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1. A model of d -wave superconductivity, antiferromagnetism, and charge order on the square lattice

   https://doi.org/10.1073/pnas.2302701120  

   Christos, Maine ; Luo, Zhu-Xi ; Shackleton, Henry ; Zhang, Ya-Hui ; Scheurer, Mathias S. ; Sachdev, Subir ( May 2023 , Proceedings of the National Academy of Sciences)

   We describe the confining instabilities of a proposed quantum spin liquid underlying the pseudogap metal state of the hole-doped cuprates. The spin liquid can be described by a SU(2) gauge theory ofN_f= 2 massless Dirac fermions carrying fundamental gauge charges—this is the low-energy theory of a mean-field state of fermionic spinons moving on the square lattice withπ-flux per plaquette in the ℤ₂center of SU(2). This theory has an emergent SO(5)_fglobal symmetry and is presumed to confine at low energies to the Néel state. At nonzero doping (or smaller Hubbard repulsionUat half-filling), we argue that confinement occurs via the Higgs condensation of bosonic chargons carrying fundamental SU(2) gauge charges also moving inπℤ₂-flux. At half-filling, the low-energy theory of the Higgs sector hasN_b= 2 relativistic bosons with a possible emergent SO(5)_bglobal symmetry describing rotations between ad-wave superconductor, period-2 charge stripes, and the time-reversal breaking “d-density wave” state. We propose a conformal SU(2) gauge theory withN_f= 2 fundamental fermions,N_b= 2 fundamental bosons, and a SO(5)_f×SO(5)_bglobal symmetry, which describes a deconfined quantum critical point between a confining state which breaks SO(5)_fand a confining state which breaks SO(5)_b. The pattern of symmetry breaking within both SO(5)s is determined by terms likely irrelevant at the critical point, which can be chosen to obtain a transition between Néel order andd-wave superconductivity. A similar theory applies at nonzero doping and largeU, with longer-range couplings of the chargons leading to charge order with longer periods.

    

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2. Quantum Melting of Spin-1 Dimer Solid Induced by Inter-chain Couplings

   Xu, Yi ; Fu, Tianfu ; Hasik, Juraj ; Nevidomskyy, Andriy H. ( September 2022 , arXivorg)

   Dimerized valence bond solids appear naturally in spin-1/2 systems on bipartite lattices, with the geometric frustrations playing a key role both in their stability and the eventual `melting' due to quantum fluctuations. Here, we ask the question of the stability of such dimerized solids in spin-1 systems, taking the anisotropic square lattice with bilinear and biquadratic spin-spin interactions as a paradigmatic model. The lattice can be viewed as a set of coupled spin-1 chains, which in the limit of vanishing inter-chain coupling are known to possess a stable dimer phase. We study this model using the density matrix renormalization group (DMRG) and infinite projected entangled-pair states (iPEPS) techniques, supplemented by the analytical mean-field and linear flavor wave theory calculations. While the latter predicts the dimer phase to remain stable up to a reasonably large interchain-to-intrachain coupling ratio r≲0.6, the DMRG and iPEPS find that the dimer solid melts for much weaker interchain coupling not exceeding r≲0.15. We find the transition into a magnetically ordered state to be first order, manifested by a hysteresis and order parameter jump, precluding the deconfined quantum critical scenario. The apparent lack of stability of dimerized phases in 2D spin-1 systems is indicative of strong quantum fluctuations that melt the dimer solid. 

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3. Anderson–Kitaev spin liquid

   https://doi.org/10.1038/s41535-020-00285-3  

   Yamada, Masahiko G. ( November 2020 , npj Quantum Materials)

   The bond-disordered Kitaev model attracts much attention due to the experimental relevance inα-RuCl₃andA₃LiIr₂O₆(A= H, D, Ag, etc.). Applying a magnetic field to break the time-reversal symmetry leads to a strong modulation in mass terms for Dirac cones. Because of the smallness of the flux gap of the Kitaev model, a small bond disorder can have large influence on itinerant Majorana fermions. The quantization of the thermal Hall conductivityκ^xy/Tdisappears by a quantum Hall transition induced by a small disorder, andκ^xy/Tshows a rapid crossover into a state with a negligible Hall current. We call this immobile liquid state Anderson–Kitaev spin liquid (AKSL). Especially, the critical disorder strengthδJ_c1~ 0.05 in the unit of the Kitaev interaction would have many implications for the stability of Kitaev spin liquids.

