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1. The multiple depleted mantle components in the Hawaiian-Emperor chain

   https://doi.org/10.1016/j.chemgeo.2019.119324  

   Harrison, L ; Weis, D ; Garcia, M.O. ( January 2020 , Chemical geology)

   Oceanic island basalts are targeted for geochemical study because they provide a direct window into mantle composition and a wealth of information on the dynamics and timescales associated with Earth mixing. Previous studies mainly focused on the shield volcanic stage of oceanic islands and the more fusible, enriched mantle components that are easily distinguished in those basalts. Mantle depleted compositions are typically more difficult to resolve unless large amounts of this material participated in mantle melting (e.g., mid-ocean ridges), or unique processes allow for their compositions to be erupted undiluted, such as very small degrees of melting of a source with minimal fusible enriched components (e.g., rejuvenated basalts) or as xenoliths (e.g., abyssal peridotites). Mantle depleted components, defined here as material with low time-integrated Rb/Sr (low 87Sr/86Sr) and high time-integrated Sm/Nd and Lu/Hf ratios (high 143Nd/144Nd and 176Hf/177Hf) relative to primitive mantle, derive from a potentially very large volume reservoir (up to 80% of the mantle), and therefore need adequate characterization in order estimate the composition of the Earth and mantle-derived melts. This review focuses on mantle depleted compositions in oceanic island basalts using the Hawaiian-Emperor chain as a case study. The Hawaiian-Emperor chain is the ∼6000 km long geologicalmore »record of the deeply sourced Hawaiian mantle plume, active for>81 Myr. Hawaiian volcanism evolves through four volcanic stages as a volcano traverses the Hawaiian plume: alkalic preshield, tholeiitic shield (80–90% volcano volume), alkalic postshield (∼1%), and silica undersaturated rejuvenated (< 0.1%). We report Pb-Sr-Nd-Hf isotope compositions and trace element concentrations of three rejuvenated Northwest Hawaiian Ridge basalts and compare them to an exhaustive compiled dataset of basalts from the Hawaiian Islands to the Emperor Seamounts. The Northwest Hawaiian Ridge (NWHR) includes 51 volcanoes spanning ∼42 m.y. between the bend in the Hawaiian-Emperor chain and the Hawaiian Islands where there is no high-precision isotopic data published on the rejuvenated-stage over ∼47% of the chain. NWHR and Hawaiian Island rejuvenated basalts are geochemically similar, indicating a consistent source for rejuvenated volcanism over ∼12.5 million years. In contrast, shield-stage basalts from the oldest Emperor Seamounts are more depleted in isotopic composition (i.e., higher 176Hf/177Hf, and 143Nd/144Nd with lower 87Sr/86Sr and 208Pb*/206Pb*) and trace element concentrations (i.e., much lower concentrations of highly incompatible elements) than all other depleted Hawaiian basalts younger than the bend, including NWHR rejuvenated basalts. The strongly depleted source for the oldest Emperor Seamounts (> 70 Ma) was likely related to interaction with the Kula-Pacific-Izanagi mid-ocean ridge spreading system active near the Hawaiian plume in the Late Cretaceous. In contrast, the incompatible trace element ratios of NWHR rejuvenated basalts require a distinct source in the Hawaiian mantle plume that was imprinted by ancient (> 1 Ga) partial melting, likely ancient recycled oceanic lithosphere. This review of the geochemistry of Hawaiian depleted components documents the need for the sampling of multiple distinctive depleted compositions, each preferentially melted during specific periods of Hawaiian plume activity. This suggests that the composition of depleted components can evolve during the lifetime of the mantle plume, as observed for enriched components in the Hawaiian mantle plume. Changes in the composition of depleted components are dominantly controlled by the upper mantle tectonic configurations at the time of eruption (i.e., proximity to a mid-ocean ridge), as this effect overwhelms the signal imparted by potentially sampling different lower mantle components through time.« less
2. Near-zero 33S and 36S anomalies in Pitcairn basalts suggest Proterozoic sediments in the EM-1 mantle plume

   https://doi.org/10.1016/j.epsl.2022.117422  

   Labidi, Jabrane ; Dottin, James W. ; Clog, Matthieu ; Hemond, Christophe ; Cartigny, Pierre ( April 2022 , Earth and planetary science letters)

