Site-Differentiated Mn II Fe II Complex Reproducing the Selective Assembly of Biological Heterobimetallic Mn/Fe Cofactors
- Award ID(s):
- 1834750
- PAR ID:
- 10398271
- Date Published:
- Journal Name:
- Journal of the American Chemical Society
- Volume:
- 145
- Issue:
- 6
- ISSN:
- 0002-7863
- Page Range / eLocation ID:
- 3491 to 3498
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
The synthesis, single-crystal structures and magnetic properties of three new cyano-bridged complexes [FeIII4MII2] (M = Fe II , Co II , Ni II ) are reported. Electronic absorption spectroscopy reveals the occurrence of intervalence charge transfer for [FeIII4FeII2]. Field-induced slow magnetic relaxation behavior is exhibited for [FeIII4CoII2] and [FeIII4NiII2] which originates from the ferromagnetic interactions between Fe III and M II spin centers of the square.more » « less
-
Jentschel, M (Ed.)γ-ray production cross sections have been deduced for reactions with incident neutrons having energies from 1.5 - 4.7 MeV. Similar measurements were made on a natural Ti sample to establish an absolute normalization. The resulting γ-ray production cross sections are compared to TENDL and TALYS calculations, as well as data from previous measurements. The models are found to describe the production cross sections for mostγrays observed from54Mn and54Fe rather well.more » « less
An official website of the United States government

