skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Comparing lithologies and geochemical signals of the Middle Devonian Thunder Bay Formation (Michigan Basin) in core and at the type section
Lithologic correlation of the Middle Devonian Traverse Group in the Michigan Basin is challenging due to a paucity of outcrops and the difficulty in correlating shallow water marine facies across the basin.This study correlates strata in the State Chester Welch #18 core (SCW-18) to outcrop exposures at the type sections of the Thunder Bay Formation and neighboring units using litho- and chemostratigraphy. Lithologically, the texture, grain sizes, and fossil assemblages found in the SCW-18 core match the outcrop samples and type section description of the Thunder Bay Formation. Both successions are gray calcareous shale and limestone with abundant fossils and stylolites. δ13C isotopes reveal a shift to more negative isotopic values through time for both bulk-rock and drilled micrite powders from the SCW-18 core, but a trend toward more positive values with relative stratigraphic position for the outcrop sample. This suggests that Thunder Bay strata in the core and outcrop are not chronostratigraphically equivalent even though they appear similar lithologically. The core data also revealed two groupings based on relationships between δ18O vs δ13C values that correspond to differences in lithology. The lower samples in the core that are situated in shaley limestone illustrate a linear trend than the upper portion which was more crystalline and isotopic values noisier. This variation might suggest differences in diagenetic processes affecting the subsurface Thunder Bay Formation as δ18O values in carbonates are often altered to some extent. This study improves our lithologic and isotope geochemistry understanding of the Thunder Bay Formation in the subsurface. Future work will incorporate elemental data from the core and outcrop to better understand diagenetic processes.  more » « less
Award ID(s):
2050697
PAR ID:
10508884
Author(s) / Creator(s):
; ; ; ;
Publisher / Repository:
Geological Society of America Abstracts with Programs
Date Published:
Volume:
56
Issue:
3
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. The “Squaw Bay Formation,” a middle Devonian mixed carbonate-clastic unit located in the Michigan basin, was named almost 100 years ago by Warthin and Cooper (1935) for a single, poorly exposed outcropping of condensed strata. Since then the stratigraphic term has been used inconsistently in the subsurface where the unit is stratigraphically expanded, but should also be revised because it is a derogatory term for Native American Women. The goal of this study is to aid in the renaming process for this formation by determining its variability and defining boundaries. To accomplish this, the current research combines lithostratigraphy, paleoecology, and geochemical analyses of the Krocker 1-17, State Chester Welch 18, and Paxton Quarry cores to provide the background information needed to revise the formation. The “Squaw Bay Formation” in core is composed of predominantly argillaceous limestone and calcareous shale and is characterized by a crinoid and brachiopod fauna. Further lithologic analysis found that there are three main facies common in the studied cores; black shale with frequent pyrite nodules and silt laminae, calcareous fossiliferous shale, and a highly bioturbated calcareous shale with few fossils and pyrite nodules. The lower “Squaw Bay Formation” also contains zones of concentrated fossil debris, especially near the contact with the Traverse Limestone which is primarily a pyritized hardground. The studied formation also has an increasing black shale content up-section and a transitional contact with the overlying Antrim Shale. Future analysis of magnetic susceptibility, pXRF, and total organic carbon data will further illuminate the variability within the formation and characteristics of its boundaries with other stratigraphic units. Ultimately, the combination of lithostratigraphic, paleoecologic, and geochemical analysis of the Krocker 1-17, State Chester Welch 18, and Paxton Quarry cores will not only facilitate a better understanding of the “Squaw Bay Formation,” but also contribute to the process of revising and renaming the unit. 
