Electrophoresis is the motion of a charged colloidal particle in an electrolyte under an applied electric field. The electrophoretic velocity of a spherical particle depends on the dimensionless electric field strength$$\beta =a^*e^*E_\infty ^*/k_B^*T^*$$, defined as the ratio of the product of the applied electric field magnitude$$E_\infty ^*$$and particle radius$$a^*$$, to the thermal voltage$$k_B^*T^*/e^*$$, where$$k_B^*$$is Boltzmann's constant,$$T^*$$is the absolute temperature, and$$e^*$$is the charge on a proton. In this paper, we develop a spectral element algorithm to compute the electrophoretic velocity of a spherical, rigid, dielectric particle, of fixed dimensionless surface charge density$$\sigma$$over a wide range of$$\beta$$. Here,$$\sigma =(e^*a^*/\epsilon ^*k_B^*T^*)\sigma ^*$$, where$$\sigma ^*$$is the dimensional surface charge density, and$$\epsilon ^*$$is the permittivity of the electrolyte. For moderately charged particles ($$\sigma ={O}(1)$$), the electrophoretic velocity is linear in$$\beta$$when$$\beta \ll 1$$, and its dependence on the ratio of the Debye length ($$1/\kappa ^*$$) to particle radius (denoted by$$\delta =1/(\kappa ^*a^*)$$) agrees with Henry's formula. As$$\beta$$increases, the nonlinear contribution to the electrophoretic velocity becomes prominent, and the onset of this behaviour is$$\delta$$-dependent. For$$\beta \gg 1$$, the electrophoretic velocity again becomes linear in field strength, approaching the Hückel limit of electrophoresis in a dielectric medium, for all$$\delta$$. For highly charged particles ($$\sigma \gg 1$$) in the thin-Debye-layer limit ($$\delta \ll 1$$), our computations are in good agreement with recent experimental and asymptotic results.
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Characteristic scales during the onset of radiatively driven convection: linear analysis and simulations
This paper considers the initial stage of radiatively driven convection, when the perturbations from a quiescent but time-dependent background state are small. Radiation intensity is assumed to decay exponentially away from the surface, and we consider parameter regimes in which the depth of the water is greater than the decay scale of$$e$$of the radiation intensity. Both time-independent and time-periodic radiation are considered. In both cases, the background temperature profile of the water column is time-dependent. A linear analysis of the system is performed based on these time-dependent profiles. We find that the perturbations grow in time according to$$\exp [(\sigma (t) t)]$$, where$$\sigma (t)$$is a time-dependent growth rate. An appropriately defined Reynolds number is the primary dimensionless number characterising the system, determining the wavelength, vertical structure and growth rate of the perturbations. Simulations using a Boussinesq model (the Stratified Ocean Model with Adaptive Refinement) confirm the linear analysis.
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- Award ID(s):
- 1829924
- PAR ID:
- 10497613
- Publisher / Repository:
- Camnbridge University Press
- Date Published:
- Journal Name:
- Journal of Fluid Mechanics
- Volume:
- 973
- ISSN:
- 0022-1120
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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