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  • Ultrafast dense DNA functionalization of quantum dots and rods for scalable 2D array fabrication with nanoscale precision
Title: Ultrafast dense DNA functionalization of quantum dots and rods for scalable 2D array fabrication with nanoscale precision
Scalable fabrication of two-dimensional (2D) arrays of quantum dots (QDs) and quantum rods (QRs) with nanoscale precision is required for numerous device applications. However, self-assembly–based fabrication of such arrays using DNA origami typically suffers from low yield due to inefficient QD and QR DNA functionalization. In addition, it is challenging to organize solution-assembled DNA origami arrays on 2D device substrates while maintaining their structural fidelity. Here, we reduced manufacturing time from a few days to a few minutes by preparing high-density DNA-conjugated QDs/QRs from organic solution using a dehydration and rehydration process. We used a surface-assisted large-scale assembly (SALSA) method to construct 2D origami lattices directly on solid substrates to template QD and QR 2D arrays with orientational control, with overall loading yields exceeding 90%. Our fabrication approach enables the scalable, high fidelity manufacturing of 2D addressable QDs and QRs with nanoscale orientational and spacing control for functional 2D photonic devices.  more » « less
Award ID(s):
1956054
PAR ID:
10508901
Author(s) / Creator(s):
; ; ; ; ;
Publisher / Repository:
Sciemces Advances
Date Published:
Journal Name:
Science Advances
Volume:
9
Issue:
32
ISSN:
2375-2548
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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