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Title: Bound-Ion Pair X-Type Ligation of Cadmium and Zinc Dithiocarbamates on Cadmium Selenide Quantum Belts
Wurtzite CdSe quantum belts with L-type n-octylamine, L-type ammonia, or Z-type Cd(oleate)2 ligands are exchanged for several metal-dithiocarbamate ligands [M(S2CNR1R2)2]: Cd(S2CNPhMe)2, Cd(S2CNEt2)2, Zn(S2CNPhMe)2, and Zn(S2CNEt2)2. Successful ligand exchange with all M(S2CNR1R2)2 compounds occurs from {CdSe[Cd(oleate)2]0.19} quantum belts (QBs), which induce similar spectral shifts in the absorption spectra of the ligand-exchanged QBs. Spectroscopic data, experimentally determined lattice strains, and ligand exchanges with [Na][Et2NCS2] and [NH4][MePhNCS2] establish that the [M(S2CNR1R2)2] ligands bind as bound-ion-paired X-type ligands with (S2CNR1R2)− groups ligated directly to the QB surfaces and [M(S2CNR1R2)]+ groups serving as the charge-balancing ion-paired countercations. The X-type dithiocarbamate ligands do not impart any special electronic effects to the CdSe QBs.  more » « less
Award ID(s):
1905751
NSF-PAR ID:
10484210
Author(s) / Creator(s):
; ; ;
Publisher / Repository:
American Chemical Society
Date Published:
Journal Name:
Inorganic Chemistry
Volume:
61
Issue:
15
ISSN:
0020-1669
Page Range / eLocation ID:
5861 to 5868
Subject(s) / Keyword(s):
Aromatic compounds,Cadmium selenide, Ligand exchange, Ligands, Ligation
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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