Young mafic lavas from the East African Western Rift record melting of subcontinental lithospheric mantle that was metasomatically modified by multiple tectonic events. We report new isotope data from monogenetic cinder cones near Bufumbira, Uganda, in the Virunga Volcanic Field:87Sr/86Sr = 0.7059–0.7079,
The accessory minerals rutile and apatite are rare or absent in the convecting upper mantle but occur in shallow, cooler, metasomatized continental lithospheric mantle (CLM) where they serve as carrier phases for the trace elements Ta (in rutile) and Th (in apatite). Because both minerals crystallize near‐solidus and are eliminated early during partial mantle melting, the relative abundances of rutile and apatite should control the Ta and Th abundances of mantle melts and provide a means of identifying the involvement of rutile‐ and/or apatite‐bearing metasomatized CLM in mafic continental magmatism. As a test, we investigated published Ta and Th abundances data from ~2,000 whole‐rock samples of mafic to intermediate composition, Cenozoic volcanic rocks in southwestern North America. Roughly half of the samples have Ta/Th values similar to those of island arc volcanic rocks (<0.2) or ocean island and mid‐ocean ridge basalts (>0.6). The remaining samples have intermediate and variable Ta/Th values between 0.2 and 0.6, independent of specific indices of crustal interaction (e.g., wt% P2O5/wt% K2O). We interpret the intermediate Ta/Th rocks as the products of direct melting of, or of extensive melt‐rock interaction with, rutile‐ and/or apatite‐bearing CLM. Intermediate Ta/Th rocks also have uniformly high87Sr/86Sr (0.706 to 0.708) compared to oceanic basalts that, unlike their Nd isotopic compositions, do not covary with lithospheric age. These observations are consistent with widespread metasomatism of the CLM by Sr‐rich, Nd‐poor, aqueous fluids generated by dehydration of oceanic lithosphere, and its overlying tectonic mélange during early Cenozoic subduction beneath southwestern North America.
more » « less- NSF-PAR ID:
- 10454452
- Publisher / Repository:
- DOI PREFIX: 10.1029
- Date Published:
- Journal Name:
- Geochemistry, Geophysics, Geosystems
- Volume:
- 21
- Issue:
- 5
- ISSN:
- 1525-2027
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract ε Nd = −6.5 to −1.3,ε Hf = −6.3 to +0.9,208Pb/204Pb = 40.1–40.7,207Pb/204Pb = 15.68–15.75, and206Pb/204Pb = 19.27–19.45. Olivine phenocrysts from the Bufumbira lavas have3He/4He = 6.0–7.4R A. The isotopic data, in conjunction with major and trace element systematics, indicate that primitive Bufumbira magmas are derived from two different metasomatized lithospheric source domains. Melts generated by lower degrees of melting record greater contributions from ∼1 to 2 Ga isotopically enriched garnet‐amphibole‐phlogopite pyroxenite veins within the lithosphere. As melting progresses, these vein melts become increasingly diluted by melts that originate near the lithosphere/asthenosphere boundary, shifting the isotopic compositions toward the common lithospheric mantle (CLM) proposed by Furman and Graham (1999,https://doi.org/10.1016/s0024-4937(99)00031-6 ). This ∼450–500 Ma source domain appears to underlie all Western Rift volcanic provinces and is characterized by87Sr/86Sr ∼ 0.705,ε Nd∼ 0,ε Hf∼ +1 to +3,206Pb/204Pb ∼ 19.0–19.2,208Pb/204Pb ∼ 39.7, and3He/4He ∼ 7R A. Basal portions of the dense subcontinental lithospheric mantle may become gravitationally unstable and founder into underlying warmer asthenosphere, exposing surfaces where melting of locally heterogeneous veins produces small‐volume, alkaline mafic melts. Mafic lavas from all Western Rift volcanic provinces record mixing between the CLM and locally variable metasomatized source domains, suggesting this style of melt generation is fundamental to the development of magma‐poor rifts. -
null (Ed.)Abstract Mantle source heterogeneity and magmatic processes have been widely studied beneath most parts of the Southwest Indian Ridge (SWIR). But less is known from the newly recovered mid-ocean ridge basalts from the Dragon Bone Amagmatic Segment (53°E, SWIR) and the adjacent magmatically robust Dragon Flag Segment. Fresh basalt glasses from the Dragon Bone Segment are clearly more enriched in isotopic composition than the adjacent Dragon Flag basalts, but the trace element ratios of the Dragon Flag basalts are more extreme compared with average mid-ocean ridge basalts (MORB) than the Dragon Bone basalts. Their geochemical differences can be explained only by source differences rather than by variations in degree of melting of a roughly similar source. The Dragon Flag basalts are influenced by an arc-like mantle component as evidenced by enrichment in fluid-mobile over fluid-immobile elements. However, the sub-ridge mantle at the Dragon Flag Segment is depleted in melt component compared with a normal MORB source owing to previous melting in the subarc. This