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In this study, we investigate the utility of Ca2FeMnO6-δand Sr2FeMnO6-δas materials with low thermal conductivity, finding potential applications in thermoelectrics, electronics, solar devices, and gas turbines for land and aerospace use. These compounds, characterized as oxygen-deficient perovskites, feature distinct vacancy arrangements. Ca2FeMnO6-δadopts a brownmillerite-type orthorhombic structure with ordered vacancy arrangement, while Sr2FeMnO6-δadopts a perovskite cubic structure with disordered vacancy distribution. Notably, both compounds exhibit remarkably low thermal conductivity, measuring below 0.50 Wm−1K−1. This places them among the materials with the lowest thermal conductivity reported for perovskites. The observed low thermal conductivity is attributed to oxygen vacancies and phonon scattering. Interestingly as SEM images show the smaller grain size, our findings suggest that creating vacancies and lowering the grain size or increasing the grain boundaries play a crucial role in achieving such low thermal conductivity values. This characteristic enhances the potential of these materials for applications where efficient heat dissipation, safety, and equipment longevity are paramount.
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New Constraints on the Thermal Conductivity of the Upper Mantle From Numerical Models of Radiation Transport
Abstract To address uncertainties in the values and mathematical form of the radiative thermal conductivitykradin the mantle, we developed new models for the transport, scattering, and absorption of thermal radiation in semitransparent multiphase polycrystalline assemblages. We show that the Rosseland diffusion equation correctly describes the diffusion of thermal radiation and infer the form of the effective spectral coefficients through numerical experimentation. We show that the scattering coefficient depends on the grain size and on interphase contact statistics in complicated ways, but that simplifications can be employed in practice. The effective opacity of a composite random material is a harmonically weighted mixture in the limit of infinitely large grain size and an arithmetically weighted mixture in the limit of infinitesimal grain size. Using existing absorption spectra for major upper mantle minerals, we estimatekradas a function of temperature, grain size, and petrology. In mantle assemblages, the scattering effect is important for small grain sizes (<1 mm), but the grain size effect on the effective opacity of a multiphase medium is important for grain sizes up to 10 cm. We calculate that upper mantlekradis about 2–3.5 W·m−1·K−1for a representative mean grain size range of 0.01 to 1 cm. This translates to a total thermal conductivity of 5.5–7 W·m−1·K−1. Application of our model to the cooling of oceanic lithosphere shows thatkradincreases net cooling by about 25%.
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- Award ID(s):
- 1826310
- PAR ID:
- 10453269
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Geochemistry, Geophysics, Geosystems
- Volume:
- 20
- Issue:
- 5
- ISSN:
- 1525-2027
- Page Range / eLocation ID:
- p. 2378-2394
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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