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1. Using induced charge detection to quantify the net charge of microdroplets within a quadrupole electrodynamic trap

   https://doi.org/10.1063/5.0294542  

   Ahmed, Firoz; Jacobs, Michael I (December 2025, Review of Scientific Instruments)

   Precise and accurate charge measurements on microdroplets are essential for understanding the role of charge in modulating microdroplet chemistry, including reaction kinetics, ion distribution, and interfacial dynamics. Despite the availability of various charge measurement techniques, existing contactless techniques either lack the sensitivity to accurately detect charges with ∼1 fC precision or lack the ability to measure charge on micron-sized particles, leaving a significant gap in the field. Here, a new technique is presented to directly measure the net charge of microdroplets exiting a quadrupole electrodynamic trap (QET) using induced charge detection. With this method, the charge droplets induce on a cylindrical electrode (Qinduced) is detected using a homebuilt charge sensitive pre-amplifier (CSP). The long time constant of the CSP (1.02 ± 0.01 s−1) facilitates accurate measurement of Qinduced on slow-moving microdroplets that interact with the detection electrode for up to 100s of ms. The new charge detection method is validated by comparing Qinduced with the charge of droplets measured using a Faraday cup (QFaraday cup) for roughly 2900 droplets with different net charges, sizes, and velocities. Regardless of droplet properties, Qinduced closely correlates with QFaraday cup with absolute differences averaging <5 fC (i.e., 1% accuracy). While the charge detection system is coupled to a QET, it could easily be adapted for other droplet-based measurements (e.g., droplet train experiments). Ultimately, the induced charge detection system presented here will support future studies exploring how charge influences the physical and chemical processing of microdroplets, such as understanding how charge can drive accelerated chemistry in microdroplets. 

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2. Evidence of cluster dipole states in germanium detectors operating at temperatures below 10 K

   https://doi.org/10.1063/5.0094194  

   Mei, D-M; Panth, R.; Kooi, K.; Mei, H.; Bhattarai, S.; Raut, M.; Acharya, P.; Wang, G-J (June 2022, AIP Advances)

   By studying charge trapping in germanium detectors operating at temperatures below 10 K, we demonstrate for the first time that the formation of cluster dipole states from residual impurities is responsible for charge trapping. Two planar detectors with different impurity levels and types are used in this study. When drifting the localized charge carriers created by α particles from the top surface across a detector at a lower bias voltage, significant charge trapping is observed when compared to operating at a higher bias voltage. The amount of charge trapping shows a strong dependence on the type of charge carriers. Electrons are trapped more than holes in a p-type detector, while holes are trapped more than electrons in an n-type detector. When both electrons and holes are drifted simultaneously using the widespread charge carriers created by γ rays inside the detector, the amount of charge trapping shows no dependence on the polarity of bias voltage. 

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3. Charge distribution guided by grain crystallographic orientations in polycrystalline battery materials

   https://doi.org/10.1038/s41467-019-13884-x  

   Xu, Zhengrui; Jiang, Zhisen; Kuai, Chunguang; Xu, Rong; Qin, Changdong; Zhang, Yan; Rahman, Muhammad Mominur; Wei, Chenxi; Nordlund, Dennis; Sun, Cheng-Jun; et al (January 2020, Nature Communications)

   Abstract Architecting grain crystallographic orientation can modulate charge distribution and chemomechanical properties for enhancing the performance of polycrystalline battery materials. However, probing the interplay between charge distribution, grain crystallographic orientation, and performance remains a daunting challenge. Herein, we elucidate the spatially resolved charge distribution in lithium layered oxides with different grain crystallographic arrangements and establish a model to quantify their charge distributions. While the holistic “surface-to-bulk” charge distribution prevails in polycrystalline particles, the crystallographic orientation-guided redox reaction governs the charge distribution in the local charged nanodomains. Compared to the randomly oriented grains, the radially aligned grains exhibit a lower cell polarization and higher capacity retention upon battery cycling. The radially aligned grains create less tortuous lithium ion pathways, thus improving the charge homogeneity as statistically quantified from over 20 million nanodomains in polycrystalline particles. This study provides an improved understanding of the charge distribution and chemomechanical properties of polycrystalline battery materials. 

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4. Investigating charge transport in a p -Si/ n -poly(benzimidazobenzophenanthroline)-BBL thin film heterojunction diode

   https://doi.org/10.1088/1361-648X/adcdb0  

   Cruz-Arzon, Alejandro J; Pinto, Nicholas J (April 2025, Journal of Physics: Condensed Matter)

   Abstract The physics of charge transport across the interface in an inorganic Si/organic conducting polymer junction diode has received little attention compared to the inorganicp–nsilicon diode. One reason is the amorphous nature of the organic polymer and the polymer chain orientation which introduces disorder and barriers to charge flow. Herein we first present an easy technique to fabricate an inorganic/organic,p-Si/n-poly(benzimidazobenzophenanthroline-BBL) junction diode. The physics of charge transport across the heterojunction, and in the BBL film is then analyzed from the device current-voltage characteristics as a function of temperature in the range 150 K <T< 370 K. The temperature dependence of the diode ideality parameter and of the saturation current density demonstrate that tunneling enhanced charge recombination via exponential trap distributions in the depletion region was responsible for charge transport across the junction. Furthermore, the temperature dependence of the diode conductance revealed that thermal activation and hopping both contributed to charge transport in the BBL film away from the junction. BBL is a ladder polymer with a discrete layered crystal structure that is oriented perpendicular to the substrate. Such polymer chain orientation, combined with a distribution of bond lengths and numerous conjugation paths available for charge delocalization result in the multiple charge transport mechanisms as observed in the diode. 

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5. Incommensurate charge-stripe correlations in the kagome superconductor CsV3Sb5−xSnx

   https://doi.org/10.1038/s41535-023-00570-x  

   Kautzsch, Linus; Oey, Yuzki M.; Li, Hong; Ren, Zheng; Ortiz, Brenden R.; Pokharel, Ganesh; Seshadri, Ram; Ruff, Jacob; Kongruengkit, Terawit; Harter, John W.; et al (July 2023, npj Quantum Materials)

   Abstract The class ofAV₃Sb₅(A=K, Rb, Cs) kagome metals hosts unconventional charge density wave states seemingly intertwined with their low temperature superconducting phases. The nature of the coupling between these two states and the potential presence of nearby, competing charge instabilities however remain open questions. This phenomenology is strikingly highlighted by the formation of two ‘domes’ in the superconducting transition temperature upon hole-doping CsV₃Sb₅. Here we track the evolution of charge correlations upon the suppression of long-range charge density wave order in the first dome and into the second of the hole-doped kagome superconductor CsV₃Sb_5−xSn_x. Initially, hole-doping drives interlayer charge correlations to become short-ranged with their periodicity diminished along the interlayer direction. Beyond the peak of the first superconducting dome, the parent charge density wave state vanishes and incommensurate, quasi-1D charge correlations are stabilized in its place. These competing, unidirectional charge correlations demonstrate an inherent electronic rotational symmetry breaking in CsV₃Sb₅, and reveal a complex landscape of charge correlations within its electronic phase diagram. Our data suggest an inherent 2k_fcharge instability and competing charge orders in theAV₃Sb₅class of kagome superconductors. 

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