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1. Anaerobic Digestion of Food Waste, Brewery Waste, and Agricultural Residues in an Off-Grid Continuous Reactor

   https://doi.org/10.3390/su13126509  

   Miller, Kimberley E. ; Herman, Tess ; Philipinanto, Dimas A. ; Davis, Sarah C. ( June 2021 , Sustainability)

   Small-scale anaerobic digestion (AD) can be an effective organic waste management system that also provides energy for small businesses and rural communities. This study measured fuel production from digestions of single and mixed feedstocks using an unheated, 2 m3 digester operated continuously in a temperate climate for over three years. Using local food waste, brewery waste, grease waste, and agricultural residues, this study determined that small-scale AD co-digestions were almost always higher yielding than single feedstocks during psychrophilic operation and seasonal temperature transitions. Agricultural residues from Miscanthus x giganteus had the greatest impact on biomethane production during co-digestion (4.7-fold greater average biogas %CH4), while mesophilic digestion of brewery waste alone produced the most biogas (0.76 gCH4 gVS−1 d−1). Biogas production during the transition from mesophilic to psychrophilic was temporarily maintained at levels similar to mesophilic digestions, particularly during co-digestions, but biogas quality declined during these temperature shifts. Full-time operation of small-scale, unheated AD systems could be feasible in temperate climates if feedstock is intentionally amended to stabilize carbon content. 

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2. Integrating dairy manure for enhanced resource recovery at a WRRF: Environmental life cycle and pilot‐scale analyses

   https://doi.org/10.1002/wer.1574  

   Bryant, Casey ; Coats, Erik R. ( April 2021 , Water Environment Research)

   The Twin Falls, Idaho wastewater treatment plant (WWTP), currently operates solely to achieve regulatory permit compliance. Research was conducted to evaluate conversion of the WWTP to a water resource recovery facility (WRRF) and to assess the WRRF environmental sustainability; process configurations were evaluated to produce five resources—reclaimed water, biosolids, struvite, biogas, and bioplastics (polyhydroxyalkanoates, PHA). PHA production occurred using fermented dairy manure. State‐of‐the‐art biokinetic modeling, performed using Dynamita's SUMO process model, was coupled with environmental life cycle assessment to quantify environmental sustainability. Results indicate that electricity production via combined heat and power (CHP) was most important in achieving environmental sustainability; energy offset ranged from 43% to 60%, thereby reducing demand for external fossil fuel‐based energy. While struvite production helps maintain a resilient enhanced biological phosphorus removal (EBPR) process, MgO₂production exhibits negative environmental impacts; integration with CHP negates the adverse consequences. Integrating dairy manure to produce bioplastics diversifies the resource recovery portfolio while maintaining WRRF environmental sustainability; pilot‐scale evaluations demonstrated that WRRF effluent quality was not affected by the addition of effluent from PHA production. Collectively, results show that a WRRF integrating dairy manure can yield a diverse portfolio of products while operating in an environmentally sustainable manner.

   Wastewater carbon recovery via anaerobic digestion with combined heat/power production significantly reduces water resource recovery facility (WRRF) environmental emissions.

   Wastewater phosphorus recovery is of value; however, struvite production exhibits negative environmental impacts due to MgO₂production emissions.

   Bioplastics production on imported organic‐rich agri‐food waste can diversify the WRRF portfolio.

   Dairy manure can be successfully integrated into a WRRF for bioplastics production without compromising WRRF performance.

   Diversifying the WRRF products portfolio is a strategy to maximize resource recovery from wastewater while concurrently achieving environmental sustainability.

    

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3. Experimental-based mechanistic study and optimization of hydrothermal liquefaction of anaerobic digestates

   https://doi.org/10.1039/D2SE00206J  

   Sudibyo, Hanifrahmawan ; Pecchi, Matteo ; Tester, Jefferson William ( May 2022 , Sustainable Energy & Fuels)

