Abstract The millimeter-wave spectrum of the SiP radical (X2Πi) has been measured in the laboratory for the first time using direct-absorption methods. SiP was created by the reaction of phosphorus vapor and SiH4in argon in an AC discharge. Fifteen rotational transitions (J+ 1 ←J) were measured for SiP in the Ω = 3/2 ladder in the frequency range 151–533 GHz, and rotational, lambda doubling, and phosphorus hyperfine constants determined. Based on the laboratory measurements, SiP was detected in the circumstellar shell of IRC+10216, using the Submillimeter Telescope and the 12 m antenna of the Arizona Radio Observatory at 1 mm and 2 mm, respectively. Eight transitions of SiP were searched: four were completely obscured by stronger features, two were uncontaminated (J= 13.5 → 12.5 and 16.5 → 15.5), and two were partially blended with other lines (J= 8.5 → 7.5 and 17.5 → 16.5). The SiP line profiles were broader than expected for IRC+10216, consistent with the hyperfine splitting. From non-LTE radiative transfer modeling, SiP was found to have a shell distribution with a radius ∼300R*, and an abundance, relative to H2, off∼ 2 × 10−9. From additional modeling, abundances of 7 × 10−9and 9 × 10−10were determined for CP and PN, respectively, both located in shells at 550–650R*. SiP may be formed from grain destruction, which liberates both phosphorus and silicon into the gas phase, and then is channeled into other P-bearing molecules such as PN and CP.
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Elusive Iron: Detection of the FeC Radical (X 3 Δ i) in the Envelope of IRC+10216
Abstract A new interstellar molecule, FeC (X3Δi), has been identified in the circumstellar envelope of the carbon-rich asymptotic giant branch star IRC+10216. FeC is the second iron-bearing species conclusively observed in the interstellar medium, in addition to FeCN, also found in IRC+10216. TheJ= 4 → 3, 5 → 4, and 6 → 5 rotational transitions of this free radical near 160, 201, and 241 GHz, respectively, were detected in the lowest spin–orbit ladder, Ω = 3, using the Submillimeter Telescope of the Arizona Radio Observatory (ARO) for the 1 mm lines and the ARO 12 m at 2 mm. Because the ground state of FeC is inverted, these transitions are the lowest energy lines. The detected features exhibit slight U shapes with LSR velocities nearVLSR≈ −26 km s−1and linewidths of ΔV1/2≈ 30 km s−1, line parameters characteristic of IRC+10216. Radiative transfer modeling of FeC suggests that the molecule has a shell distribution with peak radius near 300R*(∼6″) extending out to ∼500R*(∼10″) and a fractional abundance, relative to H2, off∼ 6 × 10−11. The previous FeCN spectra were also modeled, yielding an abundance off∼ 8 × 10−11in a larger shell situated near 800R*. These distributions suggest that FeC may be the precursor species for FeCN. Unlike cyanides and carbon-chain molecules, diatomic carbides with a metallic element are rare in IRC+10216, with FeC being the first such detection.
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- PAR ID:
- 10484828
- Publisher / Repository:
- IOP
- Date Published:
- Journal Name:
- The Astrophysical Journal Letters
- Volume:
- 958
- Issue:
- 1
- ISSN:
- 2041-8205
- Page Range / eLocation ID:
- L6
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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