skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Understanding the material properties of alkali-treated lignocellulose fiber obtained from high-altitude Lokta bushes
Lignocellulose fiber obtained from high-altitude plant species Daphne bholua and Daphne papyracea, locally named Lokta bushes, is used in Asian regions to fabricate high-quality handmade paper sheets, packaging materials, composites, and paper bills. A systematic study on the material properties of the fiber to explain the performance of Lokta fiber–based materials has not been reported yet. In this study, the physio-chemical properties of untreated and 1%, 3%, 6%, and 9% NaOH (w/v)-treated Lokta fiber were systematically investigated at ambient temperature. The retting efficiency and cellulose content increased with alkali concentration followed by a decrease in lignin, hemicellulose, and extractives. This observation was consistent with the reduction of lignin and hemicellulose characteristics peaks in the FTIR, a reduction of effective fiber bundle width, and an increase in fiber density. High-resolution scanning electron microscope (SEM) images showed that alkali treatment results in significant loss of cementing materials and separation of fiber bundles. Alkali retting also increased the crystallinity index, tensile strength, and thermal stability. The degradation temperature for untreated, 6% NaOH treated, and 9% NaOH treated samples was found to be 325 °C, 343 °C, and 347 °C; respectively. The findings of this study will be important to optimize the end properties of the Lokta fiber–based paper and composite materials.  more » « less
Award ID(s):
1900998
PAR ID:
10526738
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ;
Publisher / Repository:
Springer
Date Published:
Journal Name:
Biomass Conversion and Biorefinery
ISSN:
2190-6815
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. null (Ed.)
    Biomass conversion to alcohols using supercritical methanol depolymerization and hydrodeoxygenation (SCM-DHO) with CuMgAl mixed metal oxide is a promising process for biofuel production. We demonstrate how maple wood can be converted at high weight loadings and product concentrations in a batch and a semi-continuous reactor to a mixture of C 2 –C 10 linear and cyclic alcohols. Maple wood was solubilized semi-continuously in supercritical methanol and then converted to a mixture of C 2 –C 9 alcohols and aromatics over a packed bed of CuMgAlO x catalyst. Up to 95 wt% of maple wood can be solubilized in the methanol by using four temperature holds at 190, 230, 300, and 330 °C. Lignin was solubilized at 190 and 230 °C to a mixture of monomers, dimers, and trimers while hemicellulose and cellulose solubilized at 300 and 330 °C to a mixture of oligomeric sugars and liquefaction products. The hemicellulose, cellulose, and lignin were converted to C 2 –C 10 alcohol fuel precursors over a packed bed of CuMgAlO x catalyst with 70–80% carbon yield of the entire maple wood. The methanol reforming activity of the catalyst decreased by 25% over four beds of biomass, which corresponds to 5 turnovers for the catalyst, but was regenerable after calcination and reduction. In batch reactions, maple wood was converted at 10 wt% in methanol with 93% carbon yield to liquid products. The product concentration can be increased to 20 wt% by partially replacing the methanol with liquid products. The yield of alcohols in the semi-continuous reactor was approximately 30% lower than in batch reactions likely due to degradation of lignin and cellulose during solubilization. These results show that solubilization of whole biomass can be separated from catalytic conversion of the intermediates while still achieving a high yield of products. However, close contact of the catalyst and the biomass during solubilization is critical to achieve the highest yields and concentration of products. 
    more » « less
  2. Bacterial cellulose (BC) is a versatile biopolymer with significant potential across biomedical, food, and industrial applications. To remove bacterial contaminants, such as protein and DNA, BC pellicles undergo purification, which traditionally relies on harsh alkali treatments, such as sodium hydroxide or strong surfactants, which present environmental concerns. In response, this study evaluates the efficacy of various non-conventional surfactants—both non-biodegradable and biodegradable—as alternatives for BC purification. Among the surfactants tested, sodium cocoyl isethionate (SCI), a mild anionic and biodegradable surfactant, emerged as particularly effective, achieving an 80.7% reduction in protein content and a 65.19% reduction in double-stranded DNA (dsDNA) content relative to untreated samples. However, these advantages were not without additional challenges, such as the appearance of residual surfactants. Given SCI’s promising performance and biodegradability, it was further examined in two-step treatment protocols; additionally, sodium dodecyl sulfate (SDS) was also examined as a more traditional anionic surfactant as well as NaOH. For the two-step treatment protocol, BC pellicles were treated with one reagent for 3 h, followed by a second reagent for an additional 3 h. Notably, by using NaOH as the final step in the two-step treatment protocol, residual surfactant was not detected in the FTIR analysis. Overall, this work demonstrates that SCI, in addition to subsequent NaOH treatment, can be used as a surfactant-based approach for BC purification, representing a potential environmentally friendly alternative to traditional surfactant-based approaches for BC purification. 
