An official website of the United States government
Abstract Nano-second, capillary discharges (nCDs) are unique plasma sources in their ability to sustain high specific energy deposition ω dep approaching 10 eV/molecule in molecular gases. This high energy loading on short timescales produces both high plasma densities and high densities of molecular exited states. These high densities of electrons and excited states interact with each other during the early afterglow through electron collision quenching and associative ionization. In this paper we discuss results from a two-dimensional computational investigation of a nCD sustained in air at a pressure of 28.5 mbar and with a voltage amplitude 20 kV. Discharges were investigated for two circuit configurations—a floating low voltage electrode and with the low voltage electrode connected to ground through a ballast resistor. The first configuration produced a single ionization wave from the high to low voltage electrode. The second produced converging ionization waves beginning at both electrodes. With a decrease of the tube radius, the velocity of the ionization fronts decreased while the shape of the ionization wave changed from the electron density being distributed smoothly in the radial direction, to being hollow shaped where there is a higher electron density near the tube wall. For sufficiently small tubes, the near-wall maxima merge to have the higher density on the axis of the capillary tube. In the early afterglow, the temporal and radial behavior of the N 2 (C 3 Π u ) density is a sensitive function of ω dep due to electron collision quenching. These trends indicate that starting from ω dep ⩾ 0.3 eV/molecule, it is necessary to take into account interactions of electrons with electronically excited species during the discharge and early afterglow.
more »
« less
A novel state-resolved actinometry method to determine the nitrogen atom number density in the ground state and intra-shell excited states in low-pressure electron cyclotron resonance plasmas
Abstract The active-particle number density is a key parameter for plasma material processing, space propulsion, and plasma-assisted combustion. The traditional actinometry method focuses on measuring the density of the atoms in the ground state, but there is a lack of an effective optical emission spectroscopy method to measure intra-shell excited-state densities. The latter atoms have chemical selectivity and higher energy, and they can easily change the material morphology as well as the ionization and combustion paths. In this work, we present a novel state-resolved actinometry (SRA) method, supported by a krypton line-ratio method for the electron temperature and density, to measure the number densities of nitrogen atoms in the ground and intra-shell excited states. The SRA method is based on a collisional-radiative model, considering the kinetics of atomic nitrogen and krypton including their excited states. The densities measured by our method are compared with those obtained from a dissociative model in a miniature electron cyclotron resonance (ECR) plasma source. Furthermore, the saturation effect, in which the electron density remains constant due to the microwave propagation in an ECR plasma once the power reaches a certain value, is used to verify the electron density measured by the line-ratio method. An ionization balance model is also presented to examine the measured electron temperature. All the values obtained with the different methods are in good agreement with each other, and hence a set of verified rate coefficient data used in our method can be provided. A novel concept, the ‘excited-state system’, is presented to quickly build an optical diagnostic method based on the analysis of quantum number propensity and selection rules.
