A facile, solvent-minimized approach to functionalize commercial raw fabrics is described. Reactive vapor deposition of conjugated polymers followed by post-deposition functionalization transforms common, off-the-shelf textiles into distinctly hydrophobic or superhydrophilic materials. The fabric coatings created by reactive vapor deposition are especially resistant to mechanical and solvent washing, as compared to coatings applied by conventional, solution-phase silane chemistries. Janus fabrics with dissimilar wettability on each face are also easily created using a simple, three-step vapor coating process, which cannot be replicated using conventional solution phase functionalization strategies. Hydrophobic fabrics created using reactive vapor deposition and post-deposition functionalization are effective, reusable, large-volume oil–water separators, either under gravity filtration or as immersible absorbants.
more »
« less
Investigation of Microstructures and Air Permeability of Aerogel-Coated Textile Fabric Materials
Abstract This study focuses on fabrication of aerogel-coated macroporous polyester fabrics for the purposes of filtration of nanometric airborne particles and potential application in facemasks. Syndiotactic polystyrene (sPS) and polyimide (PI) gels that provide respectively majority macropores (diameter > 50 nm) and mesopores (diameter 2 to 50 nm) are coated onto woven polyester fabrics via a dip coating process. The resultant materials are supercritically dried to obtain aerogelcoated fabrics. The results show that sPS is more suitable for the dip coating process. However, evaporation of the solvent during handling of gel-coated fabrics leads to closure of the surface pores that are later recovered via solvent annealing. The resultant aerogel-coated fabrics offer high air permeability (∼10 –10 m 2 ) and high filtration efficiency (> 99.95%) of airborne sodium chloride test particles of size 25 to 150 nm.
more »
« less
- Award ID(s):
- 1826030
- PAR ID:
- 10396851
- Date Published:
- Journal Name:
- International Polymer Processing
- Volume:
- 36
- Issue:
- 3
- ISSN:
- 0930-777X
- Page Range / eLocation ID:
- 322 to 331
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
As wastewater reclamation and reuse technologies become more critical to meeting the growing demand for water, a need has emerged for separation platforms that can be tailored to accommodate the highly varied feed water compositions and treatment demands of these technologies. Nanofiltration (NF) membranes based on copolymer materials are a promising platform in this regard because they can be engineered at the molecular scale to address an array of separation process needs. Here, for example, a resilient NF membrane is developed through the design of a poly(trifluoroethyl methacrylate- co -oligo(ethylene glycol) methyl ether methacrylate- co -glycidyl methacrylate) [P(TFEMA-OEGMA-GMA)] copolymer that can be dip-coated onto hollow fiber supports. By exploiting the microphase separation of the oligomeric ethylene glycol side chains from the copolymer backbone and by elucidating the processing–structure–property relationships for the dip-coating process, membranes with pores 2 nm-in-diameter that exhibit a hydraulic permeability of 15.6 L m −2 h −1 bar −1 were generated. The GMA repeat units were functionalized post-coating with hexamethylene diamine to incorporate positively-charged moieties along the pore walls. This functionality resulted in membranes that rejected 98% of the MgCl 2 from a 1 mM feed solution. Moreover, the reaction with the diamine crosslinked the copolymer such that the membranes operated stably in ethanol, an organic solvent that damaged the unreacted parent membranes irreparably. Finally, the stability of the crosslinked P(TFEMA-OEGMA-GMA) copolymer resulted in membranes that could operate continuously for a 24 hour period in aqueous solutions containing 500 ppm chlorine without exhibiting signs of structural degradation as evidenced by consistent rejection of neutral probe solutes. These results demonstrate how resilient, charge-selective NF membranes can be fabricated from microphase separated copolymers by engineering each of the constituent repeat units for a directed purpose.more » « less
-
High performance carbon fibers are widely used as fiber reinforcements in composite material systems for aerospace, automotive, and defense applications. Longitudinal tensile failure of such composite systems is a result of clustering of single fiber tensile failures occurring at the microscale, on the order of a few microns to a few hundred microns. Since fiber tensile strength at the microscale has a first order effect on composite strength, it is important to characterize the strength of single fibers at microscale gage lengths which is extremely challenging. An experimental technique based on a combination of transverse loading of single fibers under SEM with DIC is a potential approach to access microscale gage lengths. The SEM-DIC technique requires creation of uniform, random, and contrastive sub-microscale speckle pattern on the curved fiber surface for accurate strain measurements. In this paper, we investigate the formation of such sub-microscale speckle patterns on individual sized IM7 carbon fibers