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1. Zircon (U-Th)/He thermochronology of Grand Canyon resolves 1250 Ma unroofing at the Great Unconformity and <20 Ma canyon carving

   https://doi.org/10.1130/G48699.1  

   Thurston, Olivia G.; Guenthner, William R.; Karlstrom, Karl E.; Ricketts, Jason W.; Heizler, Matthew T.; Timmons, J. Michael (November 2021, Geology)

   Abstract Our study used zircon (U-Th)/He (ZHe) thermochronology to resolve cooling events of Precambrian basement below the Great Unconformity surface in the eastern Grand Canyon, United States. We combined new ZHe data with previous thermochronometric results to model the <250 °C thermal history of Precambrian basement over the past >1 Ga. Inverse models of ZHe date-effective uranium (eU) concentration, a relative measure of radiation damage that influences closure temperature, utilize He diffusion and damage annealing and suggest that the main phase of Precambrian cooling to <200 °C was between 1300 and 1250 Ma. This result agrees with mica and potassium feldspar 40Ar/39Ar thermochronology showing rapid post–1400 Ma cooling, and both are consistent with the 1255 Ma depositional age for the Unkar Group. At the young end of the timescale, our data and models are also highly sensitive to late-stage reheating due to burial beneath ∼3–4 km of Phanerozoic strata prior to ca. 60 Ma; models that best match observed date-eU trends show maximum temperatures of 140–160 °C, in agreement with apatite (U-Th)/He and fission-track data. Inverse models also support multi-stage Cenozoic cooling, with post–20 Ma cooling from ∼80 to 20 °C reflecting partial carving of the eastern Grand Canyon, and late rapid cooling indicated by 3–7 Ma ZHe dates over a wide range of high eU. Our ZHe data resolve major basement exhumation below the Great Unconformity during the Mesoproterozoic (1300–1250 Ma), and “young” (20–0 Ma) carving of Grand Canyon, but show little sensitivity to Neoproterozoic and Cambrian basement unroofing components of the composite Great Unconformity. 

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2. Deep-time thermal history of the Great Unconformity in the Grand Canyon, USA: Combined zircon (U-Th)/He and K-feldspar 40Ar/39Ar thermochronometers

   https://doi.org/10.1130/B37358.1  

   Thurston, OG; Guenthner, WR; Karlstrom, KE; Heizler, MT; Ricketts, JW; McDannell, KT (May 2024, Geological Society of America Bulletin)

   Deep-time thermochronology by the zircon (U-Th)/He (ZHe) method is an emerging field of study with promise for constraining Precambrian rock thermal and exhumation histories. The Grand Canyon provides an opportunity to further explore this method because excellent geologic constraints can be integrated with multiple thermochronometers to address important questions about the spatial variability of basement erosion below the sub-Cambrian Great Unconformity composite erosional surface. In this study, we synthesize new ZHe results (n = 26) and published (n = 77) ZHe data with new K-feldspar 40Ar/39Ar data and models (n = 4) from Precambrian basement rocks of the Grand Canyon, USA. We use HeFTy and QTQt thermal history modeling to evaluate the ability of the individual ZHe and K-feldspar 40Ar/39Ar thermochronometric data sets to resolve Precambrian thermal histories and compare those results with jointly modeled data using the QTQt software. We also compare Precambrian basement thermal histories of the eastern and western Grand Canyon, where the eastern Grand Canyon has ∼4 km of Grand Canyon Supergroup strata deposited and preserved, and the western Grand Canyon, where the Supergroup was either never deposited or not preserved. In all locations, models constrained only by ZHe data have limited resolving power for the past ∼600 m.y., compared to models that combine K-feldspar 40Ar/39Ar and ZHe data, which extends the recorded history into the Mesoproterozoic. Our model results suggest that two regional basement unroofing events occurred. A ca. 1350−1250 Ma cooling event is interpreted to record basement exhumation from depths of ∼10 km, and a second cooling episode (∼200−100 °C total) records exhumation from a depth of ∼3 km to 7 km to near-surface conditions between ca. 600 Ma and 500 Ma. Easternmost Grand Canyon models suggest that the preserved maximum ∼4 km thickness of the Grand Canyon Supergroup (with burial heating at ∼100 °C) approximates the total original Mesoproterozoic and Neoproterozoic stratal thickness. Whether these Supergroup rocks were present and then eroded in the western Grand Canyon, as suggested by regional geologic studies, or were never deposited is not constrained by thermochronological data. 

