Earth cooled quickly after core and moon formation, and that habitable conditions for life existed within 250 Myr of the formation of Earth, over 800 Myr before the oldest generally accepted microfossils. These conclusions are based on oxygen isotope analyses of zircon domains with well-defined growth zoning and nearly concordant U-Pb ages within zircon grains with low magnetic susceptibility, which are further inferred to be unaltered by various tests. However, no studies of Jack Hills zircons have directly correlated oxygen isotope ratios and radiation damage, which facilitates alteration in zircon. Several previous studies have selected zircons that show radiation damaged, discordant and/or hydrous domains, and have shown that such altered material is not reliable as a record of igneous composition. In contrast, this study targeted zircons that are interpreted to pristine and not altered, and demonstrates the importance of testing zircons for radiation damage and alteration as part of any geochemical study, regardless of age. This study expands on existing data, and presents the first comprehensive evaluation of δ18O, OH/O, CL imaging, U-Pb concordance and radiation-damage state within Jack Hills zircons. A total of 115 Hadean zircon grains in this study have water contents similar to nominally anhydrous standard reference zircons and are interpreted as pristine. In situ Raman data for band broadening correlated with δ18O analyses document low levels of radiation damage, indicating significant annealing. The present-day effective doses (Deff) are uniformly less than the first percolation point (dose where damage domains, that are isolated at lower damage state, overlap to form a continuous pathway through the crystal, ~2×1015 α-decays/mg, Ewing et al., 2003) and most zircons have Deff<1×1015 α-decays/mg. Modeling of representative alpha-recoil damage and annealing histories indicates that most zircons in this study have remained below the Deff of the first percolation point throughout their history. The δ18O values for these primary zircons include many that are higher than would be equilibrated with the mantle at magmatic temperatures and average 6.32 ± 1.3‰ in the Hadean and 6.26 ± 1.6‰ in the Archean. There is no correlation in our suite of pristine Hadean zircons between δ18O and OH/O, Deff, age, or U-Pb age-concordance. These carefully documented Hadean-age zircons possess low amounts of radiation damage in domains sampled by δ18O analysis, are water-poor. The mildly elevated δ18O values are a primary-magmatic geochemical signature. These results strengthen the conclusion that mildly elevated-δ18O magmas existed during the Hadean, supporting the hypothesis that oceans and a habitable Earth existed before 4300 Ma.

    

   more » « less
5. Origin of blocky aragonite cement in Cenozoic glaciomarine sediments, McMurdo Sound, Antarctica

   https://doi.org/10.1111/sed.12690  

   Yang, Mingyu ; Frank, Tracy D. ; Fielding, Christopher R. ; Smith, Megan E. ; Swart, Peter K. ; Reijmer, ed., John ( December 2019 , Sedimentology)

   Inorganic aragonite occurs in a wide spectrum of depositional environments and its precipitation is controlled by complex physio‐chemical factors. This study investigates diagenetic conditions that led to aragonite cement precipitation in Cenozoic glaciomarine deposits of McMurdo Sound, Antarctica. A total of 42 sandstones that host intergranular cement were collected from theCIROS‐1 core, located proximal to the terminus of Ferrar Glacier. Standard petrography, Raman spectroscopy and electron microprobe analysis reveal a prominent aragonite cement phase that occurs as a pore‐filling blocky fabric throughout the core. Oxygen isotope compositions (δ¹⁸O = −30·0 to −8·6‰ Vienna Pee‐Dee Belemnite) and clumped isotope temperatures (TΔ₄₇ = 13·1 to 31·5°C) determined from the aragonite cements provide precise constraints on isotopic compositions (δ¹⁸O_w) of the parent fluid, which mostly range from −10·8 to −7·2‰ Vienna Standard Mean Ocean Water. The fluidδ¹⁸O_wvalues are consistent with those of pore water, previously identified as cryogenic brine in the nearbyAND‐2A core. Petrographic and geochemical data suggest that aragonite cement in theCIROS‐1 core precipitated from a similar brine. The brine likely formed and infiltrated sediments in flooded glacial valleys along the western margin of McMurdo Sound during the middle Miocene Climatic Transition, and subsequently flowed basinward in the subsurface. Consequently, the brine forms as a longstanding subsurface fluid that has saturated Cenozoic sediments below southern McMurdo Sound since at least the middle Miocene. Aragonite cementation in theCIROS‐1 core is interpreted to reflect its proximal position to sites of brine formation and greater likelihood of experiencing brines with sustained high carbonate saturation states and Mg/Ca ratios. This unusual occurrence expands the range of known natural occurrences of aragonite cement. Given the potential for cryogenic brine formation in glaciomarine settings, blocky aragonite, as the end member of the spectrum of aragonite cement morphology, may be more widespread in glaciomarine sediments than currently thought.

    

   more » « less