Carbon fiber reinforced polymer (CFRP) is one of promising lightweight materials for advanced air mobility (and electrical vehicles) due to the high strength, low density, and corrosion resistance. On the other hand, CFRP is more expensive than many lightweight alloys, difficult to join, less fire-resistant, lower conductivities in thermal and electrical energy, more sensitive in processing defects, and more difficult to inspect its structural damages. To improve the multifunctionality desired by advanced air mobility, CFRP could be modified with nanoparticles. Nanofiber z-threaded CFRP (ZT-CFRP) technology utilizes millions of long carbon nanofibers to z-directionally thread through all carbon fibers in per square-centimeters of ZT-CFRP prepreg. The ZT-CFRP enhanced the mechanical properties, thermal conductivity, and electrical conductivity. The unique 3D-multicscaled fiber-reinforced microstructure also provide additional performance such as enhanced resistance against the property degradation caused by void, enhanced flame-retardance, improved adhesive-joint (i.e., bond line) strength, and enhanced thermal infrared damage/defect evaluation resolutions. This paper will overview the ZT-CFRP performances along with the state of ZT-CFRP prepreg process development including the scaled up roll-to-roll hot-melt manufacturing process of the ZT-CFRP prepreg. Its potentially useful multifunctional attributes for advanced air mobility will also be discussed in this paper.
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Multifunctionality through Embedding Patterned Nanostructures in High‐Performance Composites
Despite being a pillar of high‐performance materials in industry, manufacturing carbon fiber composites with simultaneously enhanced multifunctionality and structural properties has remained elusive due to the lack of practical bottom‐up approaches with control over nanoscale interactions. Guided by the droplet's internal currents and amphiphilicity of nanomaterials, herein, a programmable spray coating is introduced for the deposition of multiple nanomaterials with tailorable patterns in composite. It is shown that such patterns regulate the formation of interfaces, damage containment, and electrical‐thermal conductivity of the composites, which is absent in conventional manufacturing that primarily rely on incorporating nanomaterials to achieve specific functionalities. Molecular dynamics simulations show that increasing the hydrophilicity of the hybrid nanomaterials, which is synchronous with shifting patterns from disk to ring, improves the interactions between the carbon surfaces and epoxy at the interfaces,manifested in enhanced interlaminar and flexural performance. Transitioning from ring to disk creates a larger interconnected network leading to improved thermal and electrical properties without penalty in mechanical properties. This novel approach introduces a new design , where the mechanical and multifunctional performance is controlled by the shape of the deposited patterns, thus eliminating the trade‐off between properties that are considered paradoxical in today's manufacturing of hierarchical composites.
more » « less- PAR ID:
- 10469210
- Publisher / Repository:
- Wiley
- Date Published:
- Journal Name:
- Advanced Materials
- Volume:
- 35
- Issue:
- 32
- ISSN:
- 0935-9648
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1002/adma.202300948