more »
« less
- Award ID(s):
- 2110023
- PAR ID:
- 10511446
- Publisher / Repository:
- Institute of Physics
- Date Published:
- Journal Name:
- Plasma Sources Science and Technology
- Volume:
- 33
- Issue:
- 5
- ISSN:
- 0963-0252
- Page Range / eLocation ID:
- 055006
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Context.Quasar outflows play a significant role in the active galactic nucleus (AGN) feedback, impacting the interstellar medium and potentially influencing galaxy evolution. Characterizing these outflows is essential for understanding AGN-driven processes. Aims.We aim to analyze the physical properties of the mini-broad absorption line outflow in quasar J1402+2330 using data from the Dark Energy Spectroscopic Instrument (DESI) survey. We seek to measure the outflow’s location, energetics, and potential impact on AGN feedback processes. Methods.In the spectrum of J1402+2330, we identify multiple ionic absorption lines, including ground and excited states. We measure the ionic column densities and then use photoionization models to determine the total hydrogen column density and ionization parameter of the outflow. We utilized the population ratio of the excited state to the ground state of N IIIand S IVto determine the electron number density. Results.The derived electron number density, combined with the ionization parameter, indicates an outflow distance of approximately 2.2 kpc from the central source. Having a mass outflow rate of more than one thousand solar masses per year and a kinetic energy output exceeding 5% of the Eddington luminosity, this outflow can significantly contribute to AGN feedback. Conclusions.Our findings suggest the absorption outflow in J1402+2330 plays a potentially significant role in AGN feedback processes. This study highlights the value of DESI data in exploring AGN feedback mechanisms.more » « less
-
ABSTRACT We analyse the VLT/UVES spectrum of the quasar SDSS J143907.5-010616.7, retrieved from the UVES Spectral Quasar Absorption Database. We identify two outflow systems in the spectrum: a mini broad absorption line (mini-BAL) system and a narrow absorption line (NAL) system. We measure the ionic column densities of the mini-BAL ($$v$$ = −1550 km s−1) outflow, which has excited state absorption troughs of $${\rm Fe\, \rm {\small {ii}}}$$. We determine that the electron number density $$\log {n_e}=3.4^{+0.1}_{-0.1}$$, based on the ratios between the excited and ground state abundances of $${\rm Fe\, \rm {\small {ii}}}$$, and find the kinetic luminosity of the outflow to be $${\lesssim}0.1\,\hbox{per cent}$$ of the quasar’s Eddington luminosity, making it insufficient to contribute to AGN feedback.more » « less
-
Abstract A key issue in the development of theory and models for plasma propulsion devices is to describe the instabilities and fluctuations of the devices. It has been widely recognized that many Hall effect thrusters (HETs) exhibit oscillations at frequencies in the range of ∼ 20 kHz. These ionization-related oscillations are generally referred to as Breathing Mode oscillations and have been the subject of considerable research. Here, for the first time, we report direct temporally resolved measurements of the ground state neutral density variation during the period of the oscillation. We used the laser-based Two-Photon Absorption Laser Induced Fluorescence (TALIF) technique to measure neutrals within the plume of a 1.5 kW HET operating on krypton (Kr). Our TALIF scheme employs a frequency-doubled, pulsed dye laser operating at ∼ 212 nm to probe ground state Kr atoms. A novel phase-binning approach is used to recover the time-dependent signal by assigning the timing of each collected TALIF signal (laser shot) relative to the phase of the discharge current. We find that the neutral density fluctuates quite strongly over the period of the oscillation, and that this fluctuation leads the current fluctuation as expected.more » « less
-
Abstract Plasma stratification has been studied for more than a century. Despite the many experimental studies reported on this topic, theoretical analyses and numerical modeling of this phenomenon have been mostly limited to rare gases. In this work, a one-dimensional fluid model with detailed kinetics of electrons and vibrationally excited molecules is employed to simulate moderate-pressure (i.e. a few Torrs) dc discharge in nitrogen in a 15.5 cm long tube of radius 0.55 cm. The model also considers ambipolar diffusion to account for the radial loss of ions and electrons to the wall. The proposed model predicts self-excited standing striations in nitrogen for a range of discharge currents. The impact of electron transport parameters and reaction rates obtained from a solution of local two-term and a multi-term Boltzmann equation on the predictions are assessed. In-depth kinetic analysis indicates that the striations result from the undulations in electron temperature caused due to the interaction between ionization and vibrational reactions. Furthermore, the vibrationally excited molecules associated with the lower energy levels are found to influence nitrogen plasma stratification and the striation pattern strongly. A balance between ionization processes and electron energy transport allows the formation of the observed standing striations. Simulations were conducted for a range of discharge current densities from ∼0.018 to 0.080 mA cm −2 , for an operating pressure of 0.7 Torr. Parametric studies show that the striation length decreases with increasing discharge current. The predictions from the model are compared against experimental measurements and are found to agree favorably.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1088/1361-6595/ad4238
