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Hypothesis: Surface tension gradient driven Marangoni flows originating from multiple sources are important to many industrial and medical applications, but the theoretical literature focuses on single surfactant sources. Understanding how two spreading surfactant sources interact allows insights from single source experiments to be applied to multi-source applications. Two key features of multi-source spreading – source translation and source deformation – can be explained by transport modeling of a two-source system. Modeling: Numerical simulations of two oleic acid disks placed at varying initial separation distances on a glycerol subphase were performed using COMSOL Multiphysics and compared to spreading of a single surfactant source. Findings: Interaction of two spreading sources can be split into three regimes: the independent regime – where each source is unaffected by the other, the interaction regime – where the presence of a second source alters one or more features of the spreading dynamics, and the quasi-one disk regime – where the two sources merge together. The translation of the sources, manifested as increasing separation distance between disk centers of mass, is driven by the flow fields within the subphase and the resultant surface deformation, while deformation of the sources occurs only once the surfactant fronts of the two sources meet.
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urfactant Spreading on a Deep Subphase: Coupling of Marangoni Flow and Capillary Waves
Abstract Hypothesis Surfactant-driven Marangoni spreading generates a fluid flow characterized by an outwardly moving “Marangoni ridge”. Spreading on thin and/or high viscosity subphases, as most of the prior literature emphasizes, does not allow the formation of capillary waves. On deep, low viscosity subphases, Marangoni stresses may launch capillary waves coupled with the Marangoni ridge, and new dependencies emerge for key spreading characteristics on surfactant thermodynamic and kinetic properties. Experiments and modeling Computational and physical experiments were performed using a broad range of surfactants to report the post-deposition motion of the surfactant front and the deformation of the subphase surface. Modeling coupled the Navier-Stokes and advective diffusion equations with an adsorption model. Separate experiments employed tracer particles or an optical density method to track surfactant front motion or surface deformation, respectively. Findings Marangoni stresses on thick subphases induce capillary waves, the slowest of which is co-mingled with the Marangoni ridge. Changing Marangoni stresses by varying the surfactant system alters the surfactant front velocity and the amplitude – but not the velocity – of the slowest capillary wave. As spreading progresses, the surfactant front and its associated surface deformation separate from the slowest moving capillary wave.
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- Award ID(s):
- 1921285
- PAR ID:
- 10347394
- Date Published:
- Journal Name:
- Journal of colloid and interface science
- Volume:
- 614
- ISSN:
- 1095-7103
- Page Range / eLocation ID:
- 511-521
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/doi.org/10.1016/j.jcis.2022.01.142