   Volcanic rocks erupted among Pitcairn seamounts sample a mantle plume that exhibits an extreme Enriched Mantle-1 signature. The origin of this peculiar mantle endmember remains contentious, and could involve the recycling of marine sediments of Archean or Proterozoic ages, delaminated units from the lower continental crust, or metasomatized peridotites from a lithospheric mantle. Here, we report the sulfur multi-isotopic signature (32S, 33S, 34S, 36S) of 15 fresh submarine basaltic glasses from three Pitcairn seamounts. We observe evidence for magmatic degassing of sulfur from melts erupted ∼2,000 meters below seawater level (mbsl). Sulfur concentrations are correlated with eruption depth, and range between 1300 ppm S (collected ∼ 2,500 mbsl) and 600 ppm S (∼2,000 mbsl). The δ34S values can be accounted for under equilibrium isotope fractionation during degassing, with αgas-melt between 1.0020 and 1.0001 and starting δ34S values between −0.9‰ and +0.6‰. The δ34S estimates are similar or higher than MORB signatures, suggesting the contribution of recycled sulfur with a ∼ 1‰ 34S enrichment compared to the Pacific upper mantle. The Δ33S and Δ36S signatures average at +0.024±0.007‰ and +0.02±0.07‰ vs. CDT, respectively (all 1σ). Only Δ33S is statistically different from MORB, by +0.02‰. The Δ33S enrichment is invariant across degassingmore »and sulfide segregation. We suggest it reflects a mantle source enrichment rather than a high-temperature fractionation of S in the basalts. Despite the small magnitude of the 33S-36S variations, our data require a substantial amount of recycled sulfur overwhelm the Pitcairn mantle source. We show that models involving metasomatized peridotites, lower crust units, or Archean sediments, may be viable, but are restricted to narrow sets of circumstances. Instead, scenarios involving the contribution of Proterozoic marine sediments appear to be the most parsimonious explanation for the EM-1 signature at Pitcairn.« less
3. Trace element partitioning between olivine and melt in lunar basalts

   https://doi.org/10.2138/am-2022-7971  

   Chen, Sha ; Ni, Peng ; Zhang, Youxue ; Gagnon, Joel ( August 2022 , American Mineralogist)

   Abstract Mineral/melt partition coefficients have been widely used to provide insights into magmatic processes. Olivine is one of the most abundant and important minerals in the lunar mantle and mare basalts. Yet, no systematic olivine/melt partitioning data are available for lunar conditions. We report trace element partition data between host mineral olivine and its melt inclusions in lunar basalts. Equilibrium is evaluated using the Fe-Mg exchange coefficient, leading to the choice of melt inclusion-host olivine pairs in lunar basalts 12040, 12009, 15016, 15647, and 74235. Partition coefficients of 21 elements (Li, Mg, Al, Ca, Ti, V, Cr, Mn, Fe, Co, Y, Zr, Nb, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) were measured. Except for Li, V, and Cr, these elements show no significant difference in olivine-melt partitioning compared to the data for terrestrial samples. The partition coefficient of Li between olivine and melt in some lunar basalts with low Mg# (Mg# < 0.75 in olivine, or < ~0.5 in melt) is higher than published data for terrestrial samples, which is attributed to the dependence of DLi on Mg# and the lack of literature DLi data with low Mg#. The partition coefficient of V in lunar basalts is measuredmore »to be 0.17 to 0.74, significantly higher than that in terrestrial basalts (0.003 to 0.21), which can be explained by the lower oxygen fugacity in lunar basalts. The significantly higher DV can explain why V is less enriched in evolved lunar basalts than terrestrial basalts. The partition coefficient of Cr between olivine and basalt melt in the Moon is 0.11 to 0.62, which is lower than those in terrestrial settings by a factor of ~2. This is surprising because previous authors showed that Cr partition coefficient is independent of fO2. A quasi-thermodynamically based model is developed to correlate Cr partition coefficient to olivine and melt composition and fO2. The lower Cr partition coefficient between olivine and basalt in the Moon can lead to more Cr enrichment in the lunar magma ocean, as well as more Cr enrichment in mantle-derived basalts in the Moon. Hence, even though Cr is typically a compatible element in terrestrial basalts, it is moderately incompatible in primitive lunar basalts, with a similar degree of incompatibility as V based on partition coefficients in this work, as also evidenced by the relatively constant V/Cr ratio of 0.039 ± 0.011 in lunar basalts. The confirmation of constant V/Cr ratio is important for constraining concentrations of Cr (slightly volatile and siderophile) and V (slightly siderophile) in the bulk silicate Moon.« less
4. The Generation of Arc Andesites and Dacites in the Lower Crust of a Cordilleran Arc, Fiordland, New Zealand

   https://doi.org/10.1093/petrology/egab043  

   Carty, Kendra ; Schwartz, Joshua J ; Wiesenfeld, John ; Klepeis, Keith A ; Stowell, Harold H ; Tulloch, Andy J ; Barnes, Calvin G ( September 2021 , Journal of Petrology)

