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1. D/H ratios and H2O contents record degassing and rehydration history of rhyolitic magma and pyroclasts

   Thomas Giachetti, Michael R.Hudak (January 2019, Earth and planetary science letters)

   Volcanic eruptions of rhyolitic magma often show shifts from powerful (Vulcanian to Plinian) explosive episodes to a more gentle effusion of viscous lava forming obsidian flows. Another prevailing characteris-tic of these eruptions is the presence of pyroclastic obsidians intermingled with the explosive tephra. This dense, juvenile product is similar to the tephra and obsidian flow in composition, but is generally less degassed than its flow counterpart. The formation mechanism(s) of pyroclastic obsidians and the information they can provide concerning the extent to which magma degassing modulates the eruptive style of rhyolitic eruptions are currently subject to active research. Porous tephra and pyroclastic and flow obsidians from the 1060CE Glass Mountain rhyolitic eruption at Medicine Lake Volcano (California) were analyzed for their porosity, φ, water content, H2O, and hydrogen isotopic composition, δD. H2O in porous pyroclasts is correlated negatively with δD and positively with φ, indicating that the samples were affected by post-eruptive rehydration. Numerical modeling suggests that this rehydration occurred at an average rate of 10−23.5±0.5m2s−1during the ∼960 years since the eruption, causing some pyroclasts to gain up to 1 wt%of meteoric water. Pyroclastic and flow obsidians were not affected by rehydration due to their very low porosity. Comparison between modeled δD-H2O relationships in degassing magma and values measured in the Glass Mountain samples supports the idea that rhyolitic magma degasses in closed-system until its porosity reaches a value of about 65±5%, beyond which degassing occurs in open-system until quench. During the explosive phase, rapidly ascending magma fragments soon after it becomes permeable, creating porous lapilli and ash that continue to degas in open-system within an expanding gas phase. As suggested by recent studies, some ash may aggregate and sinter on the conduit sides at different depths above the fragmentation level, partly equilibrating with the continuously fluxing heavier magmatic vapor, explaining the wide range of H2O contents and high variability in δD measured in the pyroclastic obsidians. Using only H2O and δD, it is impossible to rule out the possibility that pyroclastic obsidians may also form by permeable foam collapse, either syn-explosively near the conduit sides below the fragmentation level or during more effusive periods interspersed in the explosive phase. During the final effusive phase of the eruption, slowly ascending magma degasses in open-system until it reaches the surface, creating flows with low H2O and δD. This study shows that H2O measured in highly porous pyroclasts of a few hundred years or more cannot be used to infer syn-eruptive magma degassing pathways, unless careful assessment of post-eruptive rehydration is first carried out. If their mechanism of formation can be better understood, detailed analysis of the variations in texture and volatile content of pyroclastic obsidians throughout the explosive phase may help decipher the reasons why rhyolitic eruptions commonly shift from explosive to effusive phases. 

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2. Characterising the wind-advected medial fall deposit from fissure 8 fountaining during the 2018 lower East Rift Zone eruption, Kīlauea

   https://doi.org/10.1007/s00445-023-01668-7  

   Watts, Emma J.; Cockshell, Wendy A.; Houghton, Bruce F. (September 2023, Bulletin of Volcanology)

   Abstract The 2018 eruption on the lower East Rift Zone, Hawaii, involved the opening of 24 fissures before the eruption focussed on a single point source, fissure 8 (F8). This study characterises the preserved medial F8 tephra deposit using an isopach map, maximum clast size data, and total grain size distribution analysis, shedding light on the tephra transport and dispersal mechanisms beyond the F8 cone occurring during the fountaining. The medial sheet-like deposit covers approximately 0.22 km², best fit by a Power-Law thinning rate. The TephraFits model estimated the corresponding volume of the continuous medial tephra blanket to be ~ 2$$\times$$ $\times$10⁴m³, just 0.02% of the total volume erupted from fissure 8. Samples from the preserved medial deposit have grain size modes of − 3.5 to − 4 Φ, compatible with Voronoi tessellation calculations. Maximum clast size did not show a ‘typical’ fining relationship with distance from the vent; instead, it shows no clear pattern. One factor was that the extremely low clast density, a function of a secondary vesiculation event, enabled the pyroclasts to be re-entrained, often repeatedly, by large eddies downwind of the vent. This should be considered in future studies of prolonged fountaining episodes as the clasts involved in the medial fall are rarely well preserved in the geologic record due to their fragile nature but their presence adds complexity to the inferred eruption dynamics. 