    more » « less
  3. Synthetic dye removal is a topic of increasing interest as textile recycling has become more popular in industries. While methods involving dye removal from wastewater effluent have been widely studied and reported on, research on decolorization of fabric itself remains quite unknown. In regard to the lack of research, this study presents cotton fabric samples dyed with crystal violet (CV) that were treated with varying concentrations of sodium hydroxide (NaOH). Fabric decolorization was studied using several characterization methods. Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and Raman spectroscopy data showed that the cellulose structure remained unchanged after CV and NaOH treatment. Characteristic CV peaks in the FTIR and Raman spectra were apparent only in the control sample, while the spectra of NaOH-treated samples were very similar to that of the cotton fabric. X-ray diffractometry (XRD) data also confirmed that the crystallite size of cellulose was not affected by CV and NaOH treatment. A visible violet hue remained in all NaOH-treated samples, though CV intensity was inversely proportional to NaOH concentration. The L*a*b* values were utilized to complement characterization results. As the concentration of NaOH was increased, the CIELAB parameters aligned more with those of the plain untreated fabric. 
    more » « less
  4. null (Ed.)
    The potential of cotton gin waste, a considerable challenge to the gin owners, has not been fully investigated as a renewable energy source via anaerobic digestion. The weathered cotton gin trash and inoculum for triplicate biomethane potential assays were obtained from a local cotton gin mill and a municipal wastewater treatment plant, respectively. The moisture, total solids, volatile solids, and C, H, N, S, hemicellulose + cellulose, and lignin contents of gin waste were determined in triplicates. The biomethane potential of untreated and pretreated (hot water and 6% NaOH (wet CGT weight basis) gin waste was determined at different inoculum to substrate ratios. The highest cumulative biomethane yield of 111.8 mL gvs-1 was observed in inoculum to substrate ratio of 2.3, and it was statistically similar to the values; 101.8, 104.7, 100.5, and 108.9 gvs-1, observed in 0.8, 1.2, 1.5, and 1.9, respectively. The biomethane yield at the inoculum to substrate ratio of 0.4 was significantly lower than all higher ratios. The T80-90 for biomethane production was 26-30 for the ISRs of 1.2, 1.5, and 2.3. The T80-90 for inoculum to substrate ratios of 0.4, 0.8, and 1.9 were 26-31, 27-32, and 27-31 d, respectively. The modified Gompertz equation fitted very well (R2 = 0.98-0.99) to the anaerobic digestion at all inoculum to substrate ratios and pretreatments as the observed and predicted biomethane values were similar. The model predicted a lag phase of 8-10 days for control and treatments compared to the observed of 10-15 days. The highest biodegradability of 24.8±2.6% was observed at inoculum to substrate ratio of 2.3, which was statistically similar to the values observed in ratios of 0.8, 1.2, 1.5, and 1.9, respectively. Among pretreatments, the highest biodegradability of 33.0±2.4 was observed in 6% NaOH pretreatment, and it was statistically similar to hot water treatment and non-pretreated or control. These research findings advance the knowledge in the anaerobic degradation of cotton gin trash, thus helping to maximize biomethane recovery from this agro-industrial waste. 
    more » « less
  5. This paper examines the influence of biochar on the properties of alkali-activated slag pastes using two activator solutions, namely NaOH and Na2CO3. The biochar demonstrated different absorption kinetics in the mixture of slag and the two activator solutions. The pastes with biochar showed a delay in the heat flow peak, compared to the pastes without biochar, but the cumulative heat release in these pastes at later hours was increased, compared to the pastes without biochar. It was found that the use of biochar reduced autogenous shrinkage in the pastes and the reduction in autogenous shrinkage was more pronounced in the alkali-activated slag with NaOH, compared to Na2CO3. The void structure of the pastes was investigated using x-ray micro-computed tomography. It was found that refined pore structure due to reduced effective solution/slag in the pastes with biochar was able to compensate for the decreasing effect of biochar voids on compressive strength. The electrical resistivity was shown to be lower in the pastes with biochar. 
    more » « less