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1. Exploring sulfur donor atom coordination chemistry with La( ii ), Nd( ii ), and Tm( ii ) using a terphenylthiolate ligand

   https://doi.org/10.1039/d4cc01037j  

   Gilbert-Bass, Kito; Stennett, Cary R.; Grotjahn, Robin; Ziller, Joseph W.; Furche, Filipp; Evans, William J. (April 2024, Chemical Communications)

   To expand the range of donor atoms known to stabilize 4fⁿ5d¹Ln(ii) ions beyond C, N, and O first row main group donor atoms, the Ln(iii) terphenylthiolate iodides, Ln^III(SAr^iPr6)₂I (Ar^iPr6= C₆H₃-2,6-(C₆H₂-2,4,6-ⁱPr₃)₂, Ln = La, Nd) were reduced to Ln^II(SAr^iPr6)₂complexes. 

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2. Carbon isotope trends across a century of herbarium specimens suggest CO ₂ fertilization of C ₄ grasses

   https://doi.org/10.1111/nph.19868  

   del_Toro, Isa; Case, Madelon_F; Tyler_Karp, A.; Slingsby, Jasper_A; Staver, A_Carla (May 2024, New Phytologist)

   Summary Increasing atmospheric CO₂is changing the dynamics of tropical savanna vegetation. C₃trees and grasses are known to experience CO₂fertilization, whereas responses to CO₂by C₄grasses are more ambiguous.Here, we sample stable carbon isotope trends in herbarium collections of South African C₄and C₃grasses to reconstruct¹³C discrimination.We found that C₃grasses showed no trends in¹³C discrimination over the past century but that C₄grasses increased their¹³C discrimination through time, especially since 1950. These changes were most strongly linked to changes in atmospheric CO₂rather than to trends in rainfall climatology or temperature.Combined with previously published evidence that grass biomass has increased in C₄‐dominated savannas, these trends suggest that increasing water‐use efficiency due to CO₂fertilization may be changing C₄plant–water relations. CO₂fertilization of C₄grasses may thus be a neglected pathway for anthropogenic global change in tropical savanna ecosystems. 

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3. Searching for C ii Emission from the First Sample of z ∼ 6 O i Absorption-associated Galaxies with the Atacama Large Millimeter/submillimeter Array

   https://doi.org/10.3847/1538-4357/ad00b8  

   Wu, Yunjing; Cai, Zheng; Li, Jianan; Finlator, Kristian; Neeleman, Marcel; Prochaska, J Xavier; Emonts, Bjorn_H C; Zhang, Shiwu; Wang, Feige; Yang, Jinyi; et al (November 2023, The Astrophysical Journal)

   Abstract We report the first statistical analyses of [Cii] and dust continuum observations in six strong Oiabsorber fields at the end of the reionization epoch obtained by the Atacama Large Millimeter/submillimeter Array (ALMA). Combined with one [Cii] emitter reported in Wu et al., we detect one Oi-associated [Cii] emitter in six fields. At redshifts of Oiabsorbers in nondetection fields, no emitters are brighter than our detection limit within impact parameters of 50 kpc and velocity offsets between ±200 km s⁻¹. The averaged [Cii]-detection upper limit is <0.06 Jy km s⁻¹(3σ), corresponding to the [Cii] luminosity ofL_[CII]< 5.8 × 10⁷L_⊙and the [Cii]-based star formation rate of SFR_[CII]<5.5M_⊙yr⁻¹. Cosmological simulations suggest that only ∼10^−2.5[Cii] emitters around Oiabsorbers have comparable SFR to our detection limit. Although the detection in one out of six fields is reported, an order of magnitude number excess of emitters obtained from our ALMA observations supports that the contribution of massive galaxies that caused the metal enrichment cannot be ignored. Further, we also found 14 tentative galaxy candidates with a signal-to-noise ratio of ≈4.3 at large impact parameters (>50 kpc) and having larger outflow velocities within ±600 km s⁻¹. If these detections are confirmed in the future, then the mechanism of pushing metals at larger distances with higher velocities needs to be further explored from the theoretical side. 

