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  • Organometallic Ni( ii ), Ni( iii ), and Ni( iv ) complexes relevant to carbon–carbon and carbon–oxygen bond formation reactions
Title: Organometallic Ni( ii ), Ni( iii ), and Ni( iv ) complexes relevant to carbon–carbon and carbon–oxygen bond formation reactions
Herein, the pyridinophanetetradentate ligand 3,6,9-trimethyl-3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(15),11,13-triene, PyNMe 3 , is used to isolate and structurally characterize well-defined organometallic Ni( ii ) and Ni( iii ) complexes bearing the cycloneophyl fragment, an alkyl/aryl C-donor ligand. Furthermore, spectroscopic and cryo-mass spectrometry studies suggest the formation of a transient Ni( iv ) organometallic complex, and its relevance to C–C and C–O bond formation reactivity studies is discussed.  more » « less
Award ID(s):
1925751
PAR ID:
10389183
Author(s) / Creator(s):
; ; ; ; ;
Date Published:
Journal Name:
Inorganic Chemistry Frontiers
Volume:
9
Issue:
5
ISSN:
2052-1553
Page Range / eLocation ID:
1016 to 1022
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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