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3. Airfall volume of the 15 January 2022 eruption of Hunga volcano estimated from ocean color changes

   https://doi.org/10.1007/s00445-024-01744-6  

   Kelly, Liam_J; Fauria, Kristen_E; Manga, Michael; Cronin, Shane_J; Latu’ila, Folauhola_Helina; Paredes-Mariño, Joali; Mittal, Tushar; Bennartz, Ralf (May 2024, Bulletin of Volcanology)

   Abstract On 15 January 2022, Hunga volcano erupted, creating an extensive and high-reaching umbrella cloud over the open ocean, hindering traditional isopach mapping and fallout volume estimation. In MODIS satellite imagery, ocean surface water was discolored around Hunga following the eruption, which we attribute to ash fallout from the umbrella cloud. By relating intensity of ocean discoloration to fall deposit thicknesses in the Kingdom of Tonga, we develop a methodology for estimating airfall volume over the open ocean. Ash thickness measurements from 41 locations are used to fit a linear relationship between ash thickness and ocean reflectance. This produces a minimum airfall volume estimate of$${1.8}_{-0.4}^{+0.3}$$ ${1.8}_{-0.4}^{+0.3}$km³. The whole eruption produced > 6.3 km³of uncompacted pyroclastic material on the seafloor and a caldera volume change of 6 km³DRE. Our fall estimates are consistent with the interpretation that most of the seafloor deposits were emplaced by gravity currents rather than fall deposits. Our proposed method does not account for the largest grain sizes, so is thus a minimum estimate. However, this new ocean-discoloration method provides an airfall volume estimate consistent with other independent measures of the plume and is thus effective for rapidly estimating fallout volumes in future volcanic eruptions over oceans. 

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4. Evidence for Environmental Effects in the z = 4.3 Protocluster Core SPT2349–56

   https://doi.org/10.3847/2041-8213/adc1c9  

   Hughes, Chayce; Hill, Ryley; Chapman, Scott C; Aravena, Manuel; Archipley, Melanie; Dike, Veronica J; Gonzalez, Anthony; Greve, Thomas R; Gururajan, Gayathri; Hayward, Chris; et al (April 2025, The Astrophysical Journal Letters)

   Abstract We present Atacama Large Millimeter/submillimeter Array observations of the [CI] 492 and 806 GHz fine-structure lines in 25 dusty star-forming galaxies (DSFGs) atz= 4.3 in the core of the SPT2349–56 protocluster. The protocluster galaxies exhibit a median $L_{\left[\text{C}\mathrm{I}\right](2-1)}^{\prime }/L_{\left[\text{C}\mathrm{I}\right](1-0)}^{\prime }$ratio of 0.94, with an interquartile range of 0.81–1.24. These ratios are markedly different to those observed in DSFGs in the field (across a comparable redshift and 850μm flux density range), where the median is 0.55, with an interquartile range of 0.50–0.76, and we show that this difference is driven by an excess of [Ci](2–1) in the protocluster galaxies for a given 850μm flux density. Assuming local thermal equilibrium, we estimate gas excitation temperatures of $T_{\mathrm{ex}}=59.1_{-6.8}^{+8.1}$K for our protocluster sample and $T_{\mathrm{ex}}=33.9_{-2.2}^{+2.4}$K for the field sample. Our main interpretation of this result is that the protocluster galaxies have had their cold gas driven to their cores via close-by interactions within the dense environment, leading to an overall increase in the average gas density and excitation temperature, as well as an elevated [Ci](2–1) luminosity-to-far-infrared-luminosity ratio. 

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5. Global reconstruction reduces the uncertainty of oceanic nitrous oxide emissions and reveals a vigorous seasonal cycle

   https://doi.org/10.1073/pnas.1921914117  

   Yang, Simon; Chang, Bonnie X.; Warner, Mark J.; Weber, Thomas S.; Bourbonnais, Annie M.; Santoro, Alyson E.; Kock, Annette; Sonnerup, Rolf E.; Bullister, John L.; Wilson, Samuel T.; et al (May 2020, Proceedings of the National Academy of Sciences)

   Assessment of the global budget of the greenhouse gas nitrous oxide ( ${\mathrm{N}}_2$O) is limited by poor knowledge of the oceanic ${\mathrm{N}}_2$O flux to the atmosphere, of which the magnitude, spatial distribution, and temporal variability remain highly uncertain. Here, we reconstruct climatological ${\mathrm{N}}_2$O emissions from the ocean by training a supervised learning algorithm with over 158,000 ${\mathrm{N}}_2$O measurements from the surface ocean—the largest synthesis to date. The reconstruction captures observed latitudinal gradients and coastal hot spots of ${\mathrm{N}}_2$O flux and reveals a vigorous global seasonal cycle. We estimate an annual mean ${\mathrm{N}}_2$O flux of 4.2 ± 1.0 Tg N $\cdot {\mathrm{y}}^{-1}$, 64% of which occurs in the tropics, and 20% in coastal upwelling systems that occupy less than 3% of the ocean area. This ${\mathrm{N}}_2$O flux ranges from a low of 3.3 ± 1.3 Tg N $\cdot {\mathrm{y}}^{-1}$in the boreal spring to a high of 5.5 ± 2.0 Tg N $\cdot {\mathrm{y}}^{-1}$in the boreal summer. Much of the seasonal variations in global ${\mathrm{N}}_2$O emissions can be traced to seasonal upwelling in the tropical ocean and winter mixing in the Southern Ocean. The dominant contribution to seasonality by productive, low-oxygen tropical upwelling systems (>75%) suggests a sensitivity of the global ${\mathrm{N}}_2$O flux to El Niño–Southern Oscillation and anthropogenic stratification of the low latitude ocean. This ocean flux estimate is consistent with the range adopted by the Intergovernmental Panel on Climate Change, but reduces its uncertainty by more than fivefold, enabling more precise determination of other terms in the atmospheric ${\mathrm{N}}_2$O budget. 

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