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1. A window to the Early Cretaceous North American Climate and Environment: The ‘Lake Carpenter’ lacustrine strata of the Cedar Mountain Formation

   Suarez, M.B.; Al-Suwaidi, A.; Kirkland, J.I.; Snell, K.; Moller, A.; McLean, N.; Suarez, C.A.; Montgomery, E.; Paige, M. (January 2023, The Anatomical record Supplement)

   The Cedar Mountain Formation is thought to span a significant portion of the lower Cretaceous and the base of the upper Cretaceous (Valanginian to Cenomanian). As such, the Cedar Mountain Formation is important for understanding the transition of terrestrial ecosystems from those characterized by pre-angiosperm ecosystems of the Jurassic to the angiosperm-dominated ecosystems that characterized the height of dinosaur diversity in the later part of the Cretaceous. Lacustrine strata offer unique opportunities to shed light on environmental and climate conditions of the past. This study presents results from a multi-proxy study of lacustrine strata in the Cedar Mountain Formation termed “Lake Carpenter.” The sequence of strata is about ~30 m thick and located near Arches National Park. The lower ~7 m is characterized by dark organic-rich mudstones, shales, and tan limestones and dolostone. The middle portion between about 7 and 25m consists of more massive carbonate-rich strata with abundant aquatic fossils including ostracodes, charophytes, and fish scales. The upper portion to about 30 m consists of green to tan mudstones with carbonate nodules and increases in siliciclastic content. Carbonate mineralogies include calcite, high-magnesium calcite, and dolomite (including dolomicrites) based on XRD analyses. To put the lacustrine sequence into stratigraphic context, bulk organic C isotope values were utilized to construct a chemostratigraphic record. The carbon isotope values range from -32.3‰ to -21.1‰ vs. VPDB. Zircons from four suspected volcanic ash layers were analyzed for U-Pb using LA-ICP-MS. One of these produced concordant Cretaceous dates. The youngest zircons from this sample was analyzed using CA-ID-TIMS and produced a date of 115.65 ± 0.18 Ma. Based on the chemostratigraphic record and the U-Pb date, the deposition of the lacustrine sequence occurs in the mid to late Aptian and spans a time that is thought to have coincided with a cold snap based on marine records. Carbonate analyses of the carbonates within the lacustrine sequence ranges from -9.2‰ to +5.4‰ vs. VPDB for carbon and -9.3 to -0.3‰ vs. VPDB for oxygen. Overall, carbonate isotope data is positively covariant and along with the minerology, seems to suggest that the lake was a closed-basin, alkaline lake and would have likely experience significant evaporation. To investigate paleotemperature, selected samples were analyzed for clumped isotope values (47) to determine temperature of formation. Preliminary temperature estimates of calcite formation range from 27°C to 41°C. Estimates for dolomite range from 19°C to 21°C. Lacustrine carbonate formation typically is biased toward spring and summer and as such some of these temperatures (particularly the values for dolomites) seem slightly lower than expected for a greenhouse climate but may be consistent with a “cold-snap” during the late Aptian. Palustrine carbonates from the type section of the Ruby Ranch Member range 19.8°C to 44.5°C (Suarez et al. 2021) and suggests the lacustrine strata records a similar range in temperatures during the Aptian Stage in this part of North America. REFERENCES CITED: Suarez, MB, Knight, J, Snell, KE, Ludvigson, GA, Kirkland, JI, Murphy, L 2020. Multiproxy paleoclimate estimates of the continental Cretaceous Ruby Ranch Member of the Cedar Mountain Formation. In: Bojar, A-V, Pelc., A, Lecuyer, C, editors. Stable Isotopes Studies of Water Cycle and Terrestrial Environments. Geol Soc, London, Spec Pub, 507: https://doi.org/10.1144/SP507-2020-85 KEYWORDS: Early Cretaceous, lacustrine, stable isotopes, paleoclimate Presentation Mode: Invited Speaker 

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2. CARBON ISOTOPE CHEMOSTRATIGRAPHY OF THE LOWER CLASTIC KOOTENAI FORMATION, MT

   https://doi.org/10.1130/abs/2024AM-404104  

   Weldon, Annette; Suarez, Marina B; Suarez, Celina A (January 2024, Geological Society of America)

