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1. Radiogenic Power and Geoneutrino Luminosity of the Earth and Other Terrestrial Bodies Through Time

   https://doi.org/10.1029/2019GC008865  

   McDonough, W. F. ; Šrámek, O. ; Wipperfurth, S. A. ( July 2020 , Geochemistry, Geophysics, Geosystems)

   We report the Earth's rate of radiogenic heat production and (anti)neutrino luminosity from geologically relevant short‐lived radionuclides (SLR) and long‐lived radionuclides (LLR) using decay constants from the geological community, updated nuclear physics parameters, and calculations of theβspectra. We track the time evolution of the radiogenic power and luminosity of the Earth over the last 4.57 billion years, assuming an absolute abundance for the refractory elements in the silicate Earth and key volatile/refractory element ratios (e.g., Fe/Al, K/U, and Rb/Sr) to set the abundance levels for the moderately volatile elements. The relevant decays for the present‐day heat production in the Earth (19.9 ± 3.0 TW) are from⁴⁰K,⁸⁷Rb,¹⁴⁷Sm,²³²Th,²³⁵U, and²³⁸U. Given element concentrations in kg‐element/kg‐rock and densityρin kg/m³, a simplified equation to calculate the present‐day heat production in a rock isurn:x-wiley:ggge:media:ggge22244:ggge22244-math-0001

   The radiogenic heating rate of Earth‐like material at solar system formation was some 10³to 10⁴times greater than present‐day values, largely due to decay of²⁶Al in the silicate fraction, which was the dominant radiogenic heat source for the first∼10 Ma. Assuming instantaneous Earth formation, the upper bound on radiogenic energy supplied by the most powerful short‐lived radionuclide²⁶Al (t_1/2= 0.7 Ma) is 5.5×10³¹ J, which is comparable (within a factor of a few) to the planet's gravitational binding energy.

    

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2. The Importance of Subsurface Productivity in the Pacific Arctic Gateway as Revealed by High‐Resolution Biogeochemical Surveys

   https://doi.org/10.1029/2022JC019292  

   Juranek, L. W. ; Hales, B. ; Beaird, N. L. ; Goñi, M. A. ; Shroyer, E. ; Allen, J. G. ; White, A. E. ( February 2023 , Journal of Geophysical Research: Oceans)

   Following sea‐ice retreat, surface waters of Arctic marginal seas become nutrient‐limited and subsurface chlorophyll maxima (SCM) develop below the pycnocline where nutrients and light conditions are favorable. However, the importance of these “hidden” features for regional productivity is not well constrained. Here, we use a unique combination of high‐resolution biogeochemical and physical observations collected on the Chukchi shelf in 2017 to constrain the fine‐scale structure of nutrients, O₂, particles, SCM, and turbulence. We find large O₂excess at middepth, identified by positive saturation () maxima of 15%–20% that unambiguously indicate significant production occurring in middepth waters. Themaxima coincided with a complete depletion of dissolved inorganic nitrogen (DIN = NO₃⁻ + NO₂⁻ + NH₄⁺). Nitracline depths aligned with SCM depths and the lowest extent ofmaxima, suggesting this horizon represents a compensation point for balanced growth and loss. Furthermore, SCM were also associated with turbulence minima and sat just above a high turbidity bottom layer where light attenuation increased significantly. Spatially, the largestmaxima were associated with high nutrient winter‐origin water masses (14.8% ± 2.4%), under a shallower pycnocline associated with seasonal melt while lower values were associated with summer‐origin water masses (7.4% ± 3.9%). Integrated O₂excesses of 800–1,200 mmol m⁻²in regions overlying winter water are consistent with primary production rates that are 12%–40% of previously reported regional primary production. These data implicate short‐term and long‐term control of SCM and associated productivity by stratification, turbulence, light, and seasonal water mass formation, with corresponding potential for climate‐related sensitivities.