    

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4. Valence transition model of the pseudogap, charge order, and superconductivity in electron-doped and hole-doped copper oxides

   https://doi.org/DOI: 10.1103/PhysRevB.98.205153  

   Mazumdar, S. ( October 2018 , Physical review. B, Condensed matter)

   We present a valence transition model for electron- and hole-doped cuprates, within which there occurs a discrete jump in ionicity Cu2+ -> Cu1+ in both families upon doping, at or near optimal doping in the conventionally prepared electron-doped compounds and at the pseudogap phase transition in the hole-doped materials. In thin films of the T' compounds, the valence transition has occurred already in the undoped state. The phenomenology of the valence transition is closely related to that of the neutral-to-ionic transition in mixed-stack organic charge-transfer solids. Doped cuprates have negative charge-transfer gaps, just as rare-earth nickelates and BaBiO3. The unusually high ionization energy of the closed shell Cu1+ ion, taken together with the dopingdriven reduction in three-dimensional Madelung energy and gain in two-dimensional delocalization energy in the negative charge transfer gap state drives the transition in the cuprates. The combined effects of strong correlations and small d-p electron hoppings ensure that the systems behave as effective 1/2-filled Cu band with the closed shell electronically inactive O2- ions in the undoped state, and as correlated two-dimensional geometrically frustrated 1/4-filled oxygen hole band, now with electronically inactive closed-shell Cu1+ ions, in the doped state. The model thus gives microscopic justification for the two-fluid models suggested by many authors. The theory gives the simplest yet most comprehensive understanding of experiments in the normal states. The robust commensurate antiferromagnetism in the conventional T' crystals, the strong role of oxygen deficiency in driving superconductivity and charge carrier sign corresponding to holes at optimal doping are all manifestations of the same quantum state. In the hole-doped pseudogapped state, there occurs a biaxial commensurate period 4 charge density wave state consisting of O1- -Cu l(1+)-O1- spin singlets that coexists with broken rotational C-4 symmetry due to intraunit cell oxygen inequivalence. Finite domains of this broken symmetry state will exhibit twodimensional chirality and the polar Kerr effect. Superconductivity within the model results from a destabilization of the 1/4-filled band paired Wigner crystal [Phys. Rev. B 93, 165110 (2016) and ihid. 93, 205111 (2016)]. We posit that a similar valence transition, Ir4+ -> Ir3+, occurs upon electron doping Sr2IrO4. We make testable experimental predictions in cuprates including superoxygenated La2CuO4+delta and iridates. Finally, as indirect evidence for the valence bond theory of superconductivity proposed here, we note that there exist an unusually large number of unconventional superconductors that exhibit superconductivity proximate to exotic charge ordered states, whose band fillings are universally 1/4 or 3/4, exactly where the paired Wigner crystal is most stable. 

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5. Gapped magnetic ground state in quantum spin liquid candidate κ-(BEDT-TTF) 2 Cu 2 (CN) 3

   https://doi.org/10.1126/science.abc6363  

   Miksch, Björn ; Pustogow, Andrej ; Rahim, Mojtaba Javaheri ; Bardin, Andrey A. ; Kanoda, Kazushi ; Schlueter, John A. ; Hübner, Ralph ; Scheffler, Marc ; Dressel, Martin ( April 2021 , Science)

   Geometrical frustration, quantum entanglement, and disorder may prevent long-range ordering of localized spins with strong exchange interactions, resulting in an exotic state of matter. κ-(BEDT-TTF)₂Cu₂(CN)₃is considered the prime candidate for this elusive quantum spin liquid state, but its ground-state properties remain puzzling. We present a multifrequency electron spin resonance (ESR) study down to millikelvin temperatures, revealing a rapid drop of the spin susceptibility at 6 kelvin. This opening of a spin gap, accompanied by structural modifications, is consistent with the formation of a valence bond solid ground state. We identify an impurity contribution to the ESR response that becomes dominant when the intrinsic spins form singlets. Probing the electrons directly manifests the pivotal role of defects for the low-energy properties of quantum spin systems without magnetic order.

    

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