Cadmium telluride and silicon are among the widely used absorber materials in photovoltaic industry. A tandem solar cell of these two can absorb significant portion of solar spectrum to yield high efficiency due to the added voltage of the two solar cells. On basis of low-cost production, a CdTe/Si cell has the potential to produce low-cost and high efficiency tandem PV. The CdTe top cell in a substrate configuration is essential to achieve a tandem between CdTe and Si. A functional CdS/CdTe solar cell in the substrate configuration was fabricated on a Si wafer. Current -Voltage measurements show a diode-like curve with lower J-V parameters compared to standard CdS/CdTe cells. SCAPS simulations were performed to identify possible reasons for poor performance and help improve the device performance.
more »
« less
4-T CdTe/Perovskite Thin Film Tandem Solar Cells with Efficiency >24%
An integration of perovskite and cadmium telluride (CdTe) solar cells in a tandem configuration has the potential to yield efficient thin-film tandem solar cells. Owing to the promise of higher efficiency at low cost, the presented study aims to explore the potential for combining this commercially established CdTe photovoltaics (PV) with next-generation perovskite PV. Here, we developed four-terminal (4-T) CdTe/perovskite tandem solar cells, starting with 18.3% efficient near-infrared-transparent perovskite solar cells (NIR-TPSCs) with an average transmission (Tavg) of 24.76% in the 300−900 nm wavelength range. These were then integrated with 19.56% efficient opaque CdTe solar cells, achieving 23.42% efficiency in a 4-T tandem configuration. Additionally, using a refractive index matching liquid increases the overall power conversion efficiency (PCE)to 24.2%. This pioneering achievement marks the first instance of a 4-T CdTe/perovskite thin-film tandem solar cell exceeding a PCE of 24.2%, a significant 123.72% increase in overall PCE.
more »
« less
- Award ID(s):
- 2052735
- PAR ID:
- 10512631
- Editor(s):
- De_Angelis, Filippo
- Publisher / Repository:
- ACS Publications
- Date Published:
- Journal Name:
- ACS Energy Letters
- Edition / Version:
- 9
- Volume:
- 2024
- Issue:
- 9
- ISSN:
- 2380-8195
- Page Range / eLocation ID:
- 3019 to 3026
- Subject(s) / Keyword(s):
- Thin Film Tandem Solar Cells, NIR transparent solar cells, sputtered damage, index matching liquid, CdTe/Perovskite Solar Cell
- Format(s):
- Medium: X Size: 3MB Other: .cxv
- Size(s):
- 3MB
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
The tandem solar cell presents a potential solution to surpass the Shockley–Queisser limit observed in single-junction solar cells. However, creating a tandem device that is both cost-effective and highly efficient poses a significant challenge. In this study, we present proof of concept for a four-terminal (4T) tandem solar cell utilizing a wide bandgap (1.6–1.8 eV) perovskite top cell and a narrow bandgap (1.2 eV) antimony selenide (Sb2Se3) bottom cell. Using a one-dimensional (1D) solar cell capacitance simulator (SCAPS), our calculations indicate the feasibility of this architecture, projecting a simulated device performance of 23% for the perovskite/Sb2Se3 4T tandem device. To validate this, we fabricated two wide bandgap semitransparent perovskite cells with bandgaps of 1.6 eV and 1.77 eV, respectively. These were then mechanically stacked with a narrow bandgap antimony selenide (1.2 eV) to create a tandem structure, resulting in experimental efficiencies exceeding 15%. The obtained results demonstrate promising device performance, showcasing the potential of combining perovskite top cells with the emerging, earth-abundant antimony selenide thin film solar technology to enhance overall device efficiency.more » « less
-
Li, Gang; Nguyen, Thuc-Quyen; Nogueira, Ana Flávia; Rand, Barry P.; Moons, Ellen; Stingelin, Natalie (Ed.)Anti-solvent-free one-step deposition of perovskite thin film shows promising potential for application in slot-die or roll-to-roll mass fabrication processes of perovskite solar cells. The continuous coverage was confirmed by PV response of devices made using the on-step deposition process. In this work, we have developed a process to deposit MAPB0.75Sn0.25(I0.5Br0.5)3 perovskite thin films without anti-solvent adding MAAc to the ink. By varying the Br content of the perovskite precursor, we were able to tune the bandpap. Fabricated solar cells with the structure ITO/CuI/MAPb0.75Sn0.25(I0.5Br0.5)3/C60/BCP/Al with PCE of 4.59% show the parth of the fabrication process of antisolvent-free tin-lead-based solar cells.more » « less
-
Cadmium telluride (CdTe) thin-film semiconductors exhibit many desirable properties for low-cost and high-efficiency photovoltaic (PV) technology, including inherent robustness of inorganic absorber, a direct bandgap that allows full absorption of the solar spectrum with thicknesses of only few microns, and inexpensive and high-throughput manufacturing processes. At the best efficiency of 22 %, the power conversion efficiency of CdTe PVs is still well below the maximum theoretical limit (approximately 30 %). It has been suggested that the inferior efficiency is mainly attributed to the inherent polycrystalline nature of CdTe absorber (e.g., grains, grain boundaries). Understanding local photocarrier dynamics is vital to overcoming roadblocks toward higher efficiency CdTe PVs. However, conventional cell-level PV measurements often limit the microstructural analysis. In this work, we present a local PV characterization technique using point back-contacts. The thin-film CdTe solar cells used in this work were prepared by CSS (close-spaced sublimation) on a stack of n-type window layer (e.g., CdS) / transparent conductive layer (TCO; e.g., SnO2) / glass substrate.more » « less
-
Abstract: Monolithic integrated thin film tandem solar cells consisting of a high bandgap perovskite top cell and a low bandgap thin film bottom cell are expected to reach higher power conversion efficiencies (PCEs) with lower manufacturing cost and environmental impacts than the market-dominant crystalline silicon photovoltaics. There have been several demonstrations of 4-terminal and 2-terminal perovskite tandem devices with CuInGaSe 2 (CIGS) or CuInSe 2 (CIS) and, similar to the other tandem structures, the optimization of this device relies on optimal choice for the perovskite bandgap and thickness. Therefore, further advancement will be enabled by tuning the perovskite absorber to maximize the photocurrent limited by the current match condition. Here, we systematically study the optical absorption and transmission of perovskite thin films with varying absorber band gap. Based on these results, we model the photocurrent generations in both perovskite and CIS subcells and estimate the performances of projected tandem devices by considering the ideally functioning perovskite and CIS device. Our results show that for perovskite layers with 500 nm thickness the optimal bandgap is around 1.6 eV. With these configurations, PCEs above 20% could be achieved by monolithically integrated perovskite/CIS tandem solar cells. Also by modelling the absorption at every layer we calculate the quantum efficiency at each subcell in addition to tracking optical losses.more » « less
An official website of the United States government