   Abstract We present microbeam major- and trace-element data from 14 monzodiorites collected from the Malaspina Pluton (Fiordland, New Zealand) with the goal of evaluating processes involved in the production of andesites in lower arc crust. We focus on relict igneous assemblages consisting of plagioclase and amphibole with lesser amounts of clinopyroxene, orthopyroxene, biotite and quartz. These relict igneous assemblages are heterogeneously preserved in the lower crust within sheeted intrusions that display hypersolidus fabrics defined by alignment of unstrained plagioclase and amphibole. Trace-element data from relict igneous amphiboles in these rocks reveal two distinct groups: one relatively enriched in high field strength element concentrations and one relatively depleted. The enriched amphibole group has Zr values in the range of ∼25–110 ppm, Nb values of ∼5–32 ppm, and Th values up to 2·4 ppm. The depleted group, in contrast, shows Zr values <35 ppm and Nb values <0·25 ppm, and Th is generally below the level of detection. Amphibole crystallization temperatures calculated from major elements range from ∼960 to 830 °C for all samples in the pluton; however, we do not observe significant differences in the range of crystallization temperatures between enriched (∼960–840 °C) and depleted groups (∼940–830 °C). Bulk-rock Sr and Nd isotopes are also remarkably homogeneous and showmore »no apparent difference between enriched (εNdi = 0·1 to –0·1; 87Sr/86Sri = 0·70420–0·70413) and depleted groups (εNdi = 0·3 to –0·4; 87Sr/86Sri = 0·70424–0·70411). Calculated amphibole-equilibrium melt compositions using chemometric equations indicate that melts were highly fractionated (molar Mg# <50), andesitic to dacitic in composition, and were much more evolved than bulk lower continental crust or primitive basalts and andesites predicted to have formed from hydrous melting of mantle-wedge peridotite beneath an arc. We suggest that melts originated from a common, isotopically homogeneous source beneath the Malaspina Pluton, and differences between enriched and depleted trace-element groups reflect varying contributions from subducted sediment-derived melt and sediment-derived fluid, respectively. Our data demonstrate that andesites and dacites were the dominant melts that intruded the lower crust, and their compositions mirror middle and upper bulk-continental crust estimates. Continental crust-like geochemical signatures were acquired in the source region from interaction between hydrous mantle-wedge melts and recycled subducted sediment rather than assimilation and/or remelting of pre-existing lower continental crust.« less
5. Ancient helium and tungsten isotopic signatures preserved in mantle domains least modified by crustal recycling

   https://doi.org/10.1073/pnas.2009663117  

   Jackson, Matthew G. ; Blichert-Toft, Janne ; Halldórsson, Saemundur A. ; Mundl-Petermeier, Andrea ; Bizimis, Michael ; Kurz, Mark D. ; Price, Allison A. ; Harðardóttir, Sunna ; Willhite, Lori N. ; Breddam, Kresten ; et al ( November 2020 , Proceedings of the National Academy of Sciences)

   Rare high-³He/⁴He signatures in ocean island basalts (OIB) erupted at volcanic hotspots derive from deep-seated domains preserved in Earth’s interior. Only high-³He/⁴He OIB exhibit anomalous¹⁸²W—an isotopic signature inherited during the earliest history of Earth—supporting an ancient origin of high³He/⁴He. However, it is not understood why some OIB host anomalous¹⁸²W while others do not. We provide geochemical data for the highest-³He/⁴He lavas from Iceland (up to 42.9 times atmospheric) with anomalous¹⁸²W and examine how Sr-Nd-Hf-Pb isotopic variations—useful for tracing subducted, recycled crust—relate to high³He/⁴He and anomalous¹⁸²W. These data, together with data on global OIB, show that the highest-³He/⁴He and the largest-magnitude¹⁸²W anomalies are found only in geochemically depleted mantle domains—with high¹⁴³Nd/¹⁴⁴Nd and low²⁰⁶Pb/²⁰⁴Pb—lacking strong signatures of recycled materials. In contrast, OIB with the strongest signatures associated with recycled materials have low³He/⁴He and lack anomalous¹⁸²W. These observations provide important clues regarding the survival of the ancient He and W signatures in Earth’s mantle. We show that high-³He/⁴He mantle domains with anomalous¹⁸²W have low W and⁴He concentrations compared to recycled materials and are therefore highly susceptible to being overprinted with low³He/⁴He and normal (not anomalous)¹⁸²W characteristic of subducted crust. Thus, high³He/⁴He and anomalous¹⁸²W are preserved exclusively in mantle domains least modified by recycledmore »crust. This model places the long-term preservation of ancient high³He/⁴He and anomalous¹⁸²W in the geodynamic context of crustal subduction and recycling and informs on survival of other early-formed heterogeneities in Earth’s interior.

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