of nominal diameter 5.2 µm via sputter coating. Various process conditions such as working pressure, sputtering current, and coating duration are investigated for pattern creation on fiber surface using a gold-palladium (Au-Pd) target. A nanocluster type sub-microscale pattern is obtained on the fiber surface for different coating conditions. Numerical translation experiments are performed using the obtained patterns to study image correlation and identify a suitable pattern for SEM-DIC experiments. The pattern obtained at a working pressure of 120–140 mTorr with 50 mA current for a duration of 10 min is found to have an average speckle size of 53 nm and good contrast for image correlation. Rigid body translation SEM experiments for drift/distortion correction using a sized IM7 carbon fiber coated with the best patterning conditions showed that Stereo-SEM-DIC is needed for accurately characterizing fiber strain fields due to its curved surface. The effect of sputter coating on fiber tensile strength and strain is investigated via single fiber tensile tests. Results showed that there is no significant difference in the mean tensile strength and failure strain between uncoated and coated fibers (average increment in fiber diameter of ∼221 nm due to coating) at 5% significance level. SEM images of failure surfaces for uncoated and coated fibers also confirmed a tensile failure of fibers as observed for polyacrylonitrile PAN-based fibers in literature.more » « less
-
Organic solvent filtration is an important industrial process. It is widely used in pharmaceutical manufacturing, chemical processing industry, semiconductor industry, auto assembly etc. Most of the particle filtration studies reported in open literature dealt with aqueous suspension medium. The current work has initiated a study of cross-flow solvent filtration behavior of microporous ethylene chlorotrifluoroethylene (ECTFE) membranes using 12 nm silica nanoparticles suspended in an aqueous solution containing 25% ethanol. In the constant pressure mode of operation of cross-flow microfiltration (MF), permeate samples were collected at different time intervals. The permeate particle size distribution (PSD) results for different experiments were identical. Particle agglomerates having less than 100 nm size can pass through the membrane; some fouling was observed. The governing fouling mechanisms for tests operated using 3.8×10−3 kg/m3 (3.8 ppm) at 6.9×103 Pag and 1.4×104 Pag were pore blocking. For tests conducted using 3.8×10−3 kg/m3 (3.8 ppm) at 27.6×103 Pag (4 psig) and 1.9×10−3 kg/m3 (1.9 ppm) at 6.9×103, 13.8×103 and 27.6×103 Pag (1, 2 and 4 psig), the mechanism was membrane resistance control. Less particles got embedded in membrane pores in experiments operated using suspensions with lower or higher particle concentrations with a higher transmembrane pressure. This is in good agreement with the values of the shear rate in the pore flow and scanning electron microscope images of the membrane after MF. In the dead-end mode of operation of solvent filtration using methanol, ethanol and 2-propanol, the permeate flux behavior follows Jmethanol > Jethanol > J2-propanol at all testing pressures. The values of permeance (kg/m2-s-Pa) determined from the slope of the linear plot of filtration flux vs. the applied pressure difference across the membrane, were 3.9×10−4, 2.3×10−4 and 3.0×10−5 for methanol, ethanol and 2-propanol, respectively. Further exploration was made on solvent sorption results reported earlier. The critical temperature of selected solvents shows a better correlation with solvent sorption rather than the solubility parameter.more » « less
-
Dip coating consists of withdrawing a substrate from a bath to coat it with a thin liquid layer. This process is well understood for homogeneous fluids, but heterogeneities, such as particles dispersed in liquid, lead to more complex situations. Indeed, particles introduce a new length scale, their size, in addition to the thickness of the coating film. Recent studies have shown that, at first order, the thickness of the coating film for monodisperse particles can be captured by an effective capillary number based on the viscosity of the suspension, providing that the film is thicker than the particle diameter. However, suspensions involved in most practical applications are polydisperse, characterized by a wide range of particle sizes, introducing additional length scales. In this study, we investigate the dip coating of suspensions having a bimodal size distribution of particles. We show that the effective viscosity approach is still valid in the regime where the coating film is thicker than the diameter of the largest particles, although bidisperse suspensions are less viscous than monodisperse suspensions of the same solid fraction. We also characterize the intermediate regime that consists of a heterogeneous coating layer and where the composition of the film is different from the composition of the bath. A model to predict the probability of entraining the particles in the liquid film depending on their sizes is proposed and captures our measurements. In this regime, corresponding to a specific range of withdrawal velocities, capillarity filters the large particles out of the film.more » « less