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1. Water accelerated self-healing of hydrophobic copolymers

   https://doi.org/10.1038/s41467-020-19405-5  

   Davydovich, Dmitriy; Urban, Marek W. (December 2020, Nature Communications)

   null (Ed.)

   Abstract Previous studies have shown that copolymer compositions can significantly impact self-healing properties. This was accomplished by enhancement of van der Waals (vdW) forces which facilitate self-healing in relatively narrow copolymer compositional range. In this work we report the acceleration of self-healing in alternating/random hydrophobic acrylic-based copolymers in the presence of confined water molecules. Under these conditions competing vdW interactions do not allow H 2 O-diester H-bonding, thus forcing nBA side groups to adapt L-shape conformations, generating stronger dipole-dipole interactions resulting in shorter inter-chain distances compared to ‘key-and-lock’ associations without water. The perturbation of vdW forces upon mechanical damage in the presence of controllable amount of confined water is energetically unfavorable leading the enhancement of self-healing efficiency of hydrophobic copolymers by a factor of three. The concept may be applicable to other self-healing mechanisms involving reversible covalent bonding, supramolecular chemistry, or polymers with phase-separated morphologies. 

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2. Aggregation and gelation in a tunable aqueous colloid–polymer bridging system

   https://doi.org/10.1063/5.0101697  

   Gallegos, Mariah J.; Soetrisno, Diego D.; Park, Nayoung; Conrad, Jacinta C. (September 2022, The Journal of Chemical Physics)

   We report a colloid–polymer model system with tunable bridging interactions for microscopic studies of structure and dynamics using confocal imaging. The interactions between trifluoroethyl methacrylate-co-tert-butyl methacrylate copolymer particles and poly(acrylic acid) (PAA) polymers were controllable via polymer concentration and pH. The strength of adsorption of PAA on the particles, driven by pH-dependent interactions with polymer brush stabilizers on the particle surfaces, was tuned via solution pH. Particle–polymer suspensions formulated at low pH, where polymers strongly adsorbed to the particles, contained clusters or weak gels at particle volume fractions of ϕ = 0.15 and ϕ = 0.40. At high pH, where the PAA only weakly adsorbed to the particle surface, particles largely remained dispersed, and the suspensions behaved as a dense fluid. The ability to visualize the suspension structure is likely to provide insight into the role of polymer-driven bridging interactions in the behavior of colloidal suspensions. 

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3. DK Lock: Dual Key Logic Locking Against Oracle-Guided Attacks

   https://doi.org/10.1109/ISQED57927.2023.10129368  

   Maynard, Jordan; Rezaei, Amin (April 2023, Proceedings of International Symposium on Quality Electronic Design (ISQED))

   The semiconductor industry must deal with different hardware threats like piracy and overproduction as a result of outsourcing manufacturing. While there are many proposals to lock the circuit using a global protected key only known to the designer, there exist numerous oracle-guided attacks that can examine the locked netlist with the assistance of an activated IC and extract the correct key. In this paper, by adopting a low-overhead structural method, we propose DK Lock, a novel Dual Key locking method that securely protects sequential circuits with two different keys that are applied to one set of key inputs at different times. DK Lock structurally adds an activation phase to the sequential circuit, and a correct key must be applied for several cycles to exit this phase. Once the circuit has been successfully activated, a new functional key must be applied to the same set of inputs to resume normal operation. DK Lock opens up new avenues for hardware IP protection by simultaneously refuting the single static key assumption of the existing attacks and overcoming the state explosion problem of state-of-the-art sequential logic locking methods. Our experiments confirm that DK Lock maintains a high degree of security with reasonable power and area overheads. 

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4. DNA self-organization controls valence in programmable colloid design

   https://doi.org/10.1073/pnas.2112604118  

   McMullen, Angus; Hilgenfeldt, Sascha; Brujic, Jasna (November 2021, Proceedings of the National Academy of Sciences)

   Just like atoms combine into molecules, colloids can self-organize into predetermined structures according to a set of design principles. Controlling valence—the number of interparticle bonds—is a prerequisite for the assembly of complex architectures. The assembly can be directed via solid “patchy” particles with prescribed geometries to make, for example, a colloidal diamond. We demonstrate here that the nanoscale ordering of individual molecular linkers can combine to program the structure of microscale assemblies. Specifically, we experimentally show that covering initially isotropic microdroplets withNmobile DNA linkers results in spontaneous and reversible self-organization of the DNA intoZ(N) binding patches, selecting a predictable valence. We understand this valence thermodynamically, deriving a free energy functional for droplet–droplet adhesion that accurately predicts the equilibrium size of and molecular organization within patches, as well as the observed valence transitions withN. Thus, microscopic self-organization can be programmed by choosing the molecular properties and concentration of binders. These results are widely applicable to the assembly of any particle with mobile linkers, such as functionalized liposomes or protein interactions in cell–cell adhesion. 

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5. Computing Motion Plans for Assembling Particles with Global Control

   https://doi.org/10.1109/IROS55552.2023.10341556  

   Blumenberg, Patrick; Schmidt, Arne; Becker, Aaron T. (October 2023, 2023 IEEE/RSJ International Conference on Intelligent Robots and Systems (IROS))

   We investigate motion planning algorithms for the assembly of shapes in the tilt model in which unit-square tiles move in a grid world under the influence of uniform external forces and self-assemble according to certain rules. We provide several heuristics and experimental evaluation of their success rate, solution length, and runtime. Video: https://youtu.be/VU1SZYzeaXw Transcript: This animation shows colored tiles moved by a global signal so they all move in the same direction unless blocked. This simple example is solved using the Greatest Distance heuristic, which finds the shortest path in 21 steps. Each tile has glue on the four sides that only stick to compatible glues. Glue type is denoted by color. The objective is to manipulate the tiles to bond in the shape of the connected polyomino target outlined in red. The Polyomino Assembly Problem is PSPACE-hard, so optimal solutions are difficult to find. This more complicated workspace was solved using the Minimum Move to Polyomino or Target. This approach is not optimal, but is a best-first search that attempts to keep tiles not involved in the present construction step separated from each other. This is done by pruning configurations with undesired subassemblies from the search tree. The solution requires 473 steps. 

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