Among major energy conversion methods, photovoltaic (PV) solar cells have been the most popular and widely employed for a variety of applications. Although a PV solar panel has been shown as one of the most efficient green energy sources, its 2D surface solar light harvesting has reached great limitations as it requires large surface areas. There is, therefore, an increasing need to seek solar harvest in a three-dimensional fashion for enhanced energy density. In addition to a conventional 2D solar panel in the x-y area, we extend another dimension of solar harvesting in the z-axis through multiple CdTe solar panels arranged in parallel. The high transparency allows sunlight to partially penetrate multiple solar panels, resulting in significantly increased solar harvesting surface area in a 3D fashion. The advantages of the 3D multi-panel solar harvesting system include: i) enlarged solar light collecting surface area, therefore increased energy density, ii) the total output power from multiple panels can exceed that of the single panel, and iii) significantly reduced surface area needed for densely populated cities. With five CdTe solar panels of different transparencies in parallel, the multilayer system can produce collective output power 233% higher than that of the single solar panel under the same surface area when arranged in descending (i.e., PV panel with the highest transparency on top and lowest at bottom). The PCE of the multi-panel system has also increased 233% in descending order indicating the viability of 3D solar harvesting. The multi-panel system will dimensionally transform solar harvesting from 2D to 3D for more efficient energy generation.
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3D Solar Harvesting and Energy Generation via Multilayers of Transparent Porphyrin and Iron Oxide Thin Films
Photovoltaic solar cells have been extensively used for various applications and are considered one of the most efficient green energy sources. However, their 2D surface area solar harvesting has limitations, and there is an increasing need to explore the possibility of multiple layer solar harvest for enhanced energy density. To address this, we have developed spectral-selective transparent thin films based on porphyrin and iron oxide compounds that allow solar light to penetrate multiple layers, significantly increasing solar harvesting surface area and energy density. These thin films are designed as photovoltaic (PV) and photothermal (PT) panels that can convert photons into either electricity or thermal energy for various green energy applications, such as smart building skins and solar desalination. The advantages of this 3D solar harvesting system include enlarged solar light collecting surface area and increased energy density. The multilayer system transforms the current 2D to 3D solar harvesting, enabling efficient energy generation. This review discusses recent developments in the synthesis and characterization of PV and PT transparent thin films for solar harvesting and energy generation using multilayers. Major applications of the 3D solar harvesting system are reviewed, including thermal energy generation, multilayered DSSC PV system, and solar desalination. Some preliminary data on transparent multilayer DSSC PVs are presented.
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- Award ID(s):
- 1953009
- PAR ID:
- 10407073
- Date Published:
- Journal Name:
- Energies
- Volume:
- 16
- Issue:
- 7
- ISSN:
- 1996-1073
- Page Range / eLocation ID:
- 3173
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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