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Poly(ether ether ketone) (PEEK) was found to form gels in the benign solvent 1,3-diphenylacetone (DPA). Gelation of PEEK in DPA was found to form an interconnected, strut-like morphology composed of polymer axialites. To our knowledge, this is the first report of a strut-like morphology for PEEK aerogels. PEEK/DPA gels were prepared by first dissolving PEEK in DPA at 320 °C. Upon cooling to 50 °C, PEEK crystallizes and forms a gel in DPA. The PEEK/DPA phase diagram indicated that phase separation occurs by solid–liquid phase separation, implying that DPA is a good solvent for PEEK. The Flory–Huggins interaction parameter, calculated as χ12 = 0.093 for the PEEK/DPA system, confirmed that DPA is a good solvent for PEEK. PEEK aerogels were prepared by solvent exchanging DPA to water then freeze-drying. PEEK aerogels were found to have densities between 0.09 and 0.25 g/cm3, porosities between 80 and 93%, and surface areas between 200 and 225 m2/g, depending on the initial gel concentration. Using nitrogen adsorption analyses, PEEK aerogels were found to be mesoporous adsorbents, with mesopore sizes of about 8 nm, which formed between stacks of platelike crystalline lamellae. Scanning electron microscopy and X-ray scattering were utilized to elucidate the hierarchical structure of the PEEK aerogels. Morphological analysis found that the PEEK/DPA gels were composed of a highly nucleated network of PEEK axialites (i.e., aggregates of stacked crystalline lamellae). The highly connected axialite network imparted robust mechanical properties on PEEK aerogels, which were found to densify less upon freeze-drying than globular PEEK aerogel counterparts gelled from dichloroacetic acid (DCA) or 4-chlorphenol (4CP). PEEK aerogels formed from DPA were also found to have a modulus–density scaling that was far more efficient in supporting loads than the poorly connected aerogels formed from PEEK/DCA or PEEK/4CP solutions. The strut-like morphology in these new PEEK aerogels also significantly improved the modulus to a degree that is comparable to high-performance crosslinked aerogels based on polyimide and polyurea of comparable densities.
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Shocked silica aerogel radiance transition
Silica (SiO2) aerogel is widely used in high-energy-density shock experiments due to its low and adjustable density. Reported here are measurements of the shock velocity, optical radiance, and reflectivity of shocked SiO2 aerogel with initial densities of 0.1, 0.2, and 0.3 g/cm3. These results are compared with similar data from three solid polymorphs of SiO2, silica, quartz, and stishovite with initial densities 2.2, 2.65, and 4.3 g/cm3, respectively. Interestingly, below a brightness temperature of Tbright≈35,000 K, the slope of the radiance vs shock velocity is the same for each of the SiO2 aerogels and solid polymorphs. At Tbright≈35000 K, there is an abrupt change in the radiance vs shock velocity slope for aerogels, but not seen in the solid polymorphs over the pressures and temperatures explored here. An empirical model of shock front radiance as a function of SiO2 density and laser drive parameters is reported to aid in the design of experiments requiring maximum shock front radiance.
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- Award ID(s):
- 2020249
- PAR ID:
- 10439908
- Publisher / Repository:
- American Institute of Physics
- Date Published:
- Journal Name:
- Journal of Applied Physics
- Volume:
- 132
- Issue:
- 9
- ISSN:
- 0021-8979
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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