More Like this

1. Effects of Chain Ends on Thermal and Mechanical Properties and Recyclability of Poly( γ ‐butyrolactone)

   https://doi.org/10.1002/pola.29180  

   Tang, Jing; Chen, Eugene Y. ‐X. (September 2018, Journal of Polymer Science Part A: Polymer Chemistry)

   ABSTRACT This work investigates effects of poly(γ‐butyrolactone) (PγBL) with different initiation and termination chain ends on five types of materials properties, including thermal stability, thermal transitions, thermal recyclability, hydrolytic degradation, and dynamic mechanical behavior. Four different chain‐end‐capped polymers with similar molecular weights, BnO‐[C(=O)(CH₂)₃O]_n‐R, R = C(=O)Me, C(=O)CH=CH₂, C(=O)Ph, and SiMe₂CMe₃, along with a series of uncapped polymers R′O‐[C(=O)(CH₂)₃O]_n‐H (R′ = Bn, Ph₂CHCH₂) withM_nranging from low (4.95 kg mol⁻¹) to high (83.2 kg mol⁻¹), have been synthesized. The termination chain end R showed a large effect on polymer decomposition temperature and hydrolytic degradation, relative to H. Overall, for those properties sensitive to the chain ends, chain‐end capping renders R‐protected linear PγBL behaving much like cyclic PγBL. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem.2018,56, 2271–2279 

   more » « less
2. The Nature of Low-surface-brightness Galaxies in the Hyper Suprime-Cam Survey

   https://doi.org/10.3847/1538-4357/ac7238  

   Greene, Jenny E.; Greco, Johnny P.; Goulding, Andy D.; Huang 黄, Song 崧.; Kado-Fong, Erin; Danieli, Shany; Li 李, Jiaxuan 嘉轩; Kim, Ji Hoon; Komiyama, Yutaka; Leauthaud, Alexie; et al (July 2022, The Astrophysical Journal)

   Abstract We present the statistical redshift distribution of a large sample of low-surface-brightness (LSB) galaxies identified in the first 200 deg²of the Hyper Suprime-Cam Strategic Survey Program. Through cross-correlation with the NASA–SDSS Atlas, we find that the majority of objects lie withinz< 0.15 or ∼500 Mpc, yielding a mass range ofM_*≈ 10⁷−10⁹M_⊙and a size range ofr_eff,g≈ 1−8 kpc. We find a peak in the distance distribution within 100 Mpc, corresponding mostly to ∼10⁷M_⊙galaxies that fall on the known mass–size relation. There is also a tail in the redshift distribution out toz≈ 0.15, comprising more massive (M_*= 10⁸− 10⁹M_⊙) galaxies at the larger end of our size range. We see tentative evidence that at the higher-mass end (M_*> 10⁸M_⊙), the LSB galaxies do not form a smooth extension of the mass–size relation of higher-surface-brightness galaxies, perhaps suggesting that the LSB galaxy population is distinct in its formation path. 

   more » « less
3. Transverse momentum dependent distribution functions in the threshold limit

   https://doi.org/10.1007/JHEP11(2023)220  

   Kang, Zhong-Bo; Samanta, Kajal; Shao, Ding Yu; Zeng, Yang-Li (November 2023, Journal of High Energy Physics)

   A<sc>bstract</sc> We apply the joint threshold and transverse momentum dependent (TMD) factorization theorem to introduce new threshold-TMD distribution functions, including threshold-TMD parton distribution functions (PDFs) and fragmentation functions (FFs). We apply Soft-Collinear Effective Theory and renormalization group methods to carry out QCD evolution for both threshold-TMD PDFs and FFs. We show the universality of threshold-TMD functions among three standard processes, i.e. the Drell-Yan production inppcollisions, semi-inclusive deep-inelastic scattering and back-to-back two hadron production ine⁺e⁻collisions. In the end, we present the numerical predictions for different threshold-TMD functions and also transverse momentum distributions atpp,ep, ande⁺e⁻collisions. 