    more » « less
  2. Petrographic analysis can reveal information about original depositional environments and subsequent diagenetic conditions. Here we examine a well-developed pyritized interval at the contact between the Traverse Limestone (a fossiliferous dolomitic packstone) and the “Squaw Bay Formation” in the Michigan Basin. Overlying the pyritized discontinuity, the “Squaw Bay Formation” is a calcareous, highly bioturbated shale, indicating Devonian sea level rise and/or basin subsidence. Little prior petrographic analysis has been done on these formations, and, given the stratigraphic consistency of the pyritized interval across geographically diverse cores, detailed petrographic study will elucidate the diagenetic history of each formation and the contact itself. Ten thin sections were cut from three cores with samples taken at the contact and in both the underlying Traverse Limestone and overlying “Squaw Bay Formation”. Thin section petrography, SEM, and µXRF technologies are used to delineate diagenetic overprints and stratigraphic relationships. Analysis revealed extensive dolomitization of the Traverse Limestone and a variable history of fossil recrystallization in the “Squaw Bay Formation”. The presence of chalcedony, glauconite, various forms of calcite, and several crystal morphologies of pyrite at and near the contact imply a complicated diagenetic history. The nature of the calcite and pyrite generations in these samples contextualize the diagenetic history of each formation and of the contact. Calcite crystals, overgrowths, and deformations distinguish the Traverse from the “Squaw Bay,” and suggest multiple and distinct generation events. The pyrite at the contact exhibits both cubic and needle-like forms. Future SEM analyses may reveal whether the needle-like form is a result of a second generation of sulfide mineralization or diagenetic alteration of the original pyrite. Continued research will result in the development of a paragenetic sequence for this mineralized stratigraphic contact. 
    more » « less
  3. Assessing potential for diagenetic overprinting of climatic signals in benthic foraminifera: Preliminary results. Robert K. Poirier, Reinhard Kozdon, Maureen Raymo, Morgan Schaller Benthic foraminiferal stable isotope records (δ18O, δ13C) are the most common paleoclimate records produced to date, which capture changes in temperature, ice volume, and the global carbon system on orbital to sub-millennial timescales. General relationships between deep sea δ18O and sea level have long been established, and more recent paired δ18O and Mg/Ca records seek to disentangle the temperature and ice volume components of corresponding sea level records. However, the extent to which diagenesis may potentially alter the original isotopic signature recorded in tests of benthic foraminifera remains relatively undefined. We present preliminary results of a project focused on constraining the extent to which such diagenetic overprinting might alter sea level estimates based on records produced from modern to mid-Pliocene Cibicidoides and Uvigerina specimens. These include advanced imaging techniques (SEM, CL-spectroscopy), single shell stable isotope analyses (δ18O, δ13C), and chamber wall trace metal profiles (LA-ICPMS) paired with in situ δ18O analyses (SIMS). In addition, we present strict specimen screening criteria developed based on a new quantitative assessment of visual preservation in both individual foraminiferal tests and whole assemblages. http://forams2018.wp.st-andrews.ac.uk Session II: Advances in Foraminiferal Geochemistry Conveners: Jelle Bijma, Howard Spero Session Overview: http://forams2018.wp.st-andrews.ac.uk/program/ 
    more » « less
  4. null (Ed.)
    The Plio-Pleistocene El Laco iron oxide-apatite (IOA) orebodies in northern Chile are some of the most enigmatic mineral deposits on Earth, interpreted to have formed as lava flows or by hydrothermal replacement, two radically different processes. Field observations provide some support for both processes, but ultimately fail to explain all observations. Previously proposed genetic models based on observations and study of outcrop samples include (1) magnetite crystallization from an erupting immiscible Fe- and P-rich (Si-poor) melt and (2) metasomatic replacement of andesitic lava flows by a hypogene hydrothermal fluid. A more recent investigation of outcrop and drill core samples at El Laco generated data that were used to develop a new genetic model that invokes shallow emplacement and surface venting of a magnetite-bearing magmatic-hydrothermal fluid suspension. This fluid, with rheological properties similar to basaltic lava, would have been mobilized by decompression- induced collapse of the volcanic edifice. In this study, we report oxygen, including 17O, hydrogen, and iron stable isotope ratios in magnetite and bulk iron oxide (magnetite with minor secondary hematite and minor goethite) from five of seven orebodies around the El Laco volcano, excluding San Vicente Bajo and the minor Laquito deposits. Calculated values of δ18O, Δ17O, δD, and δ56Fe fingerprint the