Abstract The sensitivity of urban canopy air temperature ( ) to anthropogenic heat flux ( ) is known to vary with space and time, but the key factors controlling such spatiotemporal variabilities remain elusive. To quantify the contributions of different physical processes to the magnitude and variability of (where represents a change), we develop a forcing-feedback framework based on the energy budget of air within the urban canopy layer and apply it to diagnosing simulated by the Community Land Model Urban over the contiguous United States (CONUS). In summer, the median is around 0.01 over the CONUS. Besides the direct effect of on , there are important feedbacks through changes in the surface temperature, the atmosphere–canopy air heat conductance ( ), and the surface–canopy air heat conductance. The positive and negative feedbacks nearly cancel each other out and is mostly controlled by the direct effect in summer. In winter, becomes stronger, with the median value increased by about 20% due to weakened negative feedback associated with . The spatial and temporal (both seasonal and diurnal) variability of as well as the nonlinear response of to are strongly related to the variability of , highlighting the importance of correctly parameterizing convective heat transfer in urban canopy models.
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Pressure-induced shift of effective Ce valence, Fermi energy and phase boundaries in CeOs 4 Sb 12
Abstract CeOs4Sb12, a member of the skutterudite family, has an unusual semimetallic low-temperature -phase that inhabits a wedge-like area of the fieldH—temperatureTphase diagram. We have conducted measurements of electrical transport and megahertz conductivity on CeOs4Sb12single crystals under pressures of up to 3 GPa and in high magnetic fields of up to 41 T to investigate the influence of pressure on the differentH–Tphase boundaries. While the high-temperature valence transition between the metallic -phase and the -phase is shifted to higherTby pressures of the order of 1 GPa, we observed only a marginal suppression of the -phase that is found below 1 K for pressures of up to 1.91 GPa. High-field quantum oscillations have been observed for pressures up to 3.0 GPa and the Fermi surface of the high-field side of the -phase is found to show a surprising decrease in size with increasing pressure, implying a change in electronic structure rather than a mere contraction of lattice parameters. We evaluate the field-dependence of the effective masses for different pressures and also reflect on the sample dependence of some of the properties of CeOs4Sb12which appears to be limited to the low-field region.
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- PAR ID:
- 10366576
- Publisher / Repository:
- IOP Publishing
- Date Published:
- Journal Name:
- New Journal of Physics
- Volume:
- 24
- Issue:
- 4
- ISSN:
- 1367-2630
- Page Range / eLocation ID:
- Article No. 043044
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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