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Title: Dissociative photoionization of 1,3‐dioxolane: We need six channels to fit the elephant
Abstract

The dissociative photoionization of 1,3‐dioxolane was studied by photoelectron photoion coincidence (PEPICO) spectroscopy in the photon energy range of 9.5–13.5 eV. Our statistical thermodynamics model shows that a total of six dissociation channels are involved in the formation of three fragment ions, namely, C3H5O2+(m/z73), C2H5O+(m/z45), and C2H4O+(m/z44), with two channels contributing to the formation of each. By comparing the results of ab initio quantum chemical calculations to the experimentally derived appearance energies of the fragment ions, the most likely mechanisms for these unimolecular dissociation reactions are proposed, including a description of the relevant parts of the potential energy surface.

 
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Award ID(s):
1665464
NSF-PAR ID:
10456487
Author(s) / Creator(s):
 ;  ;  ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
Journal of Mass Spectrometry
Volume:
55
Issue:
9
ISSN:
1076-5174
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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