   Valorization of agricultural and food waste digestates is crucial for sustainable waste management to reduce environmental impacts and improve the economics of commercial farms. Hydrothermal liquefaction (HTL) of anaerobic digestates was evaluated to recover resources by converting them into carbon-dense biocrude oil and a nutrient-rich HTL aqueous phase (HTL-AP) coproduct. The effects of HTL temperature (280–360 °C), reaction time (10–50 min), feedstock pH (2.5–8.5), digestate salt content (1–5 wt%), and digestate cellulose-to-lignin ratio (0.2–1.8) on energy and nutrient recovery were systematically investigated in a set of well-designed experiments following a half-fractional central composite protocol. Response surface analysis combined with HTL product characterization and comparative literature study produced a comprehensive reaction pathway for HTL of anaerobic digestates. Moreover, this analysis revealed the importance of acidic feedstocks (pH 3.00–5.53), high reaction temperatures (337–360 °C), and reaction times <45 or 45–50 min for digestates with Cel/Lig >1 or <1, for maximizing the energy recovered in biocrude (high carbon yield and low heteroatom content) and the amounts of P, NH 3 –N, and Mg distributed in the HTL-AP. Acidic conditions catalyzed biocrude production, inhibited the Maillard reaction (lowering the nitrogen content in biocrude), and partitioned nutrients into the HTL-AP. Higher reaction temperatures coupled with longer reaction times activated hydro-denitrogenation and deoxygenation reactions to improve biocrude quality. This work provides not only validated methods to achieve targeted resource recovery for specific feedstock compositions using HTL, but also a comprehensive mechanistic understanding of the HTL of biomass waste for controlling target product characteristics. 

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4. Thermophilic Anaerobic Digestion: Enhanced and Sustainable Methane Production from Co-Digestion of Food and Lignocellulosic Wastes

   https://doi.org/10.3390/en11082058  

   David, Aditi ; Govil, Tanvi ; Tripathi, Abhilash ; McGeary, Julie ; Farrar, Kylie ; Sani, Rajesh ( August 2018 , Energies)

   This article aims to study the codigestion of food waste (FW) and three different lignocellulosic wastes (LW) (Corn stover (CS), Prairie cordgrass (PCG), and Unbleached paper (UBP)) for thermophilic anaerobic digestion to overcome the limitations of digesting food waste alone (volatile fatty acids accumulation and low C:N ratio). Using an enriched thermophilic methanogenic consortium, all the food and lignocellulosic waste mixtures showed positive synergistic effects of codigestion. After 30 days of incubation at 60 °C (100 rpm), the highest methane yield of 305.45 L·kg−1 volatile solids (VS) was achieved with a combination of FW-PCG-CS followed by 279.31 L·kg−1 VS with a mixture of FW-PCG. The corresponding volatile solids reduction for these two co-digestion mixtures was 68% and 58%, respectively. This study demonstrated a reduced hydraulic retention time for methane production using FW and LW. 

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5. Probing elemental speciation in hydrochar produced from hydrothermal liquefaction of anaerobic digestates using quantitative X-ray diffraction

   https://doi.org/10.1039/D2SE01092E  

   Sudibyo, Hanifrahmawan ; Tester, Jefferson W. ( December 2022 , Sustainable Energy & Fuels)

   Valorization of hydrochar, a solid byproduct from hydrothermal liquefaction (HTL) of anaerobically-digested agriculture wastes (digestates), requires fundamental knowledge of elemental speciation. This study investigated the effects of reaction temperatures (320–360 °C), digestate pH (3.5–8), and digestate cellulose-to-lignin ratios (0.2–1.8) on the speciation (chemical form) and composition of organics and inorganics in hydrochars produced during hydrothermal treatment. Quantitative X-ray diffraction (XRD) method was the primary technique used to characterize hydrochars. The comprehensive XRD pattern processing including the Rietveld refinement protocols demonstrated that the organic phase was comprised of mostly crystalline monocyclic, heterocyclic, and polycyclic aromatics with diverse aliphatic and aromatic substituents, while the inorganic mineral phase consisted of calcium-phosphates, magnesium-phosphates, calcium-carbonates, and magnesium-carbonates. XRD results were validated by the elemental yields of products and the distribution of chemical functionalities measured using solid-state nuclear magnetic resonance (NMR) spectroscopy. The characterization data were used to evaluate proposed mechanistic pathways using compositional analysis of biocrude and aqueous-phase coproducts. Mechanistic pathways developed in the study suggested that benzoic acids, phenols, benzaldehydes, phenolic aldehydes, α-dicarbonyls, and α-hydroxycarbonyls were responsible for the precipitation of organics through various reactions depending on operating conditions. Meanwhile, the formation of inorganic compounds appeared to be consistently represented by reactions including dehydration, hydrolysis, endergonic reduction, and structure rearrangement of native minerals in the digestates. This study provides basic knowledge needed to create and assess potential elemental speciation pathways. In addition, the results of the study facilitate the specification of process conditions to optimize targeted utilization routes of hydrochar for more economically-feasible and sustainable HTL processing. 

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