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Title: Plasma Electrochemistry for Carbon–Carbon Bond Formation via Pinacol Coupling
The formation of carbon-carbon bonds by pinacol coupling of aldehydes and ketones requires a large negative reduction potential, often realized with a stoichiometric reducing reagent. Here, we use solvated electrons generated via a plasma-liquid process. Parametric studies with methyl-4-formylbenzoate reveal that selectivity over the competing reduction to the alcohol requires careful control over mass transport. The generality is demonstrated with benzaldehydes, benzyl ketones, and furfural. A reaction-diffusion model explains the observed kinetics, and ab initio calculations provide insight into the mechanism. This study opens the possibility of a metal-free, electrically-powered, sustainable method for reductive organic reactions.  more » « less
Award ID(s):
2205819
PAR ID:
10519161
Author(s) / Creator(s):
; ; ; ; ; ; ; ;
Publisher / Repository:
American Chemical Society
Date Published:
Journal Name:
Journal of the American Chemical Society
Volume:
145
Issue:
19
ISSN:
0002-7863
Page Range / eLocation ID:
10470-10474
Subject(s) / Keyword(s):
Alcohols Aldehydes Chemical reactions Ketones Transfer reactions
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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