    

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3. Seasonal Variation of the D‐Region Ionosphere: Very Low Frequency (VLF) and Machine Learning Models

   https://doi.org/10.1029/2021JA029689  

   Richardson, David K. ; Cohen, Morris B. ( September 2021 , Journal of Geophysical Research: Space Physics)

   The D‐region ionosphere (6090 km) plays an important role in long‐range communication and response to solar and space weather; however, it is difficult to directly measure with currently available technology. Very low frequency (VLF) radio remote sensing is one of the more promising approaches, using the efficient reflection of VLF waves from the D‐region. A number of VLF beacons can therefore be turned into diagnostic tools. VLF remote sensing techniques are useful and can provide global coverage, but in practice have been applied to a limited area and often on only a small number of days. In this work, we expand the use of a recently introduced machine learning based approach (Gross & Cohen, 2020,https://doi.org/10.1029/2019JA027135) to observe and model the D‐region electron density using VLF transmitting beacons and receivers. We have extended the model to cover nighttime in addition to daytime, and have applied it to track D‐region waveguide parameters, h’ and, over 400 daytimes and 150 nighttimes on up to 21 transmitter‐receiver paths across the continental US. Using an exponential fit, h’ represents the height of the ionosphere andrepresents the slope of the electron density. Using this data set, we quantify diurnal, daily and seasonal variations of the D‐region ionosphere for both daytime and nighttime D‐region ionosphere. We show that our model identifies expected variations, as well as producing results in line with other previous studies. Additionally, we show that our daytime predictions exhibit a larger autocorrelation at higher time lags than our nighttime predictions, indicating a model with persistence may perform better.

    

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4. Turbulent Flux Measurements of the Near‐Surface and Residual‐Layer Small Particle Events

   https://doi.org/10.1029/2021JD036289  

   Islam, M. M. ; Meskhidze, N. ; Rasheeda Satheesh, A. ; Petters, M. D. ( September 2022 , Journal of Geophysical Research: Atmospheres)

   According to recent field studies, almost half of the New Particle Formation (NPF) events occur aloft, in a residual layer, near the top of the boundary layer. Therefore, measurements of the meteorological parameters, precursor gas concentrations, and aerosol loadings conducted at the ground level are often not representative of the conditions where the NPFs take place. This paper presents new measurements obtained during the Turbulent Flux Measurements of the Residual Layer Nucleation Particles, conducted at the Southern Great Plains research site. Vertical turbulent fluxes of 3–10 nm‐sized particles were measured using a sonic anemometer and two condensation particle counters with nominal cutoff diameters of3 nm and10 nm mounted at the top of the 10‐m telescoping tower. Aerosol number size distribution (5–300 nm) was determined through the ground‐based Scanning Mobility Particle Sizers. The size selected (15–50 nm) particle hygroscopicity was derived with the Humidified Tandem Differential Mobility Analyzer. The ground level observations were supplemented by vertically‐resolved measurements of horizontal and vertical wind speeds and aerosol backscatter. The data analysis suggests that (a) turbulent flux measurements of 3–10 nm particles can distinguish between near‐surface and residual‐layer small particle events; (b) sub‐50 nm particles had a hygroscopicity value of 0.2, suggesting that organic compounds dominate atmospheric nanoparticle chemical composition at the site; and (c) current methodologies are inadequate for estimating the dry deposition velocity of sub‐10 nm particles because it is not feasible to measure particle concentration very near the surface, in the diffusion sublayer.

    

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5. Thermal and Magnetic Field Switching in a Two‐Step Hysteretic Mn III Spin Crossover Compound Coupled to Symmetry Breakings

   https://doi.org/10.1002/anie.202114021  

   Dobbelaar, Emiel ; Jakobsen, Vibe B. ; Trzop, Elzbieta ; Lee, Minseong ; Chikara, Shalinee ; Ding, Xiaxin ; Müller‐Bunz, Helge ; Esien, Kane ; Felton, Solveig ; Carpenter, Michael A. ; et al ( December 2021 , Angewandte Chemie International Edition)

   A Mn^IIIspin crossover complex with atypical two‐step hysteretic thermal switching at 74 K and 84 K shows rich structural–magnetic interplay and magnetic‐field‐induced spin state switching below 14 T with an onset below 5 T. The spin states, structures, and the nature of the phase transitions are elucidated via X‐ray and magnetization measurements. An unusual intermediate phase containing four individual sites, whereare in a pure low spin state, is observed. The splitting of equivalent sites in the high temperature phase into four inequivalent sites is due to a structural reorganization involving a primary and a secondary symmetry‐breaking order parameter that induces a crystal system change from orthorhombic→monoclinic and a cell doubling. Further cooling leads to a reconstructive phase transition and a monoclinic low‐temperature phase with two inequivalent low‐spin sites. The coupling between the order parameters is identified in the framework of Landau theory.

    

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