Three‐dimensional (3D) organic–inorganic metal halide perovskite materials possess great potential applications for approaching efficient optoelectronics due to the unique optoelectronic properties of perovskite materials and cost‐effective manufacturing possibilities of optoelectronics. However, the scientific and technical challenges of 3D perovskite materials were their inferior long‐term stability, which hampered their practical applications. The low‐dimensional perovskite materials composed of alternating organic and inorganic layers are one of the most credible paths toward stable perovskite photovoltaics and optoelectronics. In this short review, we first present a discussion of the crystal structure and nontrivial optoelectronic properties of the low‐dimensional halide perovskites. The synthetic methods for the preparation of the low‐dimensional halide perovskites are reviewed. After that, we focus on the recent development of perovskite photovoltaics, light‐emitting diodes, and lasers by the low‐dimensional halide perovskites. Finally, we outline the challenges of the low‐dimensional halide perovskites and their applications.
Materials science evolves to a state where the composition and structure of a crystal can be controlled almost at will. Given that a composition meets basic requirements of stoichiometry, steric demands, and charge neutrality, researchers are now able to investigate a wide range of compounds theoretically and, under various experimental conditions, select the constituting fragments of a crystal. One intriguing playground for such materials design is the perovskite structure. While a game of mixing and matching ions has been played successfully for about 150 years within the limits of inorganic compounds, the recent advances in organic–inorganic hybrid perovskite photovoltaics have triggered the inclusion of organic ions. Organic ions can be incorporated on all sites of the perovskite structure, leading to hybrid (double, triple, etc.) perovskites and inverse (hybrid) perovskites. Examples for each of these cases are known, even with all three sites occupied by organic molecules. While this change from monatomic ions to molecular species is accompanied with increased complexity, it shows that concepts from traditional inorganic perovskites are transferable to the novel hybrid materials. The increased compositional space holds promising new possibilities and applications for the universe of perovskite materials.
more » « less- Award ID(s):
- 1719353
- NSF-PAR ID:
- 10458590
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Materials
- Volume:
- 31
- Issue:
- 47
- ISSN:
- 0935-9648
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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This article is categorized under:
Structure and Mechanism > Computational Materials Science
Electronic Structure Theory > Density Functional Theory
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