skip to main content


Title: Site-Differentiated Mn II Fe II Complex Reproducing the Selective Assembly of Biological Heterobimetallic Mn/Fe Cofactors
Award ID(s):
1834750
NSF-PAR ID:
10398271
Author(s) / Creator(s):
; ; ; ; ;
Date Published:
Journal Name:
Journal of the American Chemical Society
Volume:
145
Issue:
6
ISSN:
0002-7863
Page Range / eLocation ID:
3491 to 3498
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. null (Ed.)
  2. The synthesis, single-crystal structures and magnetic properties of three new cyano-bridged complexes [FeIII4MII2] (M = Fe II , Co II , Ni II ) are reported. Electronic absorption spectroscopy reveals the occurrence of intervalence charge transfer for [FeIII4FeII2]. Field-induced slow magnetic relaxation behavior is exhibited for [FeIII4CoII2] and [FeIII4NiII2] which originates from the ferromagnetic interactions between Fe III and M II spin centers of the square. 
    more » « less