source of the ore-forming fluid(s): Δ17Osample = δ17Osample – δ18Osample * 0.5305. Magnetite and bulk iron oxide (magnetite variably altered to goethite and hematite) from Laco Sur, Cristales Grandes, and San Vicente Alto yield δ18O values that range from 4.3 to 4.5‰ (n = 5), 3.0 to 3.9‰ (n = 5), and –8.5 to –0.5‰ (n = 5), respectively. Magnetite samples from Rodados Negros are the least altered samples and were also analyzed for 17O as well as conventional 16O and 18O, yielding calculated δ18O values that range from 2.6 to 3.8‰ (n = 9) and Δ17O values that range from –0.13 to –0.07‰ (n = 5). Bulk iron oxide from Laco Norte yielded δ18O values that range from –10.2 to +4.5‰ (avg = 0.8‰, n = 18). The δ2H values of magnetite and bulk iron oxide from all five orebodies range from –192.8 to –79.9‰ (n = 28); hydrogen is present in fluid inclusions in magnetite and iron oxide, and in minor goethite. Values of δ56Fe for magnetite and bulk iron oxide from all five orebodies range from 0.04 to 0.70‰ (avg = 0.29‰, σ = 0.15‰, n = 26). The iron and oxygen isotope data are consistent with a silicate magma source for iron and oxygen in magnetite from all sampled El Laco orebodies. Oxygen (δ18O Δ +4.4 to –10.2‰) and hydrogen (δ 2H ≃ –79.9 to –192.8‰) stable isotope data for bulk iron oxide samples that contain minor goethite from Laco Norte and San Vicente Alto reveal that magnetite has been variably altered to meteoric values, consistent with goethite in equilibrium with local δ18O and δ2H meteoric values of ≃ –15.4 and –211‰, respectively. The H2O contents of iron oxide samples from Laco Norte and San Vicente Alto systematically increase with increasing abundance of goethite and decreasing values of δ18O and δ2H. The values of δ2H (≃ –88 to –140‰) and δ18O (3.0–4.5‰) for magnetite samples from Cristales Grandes, Laco Sur, and Rodados Negros are consistent with growth of magnetite from a degassing silicate melt and/or a boiling magmatic-hydrothermal fluid; the latter is also consistent with δ18O values for quartz, and salinities and homogenization temperatures for fluid inclusions trapped in apatite and clinopyroxene coeval with magnetite. The sum of the data unequivocally fingerprint a silicate magma as the source of the ore fluids responsible for mineralization at El Laco and are consistent with a model that explains mineralization as the synergistic result of common magmatic and magmatic-hydrothermal processes during the evolution of a caldera-related explosive volcanic system. 
    more » « less
  5. Fossiliferous carbonate concretions are commonly found in sediments deposited in the Late Cretaceous Western Interior Seaway. Although concretions are diagenetic features, well-preserved fossils from within them have been instrumental in reconstructing the temperature and δ18O value of Western Interior Seaway seawater, which is essential for accurate reconstruction of Late Cretaceous climate. Here, we constrain formation conditions of Late Campanian and early Maastrichtian carbonate concretions by combining triple oxygen isotope measurements with carbonate clumped isotope paleothermometry on different carbonate phases within the concretions. We measured both fossil skeletal aragonite and sparry calcite infill from cracks and within macrofossil voids to evaluate differences between “primary” and “altered” geochemical signals. Based on the two temperature-sensitive isotope systems of the primary fossil shell aragonite, the temperature of the Western Interior Seaway was between 20 °C and 40 °C and was likely thermally stratified during the Campanian. The reconstructed δ18Oseawater values of ∼−1‰ for Campanian Western Interior Seaway waters are similar to those expected for the open ocean during greenhouse climates, while the Maastrichtian Western Interior Seaway may have been more restricted, with a δ18Oseawater value of ∼2‰, which reflects more evaporative conditions. We reconstructed the diagenetic history of the sparry infill and altered fossils using a fluid-rock mixing model. Alteration temperature, alteration fluid δ18O value, and the initial formation temperature were calculated by applying the fluid-rock mixing model to a particle swarm optimization algorithm. We found a different range of initial formation temperatures between the Campanian (25−38 °C) and Maastrichtian (9−28 °C). We also found that alteration in the presence of light meteoric fluids (δ18O ≈ −10‰) is required to explain both the sparry infill and the altered fossil isotopic values. Based on our results, both lithification and alteration of the carbonates occurred soon after burial, and light meteoric fluids support prior findings that high-topographic relief existed on the western margin of the Western Interior Seaway during the Late Cretaceous. As one of the first studies to apply these techniques in concert and across multiple mineralogical phases within samples, our results provide important constraints on paleoenvironmental conditions in an enigmatic ocean system and will improve interpretations of the overall health of ecosystems leading into the end-Cretaceous mass extinction. 
    more » « less