Betz, Markus; Elezzabi, Abdulhakem Y
                            (Ed.)
                        
                    
            
                            SnS2 is a two-dimensional (2D) layered semiconductor with a visible-range bandgap (~2.3eV), high charge carrier mobility, long carrier lifetimes, and good environmental stability. This study explores the impact of zero-valent metal intercalation into the van der Waals gaps of SnS2 on charge carrier dynamics. We demonstrate that metal intercalation enhances optical absorption in the yellow-to-IR range and induces metal-dependent bandgap shifts. Time-resolved THz spectroscopy reveals that different metals uniquely influence photoconductivity dynamics: We find that intercalation with Bi, Ni, and Fe shortens the photoconductivity decay times, whereas Rh intercalation results in a slower decay. These findings highlight the potential of metal intercalation to tailor SnS2 properties for diverse applications, from solar energy conversion to high-speed photodetectors. 
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