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3. Thermochronologic constraints on the origin of the Great Unconformity

   https://doi.org/10.1073/pnas.2118682119  

   McDannell, Kalin T.; Keller, C. Brenhin; Guenthner, William R.; Zeitler, Peter K.; Shuster, David L. (February 2022, Proceedings of the National Academy of Sciences)

   The origin of the phenomenon known as the Great Unconformity has been a fundamental yet unresolved problem in the geosciences for over a century. Recent hypotheses advocate either global continental exhumation averaging 3 to 5 km during Cryogenian (717 to 635 Ma) snowball Earth glaciations or, alternatively, diachronous episodic exhumation throughout the Neoproterozoic (1,000 to 540 Ma) due to plate tectonic reorganization from supercontinent assembly and breakup. To test these hypotheses, the temporal patterns of Neoproterozoic thermal histories were evaluated for four North American locations using previously published medium- to low-temperature thermochronology and geologic information. We present inverse time–temperature simulations within a Bayesian modeling framework that record a consistent signal of relatively rapid, high-magnitude cooling of ∼120 to 200 ° C interpreted as erosional exhumation of upper crustal basement during the Cryogenian. These models imply widespread, synchronous cooling consistent with at least ∼3 to 5 km of unroofing during snowball Earth glaciations, but also demonstrate that plate tectonic drivers, with the potential to cause both exhumation and burial, may have significantly influenced the thermal history in regions that were undergoing deformation concomitant with glaciation. In the cratonic interior, however, glaciation remains the only plausible mechanism that satisfies the required timing, magnitude, and broad spatial pattern of continental erosion revealed by our thermochronological inversions. To obtain a full picture of the extent and synchroneity of such erosional exhumation, studies on stable cratonic crust below the Great Unconformity must be repeated on all continents. 

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4. Cryogenian glacial erosion of the central Canadian Shield: The “late” Great Unconformity on thin ice

   https://doi.org/10.1130/G50315.1  

   McDannell, Kalin T.; Keller, C. Brenhin (September 2022, Geology)

   Abstract The Great Unconformity has been recognized for more than a century, but only recently have its origins become a subject of debate. Hypotheses suggest global Snowball Earth glaciations and tectonic processes associated with the supercontinent Rodinia as drivers of widespread kilometer-scale erosion in the late Neoproterozoic. We present new integrated zircon and apatite (U-Th)/He and fission-track thermochronology from Precambrian basement samples of the central Canadian Shield in northern Manitoba to test these ideas. Bayesian inverse modeling indicates that 150–200 °C of cooling (>3 km of exhumation) occurred simultaneously with Cryogenian glaciations at ca. 690–650 Ma within interior North America. This estimate for the timing of unroofing is more precise than previous appraisals and does not align with any known tectonic or magmatic events (i.e., large igneous province eruptions) potentially associated with the supercontinent cycle that occurred during the late Proterozoic along the Laurentian margins. Based on these results and interpretations, the timing and magnitude of exhumation is best explained by glacial erosion, and further establishes the importance of multiple thermochronometers for resolving detailed deeptime thermal histories. 

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5. Cenozoic tectono-thermal history of the southern Talkeetna Mountains, Alaska: Insights into a potentially alternating convergent and transform plate margin

   https://doi.org/doi.org/10.1130/GES02008.1  

   Terhune, P.; Benowitz, J.; O'Sullivan, P.; Gillis, R.; Freymuller, J. (January 2019, Geosphere)

   The Mesozoic–Cenozoic convergent margin history of southern Alaska has been dominated by arc magmatism, terrane accretion, strike-slip fault systems, and possible spreading-ridge subduction. We apply 40Ar/39Ar, apatite fission-track (AFT), and apatite (U-Th)/He (AHe) geochronology and thermochronology to plutonic and volcanic rocks in the southern Talkeetna Mountains of Alaska to document regional magmatism, rock cooling, and inferred exhumation patterns as proxies for the region’s deformation history and to better delineate the overall tectonic history of southern Alaska. High-temperature 40Ar/39Ar thermochronology on muscovite, biotite, and K-feldspar from Jurassic granitoids indicates postemplacement (ca. 158–125 Ma) cooling and Paleocene (ca. 61 Ma) thermal resetting. 40Ar/39Ar whole-rock volcanic ages and 45 AFT cooling ages in the southern Talkeetna Mountains are predominantly Paleocene–Eocene, suggesting that the mountain range has a component of paleotopography that formed during an earlier tectonic setting. Miocene AHe cooling ages within ~10 km of the Castle Mountain fault suggest ~2–3 km of vertical displacement and that the Castle Mountain fault also contributed to topographic development in the Talkeetna Mountains, likely in response to the flat-slab subduction of the Yakutat microplate. Paleocene–Eocene volcanic and exhumation-related cooling ages across southern Alaska north of the Border Ranges fault system are similar and show no S-N or W-E progressions, suggesting a broadly synchronous and widespread volcanic and exhumation event that conflicts with the proposed diachronous subduction of an active west-east–sweeping spreading ridge beneath south-central Alaska. To reconcile this, we propose a new model for the Cenozoic tectonic evolution of southern Alaska. We infer that subparallel to the trench slab breakoff initiated at ca. 60 Ma and led to exhumation, and rock cooling synchronously across south-central Alaska, played a primary role in the development of the southern Talkeetna Mountains, and was potentially followed by a period of southern Alaska transform margin tectonics. 

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