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Title: Stepwise deprotonation of truxene: structures, metal complexation, and charge-dependent optical properties

Stepwise deprotonation of truxene with alkali metals affords truxenyl anions with different charges, exhibiting core curvature dependence on charge and metal binding. UV-vis and PL studies reveal charge-dependent optical properties, which is further supported by DFT calculations.

 
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Award ID(s):
1834750 2003411
NSF-PAR ID:
10491518
Author(s) / Creator(s):
; ; ; ; ; ; ;
Publisher / Repository:
The Royal Society of Chemistry
Date Published:
Journal Name:
Chemical Science
Volume:
14
Issue:
45
ISSN:
2041-6520
Page Range / eLocation ID:
13219 to 13227
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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