   The Kootenai Formation of Western Montana records the Aptian- Albian (121.4Ma-100.5Ma), a significant interval in Earth’s history. The Early Cretaceous is notable for a multitude of changes in both the geologic and biotic realm. Significant events that occurred during this time include the tectonic evolution of the Western Interior Basin (WIB) and the displacement of gymnosperms by angiosperms. Given the significance of this time, previous and ongoing research seek to better understand the timing and interactions between these changes. The focus of this study is to refine stratigraphic constraint of the Kootenai Formation using carbon isotope chemostratigraphy. The depositional age of the lower clastic unit of the Kootenai formation has been debated over the past decade. Detrital zircon U-Pb analyses by Laskowski et al. (2013) indicated an Albian age with a U-Pb detrital zircon maximum depositional age (MDA) of 109Ma. However, more recent studies (Finezl and Rosenblume, 2020 and Rosenblume et al. 2021) using LA-ICP-MS-generated detrital zircon U-Pb analyses indicate MDAs of the lower clastic unit as old as Valanginian to Aptian (MDAs ~135-115Ma) with the upper units of the Kootenai having MDAs from Albian (~105 Ma). Detrital zircon U-Pb analyses have generally been limited in the lower units of the Kootenai particularly because syndepositionally formed zircon grains are not common in the lower units (Quin et al. 2018, Finzel and Rosenblume 2020).Additionally, previous flora in the Kootenai suggests predominately Aptian and older ages(Brown 1946). Given the limited geochronologic constraint of the lower clastic unit of the Kootenai formation, addition data is needed. For this study, approximately 60 samples from just above the basal conglomerate to the top of the lower clastic unit were collected and processed to determine bulk organic carbon isotope values. The prior MDAs suggest C isotope excursions such as those associated with OAE1a and even as old as the Valanginian Weissert event could be preserved in the strata of the lower clastic unit. The new stable isotope data will provide an opportunity to refine the age of these Cretaceous units leveraging the existing U-Pb data. 

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3. Expedition 392 Scientific Prospectus: Agulhas Plateau Cretaceous Climate

   https://doi.org/10.14379/iodp.sp.392.2020  

   Uenzelmann-Neben, G.; Bohaty, S.M.; Kulhanek, D.K. (April 2020, Scientific prospectus)

   null (Ed.)

   The long-term climate transition from the Cretaceous greenhouse to the late Paleogene icehouse provides an opportunity to study changes in Earth system dynamics associated with large changes in global temperature and atmospheric CO2 levels. Elevated CO2 levels during the mid-Cretaceous supergreenhouse interval (~95–80 Ma) resulted in low meridional temperature gradients, and oceanic deposition during this time was punctuated by widespread episodes of severe anoxia termed oceanic anoxic events, resulting in enhanced burial of organic carbon in conjunction with transient carbon isotope and temperature excursions. The prolonged interval of mid-Cretaceous warmth and subsequent Late Cretaceous–Paleogene climate trends, as well as intervening short-lived climate excursions, are poorly documented in the southern high latitudes. International Ocean Discovery Program (IODP) Expedition 392 aims to drill five sites in the southwest Indian Ocean on the Agulhas Plateau and in the Transkei Basin, positioned at paleolatitudes of 65°–58°S during the Late Cretaceous (100–66 Ma) and in the new and evolving gateway between the South Atlantic, Southern Ocean, and southern Indian Ocean basins. Recovery of basement rocks and expanded sedimentary sequences from the Agulhas Plateau and Transkei Basin will provide a wealth of new data to (i) determine the nature and origin of the Agulhas Plateau and (ii) significantly advance the understanding of how Cretaceous temperatures, ocean circulation, and sedimentation patterns evolved as CO2 levels rose and fell and the breakup of Gondwana progressed. Importantly, Expedition 392 drilling will test competing hypotheses concerning Agulhas Plateau large igneous province formation and the role of deep ocean circulation changes through southern gateways in controlling Late Cretaceous–Paleogene climate evolution. 

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4. Changing inputs of continental and submarine weathering sources of Sr to the oceans during OAE 2

   https://doi.org/10.46427/gold2020.1889  

   Nana Yobo, L.; Brandon, A.D.; Holmden, C.; Lau, K.V.; Eldrett, J. (June 2021, Geochimica et cosmochimica acta)

   Jacobson, A. (Ed.)

