skip to main content


Title: Nitride‐Oxide‐Metal Heterostructure with Self‐Assembled Core–Shell Nanopillar Arrays: Effect of Ordering on Magneto‐Optical Properties
Abstract

Magneto‐optical (MO) coupling incorporates photon‐induced change of magnetic polarization that can be adopted in ultrafast switching, optical isolators, mode convertors, and optical data storage components for advanced optical integrated circuits. However, integrating plasmonic, magnetic, and dielectric properties in one single material system poses challenges since one natural material can hardly possess all these functionalities. Here, co‐deposition of a three‐phase heterostructure composed of a durable conductive nitride matrix with embedded core–shell vertically aligned nanopillars, is demonstrated. The unique coupling between ferromagnetic NiO core and atomically sharp plasmonic Au shell enables strong MO activity out‐of‐plane at room temperature. Further, a template growth process is applied, which significantly enhances the ordering of the nanopillar array. The ordered nanostructure offers two schemes of spin polarization which result in stronger antisymmetry of Kerr rotation. The presented complex hybrid metamaterial platform with strong magnetic and optical anisotropies is promising for tunable and modulated all‐optical‐based nanodevices.

 
more » « less
Award ID(s):
2016453 1565822
NSF-PAR ID:
10362254
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  ;  ;  ;  ;  ;  ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
Small
Volume:
17
Issue:
5
ISSN:
1613-6810
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Surface plasmon polaritons (SPPs) are traditionally excited by plane waves within the Rayleigh range of a focused transverse-magnetic (TM) Gaussian beam. Here we investigate and confirm the coupling between SPPs and two-dimensional Gaussian and Bessel–Gauss wave packets, as well as one-dimensional light sheets and space-time wave packets. We encode the incoming wavefronts with spatially varying states of polarization; then we couple the respective TM components of radial and azimuthal vector beam profiles to confirm polarization-correlation and spatial-mode selectivity. Our results do not require material optimization or multi-dimensional confinement via periodically corrugated metal surfaces to achieve coupling at a greater extent, hereby outlining a pivotal, yet commonly overlooked, path towards the development of long-range biosensors and all-optical integrated plasmonic circuits.

     
    more » « less
  2. Abstract

    Plasmonic nanoparticles that can be manipulated with magnetic fields are of interest for advanced optical applications, diagnostics, imaging, and therapy. Alignment of gold nanorods yields strong polarization‐dependent extinction, and use of magnetic fields is appealing because they act through space and can be quickly switched. In this work, cationic polyethyleneimine‐functionalized superparamagnetic Fe3O4nanoparticles (NPs) are deposited on the surface of anionic gold nanorods coated with bovine serum albumin. The magnetic gold nanorods (MagGNRs) obtained through mixing maintain the distinct optical properties of plasmonic gold nanorods that are minimally perturbed by the magnetic overcoating. Magnetic alignment of the MagGNRs arising from magnetic dipolar interactions on the anisotropic gold nanorod core is comprehensively characterized, including structural characterization and enhancement (suppression) of the longitudinal surface plasmon resonance and suppression (enhancement) of the transverse surface plasmon resonance for light polarized parallel (orthogonal) to the magnetic field. The MagGNRs can also be driven in rotating magnetic fields to rotate at frequencies of at least 17 Hz. For suitably large gold nanorods (148 nm long) and Fe3O4NPs (13.4 nm diameter), significant alignment is possible even in modest (<500 Oe) magnetic fields. An analytical model provides a unified understanding of the magnetic alignment of MagGNRs.

     
    more » « less
  3. Instantaneous control over the orientation of anisotropically shaped plasmonic nanostructures allows for selective excitation of plasmon modes and enables dynamic tuning of the plasmonic properties. Herein we report the synthesis of rod-shaped magnetic/plasmonic core-shell nanocomposite particles and demonstrate the active tuning of their optical property by manipulating their orientation using an external magnetic field. We further design and construct an IR-photoelectric coupling system, which generates an output voltage depending on the extinction property of the measured nanocomposite sample. We employ the device to demonstrate that the nanocomposite particles can serve as units for information encryption when immobilized in a polymer film and additionally when dispersed in solution can be employed as a new type of magnetic-field-direction sensor. 
    more » « less
  4. Abstract

    Over the past decades, optical manipulation of magnetization by ultrafast laser pulses has attracted extensive interest. It not only shows intriguing fundamental science arising from the interactions between spins, electrons, phonons, and photons, but also manifests the potential to process and store data at a speed that is three orders of magnitude faster than the current technologies. In this paper, all‐optical helicity‐dependent switching (AO‐HDS) in hybrid metal–ferromagnet thin films, which consist of Co/Pt multilayers with perpendicular magnetic anisotropy and an Au film capping layer on the top, is experimentally demonstrated. The switching behaviors of the hybrid Co/Pt–Au material, with various laser repetition rates, scanning speeds, and fluencies, are systematically studied. In comparison with bare Co/Pt multilayers, the hybrid metal–ferromagnet thin films show pronounced AO‐HDS when the number of laser pulses per μm along the scanning direction gradually increases. In addition, the AO‐HDS effect is very robust against laser fluences. A possible mechanism is further proposed based on numerical simulations of the optomagnetic coupling model. These findings promise a new material system that exhibits stable AO‐HDS phenomena, and hence can transform future magnetic storage devices, especially with the addition of plasmonic nanostructures made of noble metals.

     
    more » « less
  5. The polarized photoluminescence from atomically thin transition metal dichalcogenides is a frequently applied tool to scrutinize optical selection rules and valley physics, yet it is known to sensibly depend on a variety of internal and external material and sample properties. In this work, we apply combined angle- and polarization-resolved spectroscopy to explore the interplay of excitonic physics and phenomena arising from the commonly utilized encapsulation procedure on the optical properties of atomically thinMoSe2. We probe monolayers prepared in both suspended and encapsulated manners. We show that the hBN encapsulation significantly enhances the linear polarization of exciton photoluminescence emission at large emission angles. This degree of linear polarization of excitons can increase up to∼<#comment/>17%<#comment/>in the hBN encapsulated samples. As we confirm by finite-difference time-domain simulations, it can be directly connected to the optical anisotropy of the hBN layers. In comparison, the linear polarization at finite exciton momenta is significantly reduced in a suspendedMoSe2monolayer, and becomes notable only in cryogenic conditions. This phenomenon strongly suggests that the effect is rooted in the k-dependent anisotropic exchange coupling inherent in 2D excitons. Our results have strong implications on further studies on valley contrasting selection rules and valley coherence phenomena using standard suspended and encapsulated samples.

     
    more » « less