When a colloidal suspension is dried, capillary pressure may overwhelm repulsive electrostatic forces, assembling aggregates that are out of thermal equilibrium. This poorly understood process confers cohesive strength to many geological and industrial materials. Here we observe evaporation-driven aggregation of natural and synthesized particulates, probe their stability under rewetting, and measure bonding strength using an atomic force microscope. Cohesion arises at a common length scale (∼5 μm), where interparticle attractive forces exceed particle weight. In polydisperse mixtures, smaller particles condense within shrinking capillary bridges to build stabilizing “solid bridges” among larger grains. This dynamic repeats across scales, forming remarkably strong, hierarchical clusters, whose cohesion derives from grain size rather than mineralogy. These results may help toward understanding the strength and erodibility of natural soils, and other polydisperse particulates that experience transient hydrodynamic forces.
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Particle segregation in falling polydisperse suspension droplets
The problem of a suspension droplet falling under gravity was examined for polydisperse droplets composed of a mixture of particles with different densities and sizes. The study was conducted using both simulations based on oseenlet particle interactions and laboratory experiments. The hydrodynamic interactions of the particles within the suspension droplet allow a polydisperse collection of particles to fall as a coherent droplet, even for cases where the difference in particle terminal velocity would cause them to separate quickly from each other in the absence of hydrodynamic interactions. However, a gradual segregation phenomenon is observed in which particles with lower terminal velocity preferentially leave the suspension droplet by entering into the droplet tail, whereas particles with higher terminal velocity remain for longer periods of time within the droplet. When computations and experiments are performed for bidisperse mixtures, a point is eventually reached where all of the lighter/smaller particles are ejected into the droplet tail and the droplet continues to fall with only the heavier/larger particles.
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- Award ID(s):
- 1144388
- NSF-PAR ID:
- 10343142
- Date Published:
- Journal Name:
- Journal of Fluid Mechanics
- Volume:
- 769
- ISSN:
- 0022-1120
- Page Range / eLocation ID:
- 79 to 102
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1017/jfm.2015.111