   more » « less
4. Improved Constraints on the 21 cm EoR Power Spectrum and the X-Ray Heating of the IGM with HERA Phase I Observations

   https://doi.org/10.3847/1538-4357/acaf50  

   Abdurashidova, The HERA Collaboration: Zara; Adams, Tyrone; Aguirre, James E.; Alexander, Paul; Ali, Zaki S.; Baartman, Rushelle; Balfour, Yanga; Barkana, Rennan; Beardsley, Adam P.; Bernardi, Gianni; et al (March 2023, The Astrophysical Journal)

   Abstract We report the most sensitive upper limits to date on the 21 cm epoch of reionization power spectrum using 94 nights of observing with Phase I of the Hydrogen Epoch of Reionization Array (HERA). Using similar analysis techniques as in previously reported limits, we find at 95% confidence that Δ²(k= 0.34hMpc⁻¹) ≤ 457 mK²atz= 7.9 and that Δ²(k= 0.36hMpc⁻¹) ≤ 3496 mK²atz= 10.4, an improvement by a factor of 2.1 and 2.6, respectively. These limits are mostly consistent with thermal noise over a wide range ofkafter our data quality cuts, despite performing a relatively conservative analysis designed to minimize signal loss. Our results are validated with both statistical tests on the data and end-to-end pipeline simulations. We also report updated constraints on the astrophysics of reionization and the cosmic dawn. Using multiple independent modeling and inference techniques previously employed by HERA Collaboration, we find that the intergalactic medium must have been heated above the adiabatic cooling limit at least as early asz= 10.4, ruling out a broad set of so-called “cold reionization” scenarios. If this heating is due to high-mass X-ray binaries during the cosmic dawn, as is generally believed, our result’s 99% credible interval excludes the local relationship between soft X-ray luminosity and star formation and thus requires heating driven by evolved low-metallicity stars. 

   more » « less
5. The Geochemistry of Englacial Brine From Taylor Glacier, Antarctica

   https://doi.org/10.1029/2018JG004411  

   Lyons, W. Berry; Mikucki, Jill A.; German, Laura A.; Welch, Kathleen A.; Welch, Susan A.; Gardner, Christopher B.; Tulaczyk, Slawek M.; Pettit, Erin C.; Kowalski, Julia; Dachwald, Bernd (March 2019, Journal of Geophysical Research: Biogeosciences)

   Abstract Blood Falls is a hypersaline, iron‐rich discharge at the terminus of the Taylor Glacier in the McMurdo Dry Valleys, Antarctica. In November 2014, brine in a conduit within the glacier was penetrated and sampled using clean‐entry techniques and a thermoelectric melting probe called the IceMole. We analyzed the englacial brine sample for filterable iron (fFe), total Fe, major cations and anions, nutrients, organic carbon, and perchlorate. In addition, aliquots were analyzed for minor and trace elements and isotopes including δD and δ¹⁸O of water, δ³⁴S and δ¹⁸O of sulfate,²³⁴U,²³⁸U, δ¹¹B,⁸⁷Sr/⁸⁶Sr, and δ⁸¹Br. These measurements were made in order to (1) determine the source and geochemical evolution of the brine and (2) compare the chemistry of the brine to that of nearby hypersaline lake waters and previous supraglacially sampled collections of Blood Falls outflow that were interpreted asend‐memberbrines. The englacial brine had higher Cl⁻concentrations than the Blood Falls end‐member outflow; however, other constituents were similar. The isotope data indicate that the water in the brine is derived from glacier melt. The H₄SiO₄concentrations and U and Sr isotope suggest a high degree of chemical weathering products. The brine has a low N:P ratio of ~7.2 with most of the dissolved inorganic nitrogen in the form of NH₄⁺. Dissolved organic carbon concentrations are similar to end‐member outflow values. Our results provide strong evidence that the original source of solutes in the brine was ancient seawater, which has been modified with the addition of chemical weathering products. 

   more » « less