Assembling different shaped particles into ordered microstructures is an open challenge in creating multifunctional particle-based materials and devices. Here, we report the two-dimensional (2D) AC electric field mediated assembly of different shaped colloidal particles into amorphous, liquid crystalline, and crystalline microstructures. Particle shapes investigated include disks, ellipses, squares, and rectangles, which show how systematic variations in anisotropy and corner curvature determine the number and type of resulting microstructures. AC electric fields induce dipolar interactions to control particle positional and orientational order. Microstructural states are determined via particle tracking to compute order parameters, which agree with computer simulations and show how particle packing and dipolar interactions together produce each structure. Results demonstrate how choice of particle shape and field conditions enable kinetically viable routes to assemble nematic, tetratic, and smectic liquid crystal structures as well as crystals with stretched 4- and 6-fold symmetry. Results show it is possible to assemble all corresponding hard particle phases, but also show how dipolar interactions influence and produce additional microstructures. Our findings provide design rules for the assembly of diverse microstructures of different shaped particles in AC electric fields, which could enable scalable and reconfigurable particle-based materials, displays, and printing technologies.
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Hard superellipse phases: particle shape anisotropy & curvature
We report computer simulations of two-dimensional convex hard superellipse particle phases vs. particle shape parameters including aspect ratio, corner curvature, and sidewall curvature. Shapes investigated include disks, ellipses, squares, rectangles, and rhombuses, as well as shapes with non-uniform curvature including rounded squares, rounded rectangles, and rounded rhombuses. Using measures of orientational order, order parameters, and a novel stretched bond orientational order parameter, we systematically identify particle shape properties that determine liquid crystal and crystalline phases including their coarse boundaries and symmetry. We observe phases including isotropic, nematic, tetratic, plastic crystals, square crystals, and hexagonal crystals (including stretched variants). Our results catalog known benchmark shapes, but include new shapes that also interpolate between known shapes. Our results indicate design rules for particle shapes that determine two-dimensional liquid, liquid crystalline, and crystalline microstructures that can be realized via particle assembly.
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- Award ID(s):
- 1928950
- NSF-PAR ID:
- 10353590
- Date Published:
- Journal Name:
- Soft Matter
- Volume:
- 18
- Issue:
- 6
- ISSN:
- 1744-683X
- Page Range / eLocation ID:
- 1319 to 1330
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/D1SM01523K
