Here, the radiation hardness of metal halide perovskite solar cells exposed to space conditions versus the effects of environmental degradation are assessed. The relative response of the constituent layers of the architecture to radiation is analyzed, revealing a general resilience of the structure when assessed across varying proton energy levels and fluences. However, despite the tolerance of the structure to irradiation, sensitivity to environmental degradation is observed during the transit of the device between the radiation and characterization facilities. Experimental evidence suggests the NiO
This content will become publicly available on February 1, 2025
ACIGS solar cells are exposed to targeted radiation to probe the front and back interfaces of the absorber to assess the impact of space environments on these systems. These data suggest ACIGS cells are more radiation‐hard than early CIGS devices likely due to the lower defect densities and more ideal interfaces in the ACIGS system. A combination of
- Award ID(s):
- 2210722
- PAR ID:
- 10539030
- Publisher / Repository:
- Advance Science News, Solar RRL
- Date Published:
- Journal Name:
- Solar RRL
- Volume:
- 8
- Issue:
- 3
- ISSN:
- 2367-198X
- Page Range / eLocation ID:
- 2300756
- Subject(s) / Keyword(s):
- ACIGS, interfaces, radiation, stability, temperatures
- Format(s):
- Medium: X Size: 2.5MB Other: pdf
- Size(s):
- 2.5MB
- Sponsoring Org:
- National Science Foundation
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Irvine, John (Ed.)
Abstract x /perovskite interface is particularly sensitive to the effects of humidity and/or temperature exposure, while the irradiation of the devices appears to induce thermally activated annealing: improving the solar cells upon radiation exposure. -
The high tolerance and stability of triple halide perovskite solar cells is demonstrated in practical space conditions at high irradiation levels. The solar cells were irradiated for a range of proton energies (75 keV, 300 keV, and 1 MeV) and fluences (up to 4 × 1014 p/cm2). The fluences of the energy proton irradiations were varied to induce the same amount of vacancies in the absorber layer due to non-ionizing nuclear energy loss (predominant at <300 keV) and electron ionization loss (predominant at >300 keV). While proton irradiation of the solar cells initially resulted in degradation of the photovoltaic parameters, self-healing was observed after two months where the performance of the devices was shown to return to their pristine operation levels. Their ability to recover upon radiation exposure supports the practical potential of perovskite solar cells for next-generation space missions.
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