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4. ND70 Series Basaltic Glass Reference Materials for Volatile Element ( H₂O , CO₂ , S, Cl, F) Measurement and the C Ionisation Efficiency Suppression Effect of Water in Silicate Glasses in SIMS

   https://doi.org/10.1111/ggr.12572  

   Moussallam, Yves; Towbin, William Henry; Plank, Terry; Bureau, Hélène; Khodja, Hicham; Guan, Yunbin; Ma, Chi; Baker, Michael B; Stolper, Edward M; Naab, Fabian U; et al (July 2024, Geostandards and Geoanalytical Research)

   We present a new set of reference materials, the ND70‐series, forin situmeasurement of volatile elements (H₂O, CO₂, S, Cl, F) in silicate glass of basaltic composition. The materials were synthesised in piston cylinders at pressures of 1 to 1.5 GPa under volatile‐undersaturated conditions. They span mass fractions from 0 to 6%m/mH₂O, from 0 to 1.6%m/mCO₂and from 0 to 1%m/mS, Cl and F. The materials were characterised by elastic recoil detection analysis for H₂O, by nuclear reaction analysis for CO₂, by elemental analyser for CO₂, by Fourier transform infrared spectroscopy for H₂O and CO₂, by secondary ion mass spectrometry for H₂O, CO₂, S, Cl and F, and by electron probe microanalysis for CO₂, S, Cl and major elements. Comparison between expected and measured volatile amounts across techniques and institutions is excellent. It was found however that SIMS measurements of CO₂mass fractions using either Cs⁺or O⁻primary beams are strongly affected by the glass H₂O content. Reference materials have been made available to users at ion probe facilities in the US, Europe and Japan. Remaining reference materials are preserved at the Smithsonian National Museum of Natural History where they are freely available on loan to any researcher. 

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5. Chemical composition tuning induced variable and enhanced dielectric properties of polycrystalline Ga_2‐2xW_xO₃ ceramics

   https://doi.org/10.1002/eng2.12300  

   Zade, Vishal B.; Rajkumar, Mohan R.; Broner, Ron; Ramana, Chintalapalle V. (December 2020, Engineering Reports)

   Abstract We report on the tunable and enhanced dielectric properties of tungsten (W) incorporated gallium oxide (Ga₂O₃) polycrystalline electroceramics for energy and power electronic device applications. The W‐incorporated Ga₂O₃(Ga_2−2xW_xO₃, 0.00 ≤ x ≤ 0.20; GWO) compounds were synthesized by the high‐temperature solid‐state chemical reaction method by varying the W‐content. The fundamental aspects of the dielectric properties in correlation with the crystal structure, phase, and microstructure of the GWO polycrystalline compounds has been investigated in detail. A detailed study performed ascertains the W‐induced changes in the dielectric constant, loss tangent (tanδ) and ac conductivity. It was found that the dielectric constant increases with addition of W in the system as a function of temperature (25°C‐500°C). Frequency dependence (10²‐10⁶ Hz) of the dielectric constant follows the modified Debye model with a relaxation time of ∼20 to 90 μs and a spreading factor of 0.39 to 0.65. The dielectric constant of GWO is temperature independent almost until ∼300°C, and then increases rapidly in the range of 300°C to 500°C. W‐induced enhancement in the dielectric constant of GWO is fully evident in the frequency and temperature dependent dielectric studies. The frequency and temperature dependent tanδreveals the typical behavior of relaxation loses in GWO. Small polaron hopping mechanism is evident in the frequency dependent electrical transport properties of GWO. The remarkable effect of W‐incorporation on the dielectric and electrical transport properties of Ga₂O₃is explained by a two‐layer heterogeneous model consisting of thick grains separated by very thin grain boundaries along with the formation of a Ga₂O₃‐WO₃composite was able to account for the observed temperature and frequency dependent electrical properties in GWO. The results demonstrate that the structure, electrical and dielectric properties can be tailored by tuning W‐content in the GWO compounds. 

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