Abstract We report the first direct detection of molecular hydrogen associated with the Galactic nuclear wind. The Far-Ultraviolet Spectroscopic Explorer spectrum of LS 4825, a B1 Ib–II star at l , b = 1.67°,−6.63° lying d = 9.9 − 0.8 + 1.4 kpc from the Sun, ∼1 kpc below the Galactic plane near the Galactic center, shows two high-velocity H 2 components at v LSR = −79 and −108 km s −1 . In contrast, the FUSE spectrum of the nearby (∼0.6° away) foreground star HD 167402 at d = 4.9 − 0.7 + 0.8 kpc reveals no H 2 absorption at these velocities. Over 60 lines of H 2 from rotational levels J = 0 to 5 are identified in the high-velocity clouds. For the v LSR = −79 km s −1 cloud we measure total log N (H 2 ) ≥ 16.75 cm −2 , molecular fraction f H 2 ≥ 0.8%, and T 01 ≥ 97 and T 25 ≤ 439 K for the ground- and excited-state rotational excitation temperatures. At v LSR = −108 km s −1 , we measure log N (H 2 ) = 16.13 ± 0.10 cm −2 , f H 2 ≥ 0.5%, and T 01 = 77 − 18 + 34 and T 25 = 1092 − 117 + 149 K, for which the excited-state ortho- to para-H 2 is 1.0 − 0.1 + 0.3 , much less than the equilibrium value of 3 expected for gas at this temperature. This nonequilibrium ratio suggests that the −108 km s −1 cloud has been recently excited and has not yet had time to equilibrate. As the LS 4825 sight line passes close by a tilted section of the Galactic disk, we propose that we are probing a boundary region where the nuclear wind is removing gas from the disk.
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This content will become publicly available on January 3, 2025
Temperature lowering of liquid nitrogen via injection of helium gas bubbles improves the generation of parahydrogen‐enriched gas
The para spin isomer of hydrogen gas possesses high nuclear spin order that can enhance the NMR signals of a variety of molecular species. Hydrogen is routinely enriched in the para spin state by lowering the gas temperature while flowing through a catalyst. Although parahydrogen enrichments approaching 100% are achievable near the H2liquefaction temperature of 20 K, many experimentalists operate at liquid nitrogen temperatures (77 K) due to the lower associated costs and overall simplicity of the parahydrogen generator. Parahydrogen that is generated at 77 K provides an enrichment value of ~51% of the para spin isomer; while useful, there are many applications that can benefit from low‐cost access to higher parahydrogen enrichments. Here, we introduce a method of improving parahydrogen enrichment values using a liquid nitrogen‐cooled generator that operates at temperatures less than 77 K. The boiling temperature of liquid nitrogen is lowered through internal evaporation into helium gas bubbles that are injected into the liquid. Changes to liquid nitrogen temperatures and parahydrogen enrichment values were monitored as a function of helium gas flow rate. The injected helium bubbles lowered the liquid nitrogen temperature to ~65.5 K, and parahydrogen enrichments of up to ~59% were achieved; this represents an ~16% improvement compared with the expected parahydrogen fraction at 77 K. This technique is simple to implement in standard liquid nitrogen‐cooled parahydrogen generators and may be of interest to a wide range of scientists that require a cost‐effective approach to improving parahydrogen enrichment values.
more » « less- Award ID(s):
- 2238852
- NSF-PAR ID:
- 10484305
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Magnetic Resonance in Chemistry
- Volume:
- 62
- Issue:
- 2
- ISSN:
- 0749-1581
- Format(s):
- Medium: X Size: p. 94-100
- Size(s):
- ["p. 94-100"]
- Sponsoring Org:
- National Science Foundation
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