fluid-metasomatized, subarc depleted mantle is entrained beneath the Dragon Flag Segment. In comparison, for the Dragon Bone axial basalts, their Pb isotopic compositions and their slight enrichment in Ba, Nb, Ta, K, La, Sr and Zr and depletion in Pb and Ti concentrations show resemblance to the Ejeda–Bekily dikes of Madagascar. Also, Dragon Bone Sr and Nd isotopic compositions together with the Ce/Pb, La/Nb and La/Th ratios can be modeled by mixing the most isotopically depleted Dragon Flag basalts with a composition within the range of the Ejeda–Bekily dikes. It is therefore proposed that the Dragon Bone axial basalts, similar to the Ejeda–Bekily dikes, are sourced from subcontinental lithospheric Archean mantle beneath Gondwana, pulled from beneath the Madagascar Plateau. The recycling of the residual subarc mantle and the subcontinental lithospheric mantle could be related to either the breakup of Gondwana or the formation and accretion of Neoproterozoic island arc terranes during the collapse of the Mozambique Ocean, and is now present beneath the ridge.more » « less
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PhD Dissertation Abstract: The imposing andesite stratovolcano is the characteristic expression of subduction zone magmatism, posing hazards to coastal populations and bearing insight into deep Earth processes. On a map of a typical volcanic arc, one can easily distinguish the approximately linear alignment and regular spacing of these major edifices that stand out from a diffuse distribution of mafic volcanoes (e.g. the Quaternary Cascades; Hildreth, 2007). The andesitic composite volcanoes have a reputation for being complex, open systems: crystal zoning “stratigraphies,” diverse crystal cargoes including antecrysts or xenocrysts, quenched magmatic inclusions, and variations in isotopic signatures are among the many lines of evidence that these systems involve a variety of igneous processes and melt sources. 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Abstract The Payenia region of Argentina (34.5–38°S) is a large Pliocene‐Quaternary volcanic province of basaltic compositions in the Andean Cordillera foothills representing the northernmost extent of back‐arc volcanism in the Andean Southern Volcanic Zone (SVZ). Although the chemical diversity of the Payenia basalts has been characterized previously, the processes and sources responsible for such variation remain controversial. Here, we report new whole‐rock major and trace element concentrations, Sr‐, Nd‐, Hf‐, and Pb‐isotope ratios and high‐precision olivine oxygen‐isotope ratios in a suite of 35 alkaline basalts from Payenia. These lavas have major and trace elements that define a compositional range from arc‐influenced to intraplate signature. Variable crustal contamination and/or recent slab‐derived inputs inadequately account for elemental and isotopic systematics and spatial compositional variations of Payenia lavas. We present a simple forward model indicating that early metasomatism and subsequent melting of the metasomatized subcontinental lithospheric mantle (SCLM) has significantly contributed to the Payenia lava compositional range. Isotopic ingrowth calculations of radiogenic Sr, Nd, Hf, and Pb suggest that the SCLM metasomatism occurred at 50–150 Ma, consistent with the timing of the breakup of Gondwana and the development of the proto‐Pacific Andean arc. Variations in δ18Oolivinevalues from modeled melts indicate that the metasomatism and melting within the SCLM can fractionate oxygen isotopes even when the metasomatizing melt has MORB‐like δ18O values, providing a different explanation for the low‐δ18O signatures observed in continental arc settings.
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The Gejiu alkaline complex (GAC) within the western part of the Youjiang Basin provides a window to investigate the evolution in the junction of Cathaysia, Yangtze and Indochina blocks. Here, we investigate the GAC in terms of their petrology, zircon U–Pb geochronology, whole‐rock geochemistry, and Sr–Nd isotopic data to gain insights into the origin and evolution of the alkaline magma. The GAC is lithologically composed of alkali syenites and feldspathoid syenites, in which some were altered into sericite syenites. Zircon U–Pb dating of the alkali syenites yielded an age of 85.03 ± 0.47 Ma, which is slightly older than the feldspathoid syenites. The alkali syenites and feldspathoid syenites are silica‐saturated and silica‐undersaturated, respectively, and are characterized by high alkalinity with K2O + Na2O of 11.55–17.08 wt% and Al2O3of 18.57–22.49 wt%, low MgO of 0.11–1.39 wt%, weakly negative Eu anomalies, enrichments of LILEs such as Th and U, HFSEs like Zr and Hf but depletion of Ba, Sr, Nb, Ta, P, Ti, strongly fractionated LREEs to HREEs. Their uniform Sr–Nd isotope composition with initial87Sr/86Sr = 0.708802–0.710571 and
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