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1. Perspective on functional metal-oxide plasmonic metastructures

   https://doi.org/10.1063/5.0134141  

   Sadeghi, Seyed M. ; Wing, Waylin J. ; Gutha, Rithvik R. ( February 2023 , Journal of Applied Physics)

   Plasmonic nanostructures and metasurfaces are appealing hosts for investigation of novel optical devices and exploration of new frontiers in physical/optical processes and materials research. Recent studies have shown that these structures hold the promise of greater control over the optical and electronic properties of quantum emitters, offering a unique horizon for ultra-fast spin-controlled optical devices, quantum computation, laser systems, and sensitive photodetectors. In this Perspective, we discuss how heterostructures consisting of metal oxides, metallic nanoantennas, and dielectrics can offer a material platform wherein one can use the decay of plasmons and their near fields to passivate the defect sites of semiconductor quantum dots while enhancing their radiative decay rates. Such a platform, called functional metal-oxide plasmonic metasubstrates (FMOPs), relies on formation of two junctions at very close vicinity of each other. These include an Au/Si Schottky junction and an Si/Al oxide charge barrier. Such a double junction allows one to use hot electrons to generate a field-passivation effect, preventing migration of photo-excited electrons from quantum dots to the defect sites. Prospects of FMOP, including impact of enhancement exciton–plasmon coupling, collective transport of excitation energy, and suppression of quantum dot fluorescence blinking, are discussed.

    

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2. Plasmonic Hot‐Electron‐Induced Control of Emission Intensity and Dynamics of Visible and Infrared Semiconductor Quantum Dots

   https://doi.org/10.1002/admi.201901998  

   Sadeghi, Seyed M. ; Gutha, Rithvik R. ; Mao, Chuanbin ( April 2020 , Advanced Materials Interfaces)

   Plasmonic hot‐electron‐assisted control of emission intensities and dynamics of CdSe/ZnS and infrared PbS quantum dots are studied. This is done by exploring the impact of Au/Si and Ag/Si Schottky junctions on the decay rates of such quantum dots when these junctions are placed in close vicinity of a Si/Al oxide charge barrier, forming metal‐oxide plasmonic metafilms. Such structures are used to investigate how metal‐dependent distributions of hot electrons and their capture via Schottky junctions can lead to suppression of the defect environments of quantum dots, offering a novel platform wherein off‐resonant (non‐Purcell) plasmonic processes are used to control exciton dynamics. These results show that Ag metafilms can enhance the emission of CdSe/ZnS quantum dots and elongate their lifetimes more than Au metafilms. This highlights the more efficient nature of Ag/Si Schottky junctions for hot electron excitation and capture. These results also show that such junctions can significantly suppress the nonradiative decay rates of PbS quantum dots at frequencies far from the plasmon resonances. These results demonstrate a field‐effect passivation of quantum dot defects via entrapment of hot electrons and control of emission intensities and dynamics of quantum dots via the nearly frequency‐independent electrostatic field of such electrons.

    

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3. Geometrically Tunable Beamed Light Emission from a Quantum‐Dot Ensemble Near a Gradient Metasurface

   https://doi.org/10.1002/adom.201901951  

   Wang, Xiaowei ; Li, Yuyu ; Toufanian, Reyhaneh ; Kogos, Leonard C. ; Dennis, Allison M. ; Paiella, Roberto ( February 2020 , Advanced Optical Materials)

   Optical metasurfaces have been widely investigated in recent years as a means to tailor the wavefronts of externally incident light for passive device applications. At the same time, their use in active optoelectronic devices such as light emitters is far less established. This work explores their ability to control the radiation properties of a nearby continuous ensemble of randomly oriented incoherent dipole sources via near‐field interactions. Specifically, a film of colloidal quantum dots is deposited on a plasmonic metasurface consisting of a 1D array of metallic nanoantennas on a metal film. The array is designed to introduce a linear phase profile upon reflection, and a bi‐periodic nanoparticle arrangement is introduced to ensure adequate sampling of the desired phase gradient. Highly directional radiation patterns are correspondingly obtained from the quantum dots at an enhanced emission rate. The underlying radiation mechanism involves the near‐field excitation of surface plasmon polaritons at the metal film, and their selective diffractive scattering by the metasurface into well‐collimated beams along predetermined geometrically tunable directions. These results underscore the distinctive ability of metasurfaces to control radiation properties directly at the source level, which is technologically significant for the continued miniaturization and large‐scale integration of optoelectronic devices.

    

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4. Plasmonic metasurface superscatters driven by infrared surface lattice resonances

   https://doi.org/10.1063/5.0159295  

   Sadeghi, Seyed M. ; Roberts, Dustin T. ; Knox, Harrison ; Gutha, Rithvik R. ( July 2023 , Applied Physics Letters)

   We have demonstrated that plasmonic metasurfaces composed of arrays of Au bowtie nanoantennas can support an infrared bidirectional superscattering state. This state arises when the nanoantennas are coherently coupled together, forming a surface lattice resonance that efficiently guides the infrared range (1–1.6 μm) of incident broadband white light along the plane of the arrays. This process exhibits strong polarization dependence, offering an “OFF” state where a 90° rotation of the incident light polarization effectively suppresses in-plane scattering from all sides. Stokes parameters analysis is used to study the states of polarization of the scattering, demonstrating transformation into a complete depolarized state. The results emphasize the significant influence of the multipolar modes of these nanoantennas on the interference processes associated with such scattering phenomena, and their potential applications in polarization optical switching and unique beamsplitting.

    

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5. Broadband control of flow of light using plasmonic metasurfaces consisting of arrays of metallic split ring nanoantennas

   https://doi.org/10.1063/5.0155031  

   Sadeghi, Seyed M. ; Roberts, Dustin T. ; Knox, Harrison ; Gutha, Rithvik R. ( June 2023 , Journal of Applied Physics)

   When a metallic U-shaped nanoantenna (split ring resonator) is observed from its sides, variations in the viewing angle can lead to significantly different size and shape projections. In this study, we demonstrate that plasmonic metasurfaces consisting of arrays of such nanoantennas can support unique side (in-plane) scattering switching and routing processes. These processes encompass a polarization switching centered at 1.6 μm, which is driven by the coherent excitation of the nanoantennas’ multipolar modes. They also include spectrally broadband (0.5–1.6 μm) directional control of the flow of in-plane light scattering. Such a process includes a total prohibition of light emerging from one side of the metasurface for a given polarization of the incident light. However, when such polarization is rotated by 90°, the flow of the in-plane scattering opens with high efficiency. We further discuss the impact of the formation of surface lattice resonance on the coherent amplification of infrared scattering around 1.6 μm and its switching process. The results underscore the influence of variations in asymmetry, associated with the sizes and shape projections, on interference processes. They also showcase how in-plane scattering has the capacity to transfer distinct characteristics of plasmonic near-field asymmetries induced by optical fields into far-field scattering.

    

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