   Ocean anoxic events (OAE) are characterized by increased organic content of marine sediment on a global scale with accompanying positive excursions in sedimentary organic and inorganic d 13C values. To sustain the increased C exports and burial required to explain the C isotope excursion, increased supplies of nutrients to the oceans are often invoked during ocean anoxic events. The potential source of nutrients in these events is investigated in this study for Oceanic Anoxic Event 2, which spans the Cenomanian-Turonian boundary. Massive eruptions of one or more Large Igneous Provinces (LIPs) are the proposed trigger for OAE 2. The global warming associated with volcanogenic loading of carbon dioxide to the atmosphere has been associated with increased continental weathering rates during OAE 2, and by extension, enhanced nutrient supplies to the oceans. Seawater interactions with hot basalts at LIP eruption sites can further deliver ferrous iron and other reduced metals to seawater that can stimulate increased productivity in surface waters and increased oxygen demand in deep waters. The relative importance of continental and submarine weathering drivers of expanding ocean anoxia during OAE 2 are difficult to disentangle. In this paper, a box model of the marine Sr cycle is used to constrain the timing and relative magnitudes of changes in the continental weathering and hydrothermal Sr fluxes to the oceans during OAE 2 using a new high-resolution record of seawater 87Sr/86Sr ratios preserved in a marl-limestone succession from the Iona-1 core collected from the Eagle Ford Formation in Texas. The results show that seawater 87Sr/86Sr ratios change synchronously with Os isotope evidence for the onset of massive LIP volcanism 60 kyr before the positive C isotope excursion that traditionally marks the onset of OAE 2. The higher temporal resolution of the seawater Sr isotope record presented in this study warrants a detailed quantitative analysis of the changes in continental weathering and hydrothermal Sr inputs to the oceans during OAE 2. Using an ocean Sr box model, it is found that increasing the continental weathering Sr flux by  1.8-times captures the change in seawater 87Sr/86Sr recorded in the Iona-1 core. The increase in the continental weathering flux is smaller than the threefold increase estimated by studies of seawater Ca isotope changes during OAE 2, suggesting that hydrothermal forcing may have played a larger role in the development of ocean anoxic events than previously considered. 

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5. Changing inputs of continental and submarine weathering sources of Sr to the oceans during OAE2

   https://doi.org/doi.org/10.1016/gca.2021.03.013  

   Nana Yobo, L.; Brandon, A.D.; Holmden, C.; Lau, K.V.; Eldrett, J. (January 2022, Geochimica et cosmochimica acta)

   Jacobson, A. (Ed.)

   Ocean anoxic events (OAE) are characterized by increased organic content of marine sediment on a global scale with accompanying positive excursions in sedimentary organic and inorganic d 13C values. To sustain the increased C exports and burial required to explain the C isotope excursion, increased supplies of nutrients to the oceans are often invoked during ocean anoxic events. The potential source of nutrients in these events is investigated in this study for Oceanic Anoxic Event 2, which spans the Cenomanian-Turonian boundary. Massive eruptions of one or more Large Igneous Provinces (LIPs) are the proposed trigger for OAE 2. The global warming associated with volcanogenic loading of carbon dioxide to the atmosphere has been associated with increased continental weathering rates during OAE 2, and by extension, enhanced nutrient supplies to the oceans. Seawater interactions with hot basalts at LIP eruption sites can further deliver ferrous iron and other reduced metals to seawater that can stimulate increased productivity in surface waters and increased oxygen demand in deep waters. The relative importance of continental and submarine weathering drivers of expanding ocean anoxia during OAE 2 are difficult to disentangle. In this paper, a box model of the marine Sr cycle is used to constrain the timing and relative magnitudes of changes in the continental weathering and hydrothermal Sr fluxes to the oceans during OAE 2 using a new high-resolution record of seawater 87Sr/86Sr ratios preserved in a marl-limestone succession from the Iona-1 core collected from the Eagle Ford Formation in Texas. The results show that seawater 87Sr/86Sr ratios change synchronously with Os isotope evidence for the onset of massive LIP volcanism 60 kyr before the positive C isotope excursion that traditionally marks the onset of OAE 2. The higher temporal resolution of the seawater Sr isotope record presented in this study warrants a detailed quantitative analysis of the changes in continental weathering and hydrothermal Sr inputs to the oceans during OAE 2. Using an ocean Sr box model, it is found that increasing the continental weathering Sr flux by
   1.8-times captures the change in seawater 87Sr/86Sr recorded in the Iona-1 core. The increase in the continental weathering flux is smaller than the threefold increase estimated by studies of seawater Ca isotope changes during OAE 2, suggesting that hydrothermal forcing may have played a larger role in the development of ocean anoxic events than previously considered. 

   more » « less