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Abstract The Phanerozoic Eon marked a major transition from marine silica deposition exclusively via abiotic pathways to a system dominated by biogenic silica sedimentation. For decades, prevailing ideas predicted this abiotic‐to‐biogenic transition were marked by a significant decrease in the concentration of dissolved silica in seawater; however, due to the lower perceived abundance and uptake affinity of sponges and radiolarians relative to diatoms, marine dissolved silica is thought to have remained elevated above modern values until the Cenozoic radiation of diatoms. Studies of modern marine silica biomineralizers demonstrated that the Si isotope ratios (δ30Si) of sponge spicules and planktonic silica biominerals produced by diatoms or radiolarians can be applied as quantitative proxies for past seawater dissolved silica concentrations due to differences in Si isotope fractionations among these organisms. We undertook 446 ion microprobe analyses of δ30Si and δ18O of sponge spicules and radiolarians from Ordovician–Silurian chert deposits of the Mount Hare Formation in Yukon, Canada. These isotopic data showed that sponges living in marine slope and basinal environments displayed small Si isotope fractionations relative to coeval radiolarians. By constructing a mathematical model of the major fluxes and reservoirs in the marine silica cycle and the physiology of silica biomineralization, we found that the concentration of dissolved silica in seawater was less than ~150 μM during early Paleozoic time—a value that is significantly lower than previous estimates. We posit that the topology of the early Paleozoic marine silica cycle resembled that of modern oceans much more closely than previously assumed.
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Environmental and Hydrogeochemical Controls of Spicular Geyserite in Opaline Hot Spring Deposits
Abstract Siliceous spicules are micro‐laminated geyserite deposits, or micro‐stromatolites, found around high temperature hot‐springs and geysers, associated with intermittent splashes of water. Understanding conditions of formation of these structures will give insights of critical parameters involved in prebiotic environments and early life. We provide a new data set around two geysers from the El Tatio hydrothermal field, Atacama Desert, Chile, a modern analogue for habitable environments on early Earth and Mars. Small spicules (<5 mm diameter) dominate in the near vent areas, whereas larger spicules (>5 mm diameter) form complex columnar structures in the distal vent (>0.3 m distance from the vent). Hydrodynamics, eruption periodicity, and environmental conditions modulate the temperature and cooling patterns around vents. During geyser eruptions, the temperature of water reaching the ground decreases with the distance from the vent. Cooling is stronger during the evenings, due to strong winds and cold air temperature. Rapid water cooling drives supersaturation of amorphous silica, and therefore precipitation rates increase significantly with distance from the vent. Cooling also controls changes in the bacterial communities, from thin filaments <1 μm diameter predominating closer to the vent, to 1–2 μm diameter filaments in the distal vent. Changes in the silica precipitation rate and biota may control the growth of spicules and the transition to columns. Estimated precipitation rates of silica provide a first approximation of the longevity of these structures and the timing for the formation of internal laminations. Microlamination will form in year time‐scales closer to the vent, and weeks farther from the vent.
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- Award ID(s):
- 2143533
- PAR ID:
- 10420778
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Earth and Space Science
- Volume:
- 10
- Issue:
- 3
- ISSN:
- 2333-5084
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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